vestichИзвестия Национальной академии наук Беларуси. Серия химических наукProceedings of the National Academy of Sciences of Belarus, Chemical Series1561-83312524-2342The Republican Unitary Enterprise Publishing House "Belaruskaya Navuka"10.29235/1561-8331-2026-62-3-222-228vestich-1030Research ArticleБИООРГАНИЧЕСКАЯ ХИМИЯBIOORGANIC CHEMISTRYСинтез и биологическая активность комплексных соединений марганца (II) с аминокислотамиSynthesis and biological activity of complex compounds of manganese (II) with amino acidshttps://orcid.org/0009-0003-4816-2420ГусейновЭ. Р.HuseynovE. R.

Гусейнов Эльчин Рамиз – кандидат химических наук, доцент, ведущий научный сотрудник

пр-т Г. Джавида, 113, AZ1143, Баку

Huseynov Elchin R. – Ph. D. (Chemistry), Associate Professor, Leading Researcher

113, H. Javid Ave., AZ1143, Baku 

ger.999@mail.ruhttps://orcid.org/0000-0002-0998-1947ЗейналовЭ. Б.ZeynalovE. B.

Зейналов Эльдар Багадур – член-корреспондент НАН Азербайджана, доктор химических наук, профессор, заведующий лабораторией

пр-т Г. Джавида, 113, AZ1143, Баку

Zeynalov Eldar B. – Corresponding Member of the National Academy of Sciences of Azerbajjan, Dr. Sci. (Chemistry), Pro­ fessor, Head of Laboratory

113, H. Javid Ave., AZ1143, Baku 

elzey@mail.ruhttps://orcid.org/0009-0006-0276-1067ШарифоваС. К.SharifovaS. K.

Шарифова Сайда Камиль – кандидат химических наук, доцент, ведущий научный сотрудник

пр-т Г. Джавида, 113, AZ1143, Баку

Sharifova Saida K. – Ph. D. (Chemistry), Associate Professor, Leading Researcher

113, H. Javid Ave., AZ1143, Baku 

https://orcid.org/0009-0006-0276-1067АбдуллаеваФ. А.AbdullayevaF. A.

Абдуллаева Фарида Али – кандидат химических наук, доцент, ведущий научный сотрудник

пр-т Г. Джавида, 113, AZ1143, Баку

Abdullayeva Farida A. – Ph. D. (Chemistry), Associate Professor, Leading Researcher

113, H. Javid Ave., AZ1143, Baku 

faridaabdullaeva1949@gmail.comhttps://orcid.org/0009-0009-0608-7294БехбудоваС. К.BehbudovaS. K.

Бехбудова Саадат Камо – научный сотрудник 

пр-т Г. Джавида, 113, AZ1143, Баку

Behbudova Saadat K. – Researcher 

113, H. Javid Ave., AZ1143, Baku 

chem@kgki.science.azИнститут катализа и неорганической химии имени академика М. Нагиева Министерства науки и образования Азербайджанской РеспубликиАзербайджанAcademician M. Nagiyev Institute of Catalysis and Inorganic ChemistryAzerbaijan202629082026623222228Copyright © Гусейнов Э.Р., Зейналов Э.Б., Шарифова С.К., Абдуллаева Ф.А., Бехбудова С.К., 20262026Гусейнов Э.Р., Зейналов Э.Б., Шарифова С.К., Абдуллаева Ф.А., Бехбудова С.К.Huseynov E.R., Zeynalov E.B., Sharifova S.K., Abdullayeva F.A., Behbudova S.K.Данная работа распространяется под лицензией Creative Commons Attribution 4.0.This work is licensed under a Creative Commons Attribution 4.0 License.https://vestichem.belnauka.by/jour/article/view/1030

Синтезированы комплексные соединения на основе кристаллогидрата хлорида марганца (II) MnCl2∙4H2O с аминокислотами различного класса: алифатическими – глицином и гетероциклическими − гистидином и трипто­ фаном с соответствующими выходами. Идентификацию полученных соединений проводили методами ИК-спектро­ скопии, дифференциально-термического анализа, электронной микроскопии и элементного анализа. На основе химического анализа и электронной микроскопии установлен количественный состав комплекса [NH2CH2COO]2Mn ∙ 2H2O. Исследована каталитическая окислительная активность [NH2CH2COO]2Mn ∙2H2O, использованного в качестве активной добавки в модельной реакции аэробного окисления изопропилбензола (кумола). Установлено, что соеди­ нение обладает высокой каталитической активностью и ускоряет реакцию в 10 раз по сравнению с контрольным образцом. Синтезированные комплексы были апробированы на биологическую активность. Выявлено, что они обла­ дают антибактериальными, антивирусными и психотропными свойствами.

Complex compounds based on manganese (II) chloride crystal hydrate MnCl2 ∙ 4H2O with amino acids of different classes, such as aliphatic – glycine and heterocyclic – histidine and tryptophan have been synthesized and identified with IR spectroscopy, differenti-al thermal analysis, electron microscopy and elemental analysis. Using elemental analysis and electron microscopy we determined chemical composition of the complex as [NH2CH2COO]2Mn ∙ 2H2O. The catalytic oxidative activity of [NH2CH2COO]2Mn ∙ 2H2O comples has been tested in the model reaction of aerobic oxidation of isopropyl-benzene (cumene). [NH2CH2COO]2Mn ∙ 2H2O complex demostrated high catalytic activity and accelerated the reaction by 10 times compared to the control sample. The tests for biological activity demonstrate antibacterial, antiviral and psychotropic properties of synthesized complexes.

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The authors declare that there are no conflicts of interest present.