vestichИзвестия Национальной академии наук Беларуси. Серия химических наукProceedings of the National Academy of Sciences of Belarus, Chemical Series1561-83312524-2342The Republican Unitary Enterprise Publishing House "Belaruskaya Navuka"10.29235/1561-8331-2019-55-2-196-204vestich-391Research ArticleХИМИЯ ВЫСОКОМОЛЕКУЛЯРНЫХ СОЕДИНЕНИЙPOLYMER CHEMISTRYПалладий-полимерный нанокомпозит: эффективный катализатор зеленых процессов кросссочетания по Сузуки–Мияуре и восстановления нитробензола по Мотт-ШоткиPalladiumPolymer Nanocomposite: An Efficient Catalyst for Green Suzuki–Miyaura Cross-Coupling and Mott-Schottky Nitrobenzene Reduction ProcessesЗураевА. В.ZuraevA. V.

Зураев Александр Викторович – аспирант кафедры неорганической химии, Белорусский государственный университет

пр. Независимости, 4, 220030, Минск;

мл. науч. сотрудник, Научно-исследовательский институт физико-химических проблем Белорусского государственного университета

ул. Ленинградская, 14, 220030, Минск

Alexandr V. Zuraev – Postgraduate student, Belarusian State University

4, Nezavisimosti Ave., 220030, Minsk;

Junior researcher, Research Institute for Physical Chemical Problems of the Belarusian State University

14, Leningradskaya Str., 220030, Minsk

alex.zuraev@gmail.comГригориевЮ. В.GrigorievY. V.

Григориев Юрий Викторович – канд. хим. наук, зав. лаб.

ул. Ленинградская, 14, 220030, Минск

Yurii V. Grigoriev – Ph. D. (Chemistry), Head of the laboratory

14, Leningradskaya Str., 220030, Minsk

azole@bsu.byВербилоК. М.VerbiloC. M.

Вербило Кирилл Маратович – студент

пр. Независимости, 4, 220030, Минск

Ciryl M. Verbilo – student

4, Nezavisimosti Ave., 220030, Minsk

cyrilvermar@gmail.comИвашкевичЛ. С.IvashkevichL. S.

Ивашкевич Людмила Сергеевна – канд. хим. наук, доцент, зав. лаб.

ул. Ленинградская, 14, 220030, Минск

Ludmila S. Ivashkevich – Ph. D. (Chemistry), Associate Professor, Head of Laboratory

14, Leningradskaya Str., 220030, Minsk

iva@bsu.byЛяховА. С.LyakhovA. S.

Ляхов Александр Семенович – канд. хим. наук, доцент, вед. науч. сотрудник

ул. Ленинградская, 14, 220030, Минск

Alexandr S. Lyakhov – Ph. D. (Chemistry), the Professor, assistant, Leading research

14, Leningradskaya Str., 220030, Minsk

lyakhov@bsu.byИвашкевичО. А.IvashkevichO. A.

Ивашкевич Олег Анатольевич – академик, д-р хим. наук, профессор, первый проректор

пр. Независимости, 4, 220030, Минск

Oleg A. Ivashkecich – Academician, D. Sc. (Chemistry), Professor, the First Prorector

4, Nezavisimosti Ave., 220030, Minsk

IvashkevichO@bsu.byНаучно-исследовательский институт физико-химических проблем Белорусского государственного университета; Белорусский государственный университетResearch Institute for Physical Chemical Problems of Belarusian State University; Belarusian State UniversityНаучно-исследовательский институт физико-химических проблем Белорусского государственного университетаResearch Institute for Physical Chemical Problems of Belarusian State UniversityБелорусский государственный университетBelarusian State University201929062019552196204Copyright © Зураев А.В., Григориев Ю.В., Вербило К.М., Ивашкевич Л.С., Ляхов А.С., Ивашкевич О.А., 20192019Зураев А.В., Григориев Ю.В., Вербило К.М., Ивашкевич Л.С., Ляхов А.С., Ивашкевич О.А.Zuraev A.V., Grigoriev Y.V., Verbilo C.M., Ivashkevich L.S., Lyakhov A.S., Ivashkevich O.A.Данная работа распространяется под лицензией Creative Commons Attribution 4.0.This work is licensed under a Creative Commons Attribution 4.0 License.https://vestichem.belnauka.by/jour/article/view/391

Посредством термолиза поли-5-винилтетразолата палладия(II) был получен новый катализатор для зеленых процессов кросс-сочетания Сузуки–Мияуры и восстановления нитробензола по Мотт-Шотки. Гетерогенный катализатор содержит наночастицы Pd, стабилизированные полимерной матрицей. Данный катализатор является легко восстанавливаемым и пригодным для повторного использования, а также катализирует реакции, проводимые в водной среде при комнатной температуре в аэробных условиях.

A new catalyst for green Suzuki–Miyaura cross-coupling and Mott-Schottky nitrobenzene reduction processes was prepared by thermolysis of palladium (II) poly-5-vinyltetrazolate. Heterogeneous catalyst includes Pd-nanoparticles supported on polymeric matrix. It presents recoverable and recyclable catalyst and the catalyzed reactions proceed in aqueous media at room temperature in aerobic conditions.

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The authors declare that there are no conflicts of interest present.