vestichИзвестия Национальной академии наук Беларуси. Серия химических наукProceedings of the National Academy of Sciences of Belarus, Chemical Series1561-83312524-2342The Republican Unitary Enterprise Publishing House "Belaruskaya Navuka"10.29235/1561-8331-2020-56-1-7-14vestich-560Research ArticleФИЗИЧЕСКАЯ ХИМИЯPHYSICAL CHEMISTRYМатематическое описание сорбции этиламинов из воздуха волокнистыми катионитами в условиях ограниченной проницаемости сорбатаMathematical description of ethylamine sorption from air by fibrous cation exchangers under conditions of limited sorbate permeabilityКосандровичЕ. Г.KosandrovichE. G.

Косандрович Евгений Генрихович – кандидат химических наук, доцент, зав. лабораторией

ул. Сурганова, 13, 220072, Минск

Evgenii G. Kasandrovich – Ph. D. (Chemistry), Associate Professor, Head of the Laboratory

13, Surganov Str., 220072, Minsk

kosandrovich@ifoch.bas-net.byШаченковаЛ. Н.ShachenkovaL. N.

Шаченкова Лариса Николаевна – кандидат химических наук, старший научный сотрудник

ул. Сурганова, 13, 220072, Минск

Larisa N. Shachenkova – Ph. D. (Chemistry), Senior Researcher

13, Surganov Str., 220072, Minsk

sln13102005@mail.ruПушкарчукА. Л.PushkarchukA. L.

Пушкарчук Александр Леонидович – кандидат физико-математических наук, старший научный сотрудник

ул. Сурганова, 13, 220072, Минск

Alexander L. Pushkarchuk – Ph. D. (Physics), Senior Researcher

13, Surganov Str., 220072, Minsk

alexp51@bk.ruБезъязычнаяТ. В.Bez’yazychnayaT. V.

Безъязычная Татьяна Владимировна – кандидат физико-математических наук, старший научный сотрудник

ул. Сурганова, 13, 220072, Минск

Tatyana V. Bezyazychnaya – Ph. D. (Physics), Senior Researcher

13, Surganov Str., 220072, Minsk

kvant@ifoch.bas-net.byСолдатовВ. С.SoldatovV. S.

Солдатов Владимир Сергеевич – академик, доктор химических наук, профессор, главный научный сотрудник

ул. Сурганова, 13, 220072, Минск

Soldatov Vladimir Sergeevich – Academician, D.Sc. (Chemistry), Professor, Chief Researcher

13, Surganov Str., 220072, Minsk

soldatov@ifoch.bas-net.byИнститут физико-органической химии Национальной академии наук БеларусиInstitute of Physical Organic Chemistry of the National Academy of Sciences of Belarus202018032020561714Copyright © Косандрович Е.Г., Шаченкова Л.Н., Пушкарчук А.Л., Безъязычная Т.В., Солдатов В.С., 20202020Косандрович Е.Г., Шаченкова Л.Н., Пушкарчук А.Л., Безъязычная Т.В., Солдатов В.С.Kosandrovich E.G., Shachenkova L.N., Pushkarchuk A.L., Bez’yazychnaya T.V., Soldatov V.S.Данная работа распространяется под лицензией Creative Commons Attribution 4.0.This work is licensed under a Creative Commons Attribution 4.0 License.https://vestichem.belnauka.by/jour/article/view/560

Предложена математическая модель, позволяющая описывать зависимость величины сорбции ионитами протонизирующихся в водных растворах щелочных соединений (на примере аммиака, моно-, диитриэтиламина). Для этих веществ экспериментально определены константы Генри. Модель учитывает концентрацию и кислотно-основные свойства сорбата, относительную влажность воздуха, кислотно-основные свойства и обменную емкость ионита, доступность функциональных групп для взаимодействия в условиях ограниченной проницаемости полимерного ионита. Показано хорошее соответствие рассчитанных по модели и экспериментальных данных по сорбции аммиака и этиламинов из воздуха волокнистыми карбоксильным и сульфоионитом.

A mathematical model for description of the sorption capacity of ion exchangers on alkaline compounds protonizable in aqueous solutions (exemplified by ammonia, mono-, diand triethylamine) was proposed. The Henry’s constants for these substances were experimentally determined. The model accounts for the concentration and acid-base properties of the sorbate, relative air humidity, acid-base properties and exchange capacity of the ion exchanger, as well as spatial availability of functional groups for interaction under conditions of limited permeability of polymeric ion exchanger. The applicability of the model is illustrated by processing the experimental results on the sorption of ammonia and ethylamines by fibrous carboxylic and sulfonic cation exchangers. Good agreement between the calculated and experimental data is observed.

волокнистый ионитсорбциявоздухаммиакэтиламиндиэтиламинтриэтиламинконстанта Генриfibrous ion exchangersorptionairammoniaethylaminediethylaminetriethylamineHenry’s constantReferencesGostelov, P. Odour measurements for sewage treatment works / P. Gostelov, S. A. Parsons, R. M. Stuetz // Water Research. – 2001. – Vol. 35, N 3. – P. 579–597. https://doi.org/10.1016/S0043-1354(00)00313-4Gostelov P., Parsons S. A., Stuetz R. M. Odour measurements for sewage treatment works. Water Research, 2001, vol. 35, no. 3, pp. 579–597. https://doi.org/10.1016/S0043-1354(00)00313-4Hayes, E. T. Odour and ammonia emissions from intensive pig units in Ireland / E. T. Hayes, T. P. Curran, V. A. Dodd // Bioresource Technology. – 2006. – Vol. 97, N 7. – P. 940–948. DOI: 10.1016/j.biortech.2005.04.023Hayes E. T., Curran T. P., Dodd V. A. Odour and ammonia emissions from intensive pig units in Ireland. Bioresource Technology, 2006, vol. 97, no. 7, pp. 940–948. https://doi.org/10.1016/j.biortech.2005.04.023Removal of methylamine from air by means of fibrous ion exchangers / H. Wasag [et al.] // III ogolnopolski kongres inzynierii srodowiska. Lublin. Poland. 13–17 september. – 2009. – P. 247–253.Wasag H., Guz L., Sobczuk H., Czerwinski J., Kujawska J. Removal of methylamine from air by means of fibrous ion exchangers. III ogolnopolski kongres inzynierii srodowiska. Lublin, Poland, 13–17 september, 2009. Lublin, 2009, pp. 247–253.Soldatov, V. S. Ion exchangers for air purification / V. S. Soldatov, E. G. Kosandrovich // Ion Exchange and Solvent Extraction Series. – 2011. – Vol. 20. – P. 45–117. https://doi.org/10.1201/b10813-3Soldatov V. S., Kosandrovich E. G. Ion exchangers for air purification. Ion Exchange and Solvent Extraction Series, 2011, vol. 20, pp. 45–117. https://doi.org/10.1201/b10813-3Airborn Molecular Contamination. Chemical filters – the right solution for every customer [Electronic Resource] // Technical Bulletin of M+W Zander Ltd, Stuttgart, Germany. 2001. – Mode of access: https://www.entegris.com/content/dam/shared-product-assets/vaporsorb/brochure-airborne-molecular-contamination-solutions-for-the-microelectronicsindustry-10092.pdf. – Date of access: 18.10.2019.Airborn Molecular Contamination. Chemical filters – the right solution for every customer. Technical Bulletin of M+W Zander Ltd, Stuttgart, Germany. 2001. Available at: https://www.entegris.com/content/dam/shared-product-assets/vaporsorb/brochure-airborne-molecular-contamination-solutions-for-the-microelectronics-industry-10092.pdf (accessed 18 October 2019).PURATEX Air Chemical Filters, Technical Bulletin of TAKUMA Co., Ltd, Japan [Electronic Resource]. – Mode of access: https://www.takuma.co.jp/english/investor/annual_report/images/2017/annualreport2017. – Date of access: 05.10.2019.PURATEX Air Chemical Filters. Technical Bulletin of TAKUMA Co., Ltd, Japan. Available at: https://www.takuma.co.jp/english/investor/annual_report/images/2017/annualreport2017 (accessed 05 October 2019).Soldatov, V. S. Synthesis, structure and applications of new fibrous ion exchangers / V. S. Soldatov, A. A. Shunkevich, G. I. Sergeev // React. Polymers. – 1988. – N 7. – P. 159–172. https://doi.org/10.1016/0167-6989(88)90136-5Soldatov V. S., Shunkevich A. A., Sergeev G. I. Synthesis, structure and applications of new fibrous ion exchangers. Reactive Polymers, 1988, no. 7, pp. 159–172. https://doi.org/10.1016/0167-6989(88)90136-5A strong acid nonwoven filtering medium for deep air purification / V. S. Soldatov [et al.] // Fibres and textiles in Eastern Europe. – 2004. – Vol. 12, N 4. – P. 56–61.Soldatov V. S., Polus Z., Pawlowska M., Maczka I., Shunkevich A., Kosandrovich E., Polikarpov А. A strong acid nonwoven filtering medium for deep air purification. Fibres and textiles in Eastern Europe, 2004, vol.12, no 4, pp. 56–61.Odour control by fibrous ion exchangers / V. S. Soldatov [et al.] // Chemical Engineering Transactions. Proceedings of NOSE2008: 1st International Conference on Environmental Odour Monitoring and Control. 6-8 July 2008. Rome. Italy. – 2008. – Vol. 15. – P. 387–395.Soldatov V. S., Wasag H., Kosandrovich E. G., Sobczuk H. Odour control by fibrous ion exchangers. Chemical Engineering Transactions. Proceedings of NOSE2008: 1st International Conference on Environmental Odour Monitoring and Control. 6–8 July 2008. Rome. Italy, 2008, vol. 15, pp. 387–395.Removal of ammonia from air by fibrous ion exchangers / H. Wasag [et al.] // Environment protection engineering. – 2009. – Vol. 35, N 3. – P. 293–304.Wasag H., Pawlowski L., Soldatov V., Kosandrovich E. Removal of ammonia from air by fibrous ion exchangers. Environment protection engineering, 2009, vol. 35, no 3, pp. 293–304.Косандрович, Е. Г. Сорбция первичных, вторичных и третичных этиламинов из воздуха волокнистыми ионитами. 1. Сильнокислотный сульфокатионит ФИБАН К-1 / Е. Г. Косандрович // Вес. Нац. акад. навук Беларусi. Сер. хiм. навук. – 2014. – № 4. – С. 11–15.Kosandrovich E. G. Sorption of primary, secondary and tertiary ethylamines from the air with fibrous ion exchangers. 1. Strongly acid sulfocationite FIBAN K-1. Vestsi Natsyyanal’nai akademii navuk Belarusi. Seryya khimichnykh navuk = Proceedings of the National Academy of Sciences of Belarus. Chemiсal series, 2014, no. 4, pp. 11–15 (in Russian).Сорбция первичных, вторичных и третичных этиламинов из воздуха волокнистыми ионитами. 2. Слабокислотный карбоксильный катионит ФИБАН К-4 / О. Н. Дорошкевич [и др.] // Вес. Нац. акад. навук Беларусi. Сер. хiм. навук. – 2014. – № 4. – С. 16–20.Doroshkevich O. N., Kosandrovich E. G. Kashinskiy A. V., Shachenkova L. N., Zelenkovskii V. М. Sorption of primary, secondary and tertiary ethylamines from the air with fibrous ion exchangers. 