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<article article-type="research-article" dtd-version="1.3" xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xml:lang="ru"><front><journal-meta><journal-id journal-id-type="publisher-id">vestich</journal-id><journal-title-group><journal-title xml:lang="ru">Известия Национальной академии наук Беларуси. Серия химических наук</journal-title><trans-title-group xml:lang="en"><trans-title>Proceedings of the National Academy of Sciences of Belarus, Chemical Series</trans-title></trans-title-group></journal-title-group><issn pub-type="ppub">1561-8331</issn><issn pub-type="epub">2524-2342</issn><publisher><publisher-name>The Republican Unitary Enterprise Publishing House "Belaruskaya Navuka"</publisher-name></publisher></journal-meta><article-meta><article-id custom-type="elpub" pub-id-type="custom">vestich-69</article-id><article-categories><subj-group subj-group-type="heading"><subject>Research Article</subject></subj-group><subj-group subj-group-type="section-heading" xml:lang="ru"><subject>ФИЗИЧЕСКАЯ ХИМИЯ</subject></subj-group><subj-group subj-group-type="section-heading" xml:lang="en"><subject>PHYSICAL CHEMISTRY</subject></subj-group></article-categories><title-group><article-title>Кинетика формирования наночастиц серебра в среде полиэтиленгликоля 400</article-title><trans-title-group xml:lang="en"><trans-title>Kinetics of silver nanoparticle formation in (poly)ethylene glycol 400</trans-title></trans-title-group></title-group><contrib-group><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Плиско</surname><given-names>Т. В.</given-names></name><name name-style="western" xml:lang="en"><surname>Plisko</surname><given-names>T. V.</given-names></name></name-alternatives><email xlink:type="simple">noemail@neicon.ru</email><xref ref-type="aff" rid="aff-1"/></contrib><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Бильдюкевич</surname><given-names>А. В.</given-names></name><name name-style="western" xml:lang="en"><surname>Bildyukevich</surname><given-names>A. V.</given-names></name></name-alternatives><email xlink:type="simple">noemail@neicon.ru</email><xref ref-type="aff" rid="aff-1"/></contrib><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Браницкий</surname><given-names>Г. А.</given-names></name><name name-style="western" xml:lang="en"><surname>Branitski</surname><given-names>G. A.</given-names></name></name-alternatives><email xlink:type="simple">noemail@neicon.ru</email><xref ref-type="aff" rid="aff-2"/></contrib><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Кулак</surname><given-names>А. И.</given-names></name><name name-style="western" xml:lang="en"><surname>Kulak</surname><given-names>A. I.</given-names></name></name-alternatives><email xlink:type="simple">noemail@neicon.ru</email><xref ref-type="aff" rid="aff-3"/></contrib></contrib-group><aff xml:lang="ru" id="aff-1"><institution>Институт физико-органической химии НАН Беларуси</institution><country>Belarus</country></aff><aff xml:lang="ru" id="aff-2"><institution>НИИ физико-химических проблем БГУ</institution><country>Belarus</country></aff><aff xml:lang="ru" id="aff-3"><institution>Институт общей и неорганической химии НАН Беларуси</institution><country>Belarus</country></aff><pub-date pub-type="collection"><year>2014</year></pub-date><pub-date pub-type="epub"><day>08</day><month>06</month><year>2016</year></pub-date><volume>0</volume><issue>4</issue><fpage>26</fpage><lpage>31</lpage><permissions><copyright-statement>Copyright &amp;#x00A9; Плиско Т.В., Бильдюкевич А.В., Браницкий Г.А., Кулак А.И., 2016</copyright-statement><copyright-year>2016</copyright-year><copyright-holder xml:lang="ru">Плиско Т.В., Бильдюкевич А.В., Браницкий Г.А., Кулак А.И.</copyright-holder><copyright-holder xml:lang="en">Plisko T.V., Bildyukevich A.V., Branitski G.A., Kulak A.I.</copyright-holder><license xml:lang="ru" license-type="creative-commons-attribution" xlink:href="https://creativecommons.org/licenses/by/4.0/" xlink:type="simple"><license-p>Данная работа распространяется под лицензией Creative Commons Attribution 4.0.</license-p></license><license xml:lang="en" license-type="creative-commons-attribution" xlink:href="https://creativecommons.org/licenses/by/4.0/" xlink:type="simple"><license-p>This work is licensed under a Creative Commons Attribution 4.0 License.</license-p></license></permissions><self-uri xlink:href="https://vestichem.belnauka.by/jour/article/view/69">https://vestichem.belnauka.by/jour/article/view/69</self-uri><abstract><p>Проведено исследование кинетических особенностей образования наночастиц серебра при взаимодействии нитрата серебра с полиэтиленгликолем 400 различных производителей (Aldrich, BASF, BioChemica и Fluka), поведение образцов которого существенно различается в данном процессе. Выявлены отличия в начальной скорости процесса взаимодействия полиэтиленгликолей различных производителей с ионами серебра. Установлено, что для аппроксимации кинетических кривых для полиэтиленгликолей производства Aldrich, BASF и Fluka наилучшие результаты достигаются при использовании сигмоидальной функции Больцмана, а для полиэтиленгликоля производства BioChemica - уравнения обратного экспоненциального роста.</p></abstract><trans-abstract xml:lang="en"><p>Kinetics of silver nanoparticle formation in the reaction between silver nitrate and (poly)ethylene glycol 400 produced by Aldrich, BASF, BioChemica and Fluka has been studied. It has been found that different polyethylene glycol samples show significant variations of behavior in this process. The initial rate of (poly)ethylene glycol reaction with silver ions has been found to vary broadly when (poly)ethylene glycol samples of different manufacturers are used. It has been shown that kinetic curves of the (poly)ethylene glycols produced by Aldrich, BASF and Fluka can be fitted by Boltzmann sigma function while the kinetic curve of (poly)ethylene glycol produced by BioChemica can be fitted by reversed exponential growth equation.</p></trans-abstract></article-meta></front><back><ref-list><title>References</title><ref id="cit1"><label>1</label><citation-alternatives><mixed-citation xml:lang="ru">Moritz M., Geszke-Moritz M. // Chemical Engineering Journal. 2013. Vol. 228. P. 596-613.</mixed-citation><mixed-citation xml:lang="en">Moritz M., Geszke-Moritz M. // Chemical Engineering Journal. 2013. Vol. 228. P. 596-613.</mixed-citation></citation-alternatives></ref><ref id="cit2"><label>2</label><citation-alternatives><mixed-citation xml:lang="ru">Shameli K., Ahmad M. B., Jazayeri S. D. // International Journal of Molecular Science. 2012. Vol. 13. P. 6639-6650.</mixed-citation><mixed-citation xml:lang="en">Shameli K., Ahmad M. B., Jazayeri S. 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