vestichИзвестия Национальной академии наук Беларуси. Серия химических наукProceedings of the National Academy of Sciences of Belarus, Chemical Series1561-83312524-2342The Republican Unitary Enterprise Publishing House "Belaruskaya Navuka"10.29235/1561-8331-2022-58-3-263-272vestich-736Research ArticleНЕОРГАНИЧЕСКАЯ ХИМИЯINORGANIC CHEMISTRYФормирование октакальцийфосфата при взаимодействии карбоната кальция и монокальцийфосфата моногидрата в гальваностатических условияхFormation of octacalcium phosphate in the interaction of calcium carbonate and monocalcium phosphate monohydrate under galvanostatic conditionsКрутькоВ. К.Krut’koV. K.

Крутько Валентина Константиновна – кандидат химических наук, доцент, заведующий лабораторией.

Ул. Сурганова, 9/1, 220072, Минск

Krut’ko Valentina K. – Ph. D. (Chemistry), Associate professor, Head of the Laboratory.

9/1, Surganov str., 220072, Minsk

tsuber@igic.bas-net.byДорошенкоА. Е.DoroshenkoA. E.

Дорошенко Анна Евгеньевна – аспирант, младший научный сотрудник.

Ул. Сурганова, 9/1, 220072, Минск

Doroshenko Anna E. – Ph. D. student, Junior researcher.

9/1, Surganov str., 220072, Minsk

tsuber@igic.bas-net.byМусскаяО. Н.MusskayaO. N.

Мусская Ольга Николаевна – кандидат химических наук, доцент, ведущий научный сотрудник.

Ул. Сурганова, 9/1, 220072, Минск

Musskaya Olga N. – Ph. D. (Chemistry), Associate professor, Leading researcher.

9/1, Surganov str., 220072, Minsk

musskaja@igic.basnet.byРабчинскийС. М.RabchynskiS. M.

Рабчинский Сергей Михайлович – кандидат химических наук, доцент.

Пр-т Независимости, 4, 220030, Минск

Rabchinsky Sergey M. – Ph. D. (Chemistry), Associate 0professor.

4, Nezavisimosti ave., 220030, Minsk

rabchinskij_sm@tut.byКулакА. И.KulakA. I.

Кулак Анатолий Иосифович – академик НАН Беларуси, доктор химических наук, профессор, директор.

Ул. Сурганова, 9/1, 220072, Минск

Kulak Anatoly I. – Academician of the National Academy of Sciences of Belarus, D. Sc. (Chemistry), Professor, Director.

9/1, Surganov str., 220072, Minsk

kulak@igic.bas-net.byИнститут общей и неорганической химии, Национальная академия наук БеларусиInstitute of General and Inorganic Chemistry, National Academy of Sciences of BelarusБелорусский государственный университетBelarusian State University202207092022583263272Copyright © Крутько В.К., Дорошенко А.Е., Мусская О.Н., Рабчинский С.М., Кулак А.И., 20222022Крутько В.К., Дорошенко А.Е., Мусская О.Н., Рабчинский С.М., Кулак А.И.Krut’ko V.K., Doroshenko A.E., Musskaya O.N., Rabchynski S.M., Kulak A.I.Данная работа распространяется под лицензией Creative Commons Attribution 4.0.This work is licensed under a Creative Commons Attribution 4.0 License.https://vestichem.belnauka.by/jour/article/view/736

Кальцийфосфатный композит октакальцийфосфат/кальцит получали в водной среде при pH 5–7 из суспензии CaCO3/Ca(H2PO4)2 в гальваностатическом режиме при плотности тока 20 мА/см2 в течение 20 мин. Высушивание при 80 °C без стадии созревания осадка приводило к получению порошка, состоящего из брушита, кальцита и малого количества октакальцийфосфата. Длительное созревание на воздухе (2 мес.) приводило к гидролитической трансформации брушита в октакальцийфосфат, стабилизированный кальцитом. Использование электрического тока позволило увеличить количество октакальцийфосфата в составе композитного порошка с морфологией пластинчатых розеток. Термообработка при 800 °C композитных порошков приводила к формированию α/β-трикальцийфосфата, β-пирофосфата кальция, гидроксиапатита и оксида кальция.

The calcium phosphate composite octacalcium phosphate / calcite was obtained at pH 5–7 from the CaCO3/Ca(H2PO4)2 aqueous suspension in a galvanostatic mode at a current density of 20 mA/cm2 for 20 min. Drying at 80 °C without the precipitate maturation stage led to a powder formation consisting of brushite, calcite and a small amount of octacalcium phosphate. Prolonged maturation in air for 2 months led to the hydrolytic transformation of brushite into octacalcium phosphate stabilized by calcite. The use of electric current made it possible to increase the amount of octacalcium phosphate in the composite powder with the morphology of lamellar rosettes. Calcination at 800 °C of the composite powders led to the formation of α/β-tricalcium phosphate, β-calcium pyrophosphate, hydroxyapatite, and calcium oxide.

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The authors declare that there are no conflicts of interest present.