2. Weak-acid carboxyl cation exchanger FIBAN K-4. Vestsi Natsyyanal’nai akademii navuk Belarusi. Seryya khimichnykh navuk = Proceedings of the National Academy of Sciences of Belarus. Chemical series, 2014, no. 4, pp. 16–20 (in Russian).Soldatov, V. S. Сhemical equilibria between the ion exchanger and gas phase / V. S. Soldatov, E. G. Kosandrovich // Reсent аdvances in Ion Exchange Theory and Practice (Proceedings of IEX 2008), Fitxwilliam College, Cambridge, 9–11 July. – 2008. – P. 103–110.Soldatov V. S., Kosandrovich E. G. Сhemical equilibria between the ion exchanger and gas phase. Reсent аdvances in Ion Exchange Theory and Practice (Proceedings of IEX 2008), Fitxwilliam College, Cambridge 9–11 July, 2008, pp. 103–110.Солдатов, В. С. Теоретическое описание сорбционных равновесий в системах ионит-газ / В. С. Солдатов, Е. Г. Косандрович // Химия и технология новых веществ и материалов: сб. науч. трудов / под ред. А. В. Бильдюкевича [и др.]. – Минск: Белорус. наука, 2008. – Вып. 2 – С. 206–228.Soldatov V. S, Kosandrovich E. G. Theoretical description of sorption equilibria in ion-gas systems. Khimiya i tekhnologiya novykh veshchestv i materialov: sb. nauch. trudov [Chemistry and technology of new substances and Materials: a collection of scientific works]. Minsk, Belaruskaya navuka Publ., 2008, iss. 2, pp. 206–228 (in Russian).Косандрович, Е. Г. Сорбция аммиака из воздуха волокнистым сульфокатионитом ФИБАН К-1 / Е. Г. Косандрович, В. С. Солдатов // Вес. Нац. акад. навук Беларусi. Сер. хiм. навук. – 2004. – № 3. – С. 95–98.Kosandrovich E. G., Soldatov V. S. Ammonia sorption from air by FIBAN K-1 fibrous sulphonic cation exchanger. Vestsi Natsyyanal’nai akademii navuk Belarusi. Seryya khimichnykh navuk = Proceedings of the National Academy of Sciences of Belarus. Chemical series, 2004, no. 3, pp. 95–98 (in Russian).Soldatov, V. Hydration of ion exchangers: thermodynamics and quantum chemistry calculations. II an improved variant of the predominant hydrates model / V. Soldatov, V. Zelenkovskii, E. Kosandrovich // React. and Funct. Polym. – 2016. – Vol. 102. – P. 147–155. https://doi.org/10.1016/j.reactfunctpolym.2016.03.014Soldatov V., Zelenkovskii V., Kosandrovich E. Hydration of ion exchangers: thermodynamics and quantum chemistry calculations. II an improved variant of the predominant hydrates model. Reactive and Functional Polymers, 2016, vol. 102, pp. 147–155. https://doi.org/10.1016/j.reactfunctpolym.2016.03.014Косандрович, Е. Г. Распределение аммиака, моно-, дии триэтиламина в системе «водный раствор-газовая фаза» / Е. Г. Косандрович, Л. Н. Шаченкова, В. С. Солдатов // Докл. Нац. акад. наук Беларуси. – 2019. – Т. 63, № 2. – С. 164–168. https://doi.org/10.29235/1561-8323-2019-63-2-164-168Kosandrovich E., Shachenkova L., Soldatov V. Distribution of ammonia, mono-, diand triethylamine in the “Water solution раствор gas phase” system. Doklady Natsional’noy akademii nauk Belarusi = Doklady of the National Academy of Sciences of Belarus, 2019, vol. 63, no. 2, pp. 164–168 (in Russian). https://doi.org/10.29235/1561-8323-2019-63-2-164-168Kosandrovich, E. G. Fibrous ion exchangers / E. G. Kosandrovich, V. S. Soldatov // Ion exchange technology I: theory and materials / ed. by Inamuddin [et al.]. – London, 2012. – Р. 299–371. https://doi.org/10.1007/978-94-007-1700-8_9Kosandrovich E. G., Soldatov V. S. Fibrous ion exchangers. Ion exchange technology I: theory and materials. London, GB, 2012, pp. 299–371. https://doi.org/10.1007/978-94-007-1700-8_9

The authors declare that there are no conflicts of interest present.