vestichИзвестия Национальной академии наук Беларуси. Серия химических наукProceedings of the National Academy of Sciences of Belarus, Chemical Series1561-83312524-2342The Republican Unitary Enterprise Publishing House "Belaruskaya Navuka"10.29235/1561-8331-2020-56-4-399-407vestich-611Research ArticleФИЗИЧЕСКАЯ ХИМИЯPHYSICAL CHEMISTRYНанотрубки со структурой типа «магнитное ядро-оболочка из благородного металла»Nanotubes with a structure of the «magnetic core-noble metal shell» typeШумскаяЕ. Е.ShumskayaE. E.

Шумская Елена Евгеньевна - научный сотрудник.

Ул. Ф. Скорины, 36, 220141, Минск

Alena E. Shumskaya - Researcher.

36, F. Skoryna Str., 220141, Minsk

Lunka7@mail.ruРогачевА. А.RogachevA. A.

Рогачев Александр Александрович - доктор технических наук, профессор, директор.

Ул. Ф. Скорины, 36, 220141, Минск

Alexandr A. Rogachev - D. Sc. (Engineering), Professor, Director.

36, F. Sko-ryna Str., 220141, Minsk

rogachev78@mail.ruАгабековВ. Е.AgabekovV. E.

Агабеков Владимир Енокович - зкадемик, доктор химических наук, профессор.

Ул. Ф. Скорины, 36, 220141, Минск

Vladimir E. Agabekov - Academician, D. Sc. (Chemistry), Professor.

36, F. Sko-ryna Str., 220141, Minsk

agabekov@ichnm.byДовыденкоЕ. М.DovydenkoE. М.

Довыденко Егор Михайлович - младший научный сотрудник.

Ул. Ф. Скорины, 36, 220141, Минск

Egor M. Dovydenko - Junior Researcher.

36, F. Skoryna Str., 220141, Minsk

dovydenko.e93@mail.ruПеткевичА. В.PetkevichA. V.

Петкевич Анна Васильевна - младший научный сотрудник.

Ул. Ф. Скорины, 36, 220141, Минск

Anna V. Petkevich - Junior Researcher.

36, F. Skoryna Str., 220141, Minsk

m_a_w1987@mail.ruКорольковИ. В.KorolkovI. V.

Корольков Илья Владимирович - кандидат технических наук, зав. лабораторией

Пр. Абылай хана, 2/1, 010008, Астана

Ilya V. Korolkov - Ph. D. (Engineering), Head of the Laboratory.

2/1, Abylaikhan Ave., 010008, Astana

korolkovelf@gmail.comКозловскийА. Л.KozlovskyiA. L.

Козловский Артем Леонидович - кандидат технических наук, зав. лабораторией Астанинский филиал Институт ядерной физики (

Пр. Абылай хана, 2/1, 010008, Астана

Artem L. Kozlovskiy - Ph. D. (Engineering), Acting Head of the Laboratory.

2/1, Abylaikhan Ave., 010008, Astana

artem88sddt@mail.ruЗдоровецМ. В.ZdorovetsM. V.

Здоровец Максим Викторович - кандидат физико-математических наук, руководитель лаборатории инженерного профиля.

Пр. Абылай хана, 2/1, 010008, Астана

Maxim V. Zdorovets - Ph. D. (Physics and Mathematics), Head of the Laboratory.

2/1, Abylaikhan Ave., 010008, Astana

mzdorovets@gmail.comБундюковаВ. Д.BundyukovaV. D.

Бундюкова Виктория Дмитриевна - младший научный сотрудник.

Ул. П. Бровки, 19, 220072, Минск

Victoria D. Bundyukova - Junior Researcher.

victoria.bundyukova@gmail.comЯкимчукД. В.YakimchukD. V.

Якимчук Дмитрий Владимирович - старший научный сотрудник.

Ул. П. Бровки, 19, 220072, Минск

Dmitry V. Yakimchuk - Leading Researcher.

19, P. Brovka Str., 220072, Minsk

dim2yakim@gmail.comКанюковЕ. Ю.KaniukovE. Yu.

Канюков Егор Юрьевич - старший научный сотрудник.

Ленинский пр-т., 4, 119049, Москва

Egor Yu. Kaniukov - Senior Researcher.

ka.egor@mail.ruИнститут химии новых материалов, Национальная академия наук БеларусиInstitute of Chemistry of New Materials, National Academy of Science of BelarusАстанинский филиал института ядерной физикиAstana branch of the Institute of Nuclear PhysicsЕвразийский национальный университет им. Л.Н. ГумилеваL.N. Gumilyov Eurasian National UniversityНаучно-практический центр, Национальная академия наук Беларуси по материаловедениюScientific and Practical Materials Research Center, National Academy of Sciences of BelarusНациональный исследовательский технологический университет МИСиСResearch Technological University MISiS202004122020564399407Copyright © Шумская Е.Е., Рогачев А.А., Агабеков В.Е., Довыденко Е.М., Петкевич А.В., Корольков И.В., Козловский А.Л., Здоровец М.В., Бундюкова В.Д., Якимчук Д.В., Канюков Е.Ю., 20202020Шумская Е.Е., Рогачев А.А., Агабеков В.Е., Довыденко Е.М., Петкевич А.В., Корольков И.В., Козловский А.Л., Здоровец М.В., Бундюкова В.Д., Якимчук Д.В., Канюков Е.Ю.Shumskaya E.E., Rogachev A.A., Agabekov V.E., Dovydenko E.М., Petkevich A.V., Korolkov I.V., Kozlovskyi A.L., Zdorovets M.V., Bundyukova V.D., Yakimchuk D.V., Kaniukov E.Y.Данная работа распространяется под лицензией Creative Commons Attribution 4.0.This work is licensed under a Creative Commons Attribution 4.0 License.https://vestichem.belnauka.by/jour/article/view/611

С использованием простого двухстадийного метода, включающего электрохимический синтез Ni нанотрубок в порах ПЭТФ-мембран и их покрытие золотом или платиной химическим методом, синтезированы нанотрубки со структурой типа «магнитное ядро-оболочка из благородного металла». Морфология покрытия представляет собой тонкие постоянные пленки с наростами различной формы. Рентгеноструктурный анализ выявил отдельные фазы никеля (ядро) и благородного металла (покрытие). Магнитные свойства покрытых нанотрубок существенно не отличаются от свойств исходных нанотрубок. Метод позволяет синтезировать одномерные наноструктуры типа «магнитное ядро-оболочка из благородного металла» для применения при детектировании химических и биологических соединений, в качестве магнитных носителей при доставке лекарств и генов, а также могут быть использованы в качестве многоциклических катализаторов на магнитном носителе.

Using a simple two-stage method including the electrochemical synthesis of Ni nanotubes in the pores of PET membranes and their coating with gold or platinum, nanotubes with a structure of the «magnetic core - noble metal shell» type have been synthesized. The morphology of the coating is a thin continuous film with growths of various shapes. X-ray diffraction analysis estimated separate phases of nickel (core) and noble metal (coating). The magnetic properties of coated nanotubes do not differ significantly from the properties of the initial nanotubes. The method allows one to synthesize structures such as one-dimensional nanostructures of the «magnetic core - noble metal shell» type for use in the detection of chemical and biological compounds, as magnetic carriers for the delivery of drugs and genes, which can also be used as multicyclic catalysts on a magnetic carrier.

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The authors declare that there are no conflicts of interest present.