References

vestich

Известия Национальной академии наук Беларуси. Серия химических наук

Proceedings of the National Academy of Sciences of Belarus, Chemical Series

1561-83312524-2342

The Republican Unitary Enterprise Publishing House "Belaruskaya Navuka"

10.29235/1561-8331-2023-59-1-78-88

vestich-792

Research Article

ТЕХНИЧЕСКАЯ ХИМИЯ И ХИМИЧЕСКАЯ ТЕХНОЛОГИЯ

TECHNICAL CHEMISTRY AND CHEMICAL ENGINEERING

Теплота сгорания сельскохозяйственной биомассы: базовое значение и интервалы для отдельных видов

Heating value of agricultural biomass: the basic value and intervals for certain types

Максимук

Ю. В.

Maksimuk

Yu. V.

Максимук Юрий Владимирович – канд. хим. наук,доцент, вед. науч. сотрудник

ул. Ленинградская, 14, 220006, Минск

Maksimuk Yury V. – Ph. D. (Chemistry), Associate Professor, Leading Researcher

14, Leningradskaya Str, 220006, Minsk

maksimuk@bsu.by

Курсевич

В. Н.

Kursevich

V. N.

Курсевич Вера Николаевна – науч. сотрудник

ул. Ленинградская, 14, 220006, Минск

Kursevich Vera N. – Researcher

14, Leningradskaya Str, 220006, Minsk

kursevich@bsu.by

Корсакова

А. С.

Korsakova

A. S.

Корсакова Алина Сергеевна – мл. науч. сотрудник

ул. Ленинградская, 14, 220006, Минск

Korsakova Alina S. – Junior Researcher

14, Leningradskaya Str, 220006, Minsk

a.korsakova96@mail.ru

Антонова

М. В.

Antonova

M. V.

Антонова Мария Викторовна – канд. биол. наук, ст.науч. сотрудник

ул. Ленинградская, 14, 220006, Минск

Antonova Maria V. – Ph. D. (Biology), Senior Researcher

14, Leningradskaya Str, 220006, Minsk

mariantonova@gmail.com

Крук

В. С.

Krouk

V. S.

Крук Владимир Сергеевич – канд. хим. наук, науч.сотрудник

ул. Ленинградская, 14, 220006, Минск

Krouk Vladimir S. – Ph. D. (Chemistry), Researcher

14, Leningradskaya Str, 220006, Minsk

krouk@bsu.by

Научно-исследовательский институт физико-химических проблем БГУResearch Institute for Physical Chemical Problems of the Belarusian State University

2023

07032023

5917888

2023

Максимук Ю.В., Курсевич В.Н., Корсакова А.С., Антонова М.В., Крук В.С.

Maksimuk Y.V., Kursevich V.N., Korsakova A.S., Antonova M.V., Krouk V.S.

Данная работа распространяется под лицензией Creative Commons Attribution 4.0.

This work is licensed under a Creative Commons Attribution 4.0 License.

https://vestichem.belnauka.by/jour/article/view/792

Высшая теплота сгорания (ВТС) в пересчете на сухое и oбеззольное состояние (daf) является удобной платформой для сравнения энергоемкости различных видов сельскохозяйственной биомассы. Экспериментально определены ВТС и зольность для 90 образцов соломы, семян, лузги, шрота и т.д. На основании литературных данных рассчитаны значения ВТСdaf для 80 образцов из разных регионов. Предложено базовое значение ВТСdaf сельскохозяйственной биомассы равное 19,6 МДж кг-1 для верификации данных по твердому биотопливу. Установлены интервалы варьирования ВТСdaf для свекловичного жома, соломы, шрота, льнокостры и лузги подсолнечника. Обсуждены отклонения ВТСdaf от базового значения и интервалов варьирования для отдельных видов сельскохозяйственной биомассы.

Higher heating value (HHV) on a dry and ash free basis (daf) is a convenient platform for comparing the energy content in various types of agricultural biomass. HHV and ash content for 90 samples of straw, seed, husk, meal, its waste, etc. were experimentally determined. HHVdaf for 80 samples from different regions were calculated by the literature data. The basic value of HHVdaf agricultural biomass at 19.6 MJ kg–1 was recommended for verifying data on solid biofuels. The intervals of variation of HHVdaf for sugar beet pulp, straw, meal, flax shives and sunflower husk are established. The deviations from the base value of HHVdaf and from intervals of variation of HHVdaf for certain types of agricultural biomass are discussed.

высшая теплота сгораниясельскохозяйственная биомассасоломажом сахарной свеклыльнокостралузга подсолнечника

higher heating valueagricultural biomassstrawsugar beet pulpflax shivessunflower husk

References1

Godin B., Lamaudière S., Agneessens R., Schmit T., Goffart J. P., Stilmant D., Gerin P. A., Delcarte J. Chemical composition and biofuel potentials of a wide diversity of plant biomasses. Energy and Fuels, 2013, vol. 27, no. 5, pp. 2588–2598. https://doi.org/10.1021/ef3019244

Montero G., Coronado M. A., Torres R., Jaramillo B. E., García C., Stoytcheva M., Vázquez A. M., León J. A., Lambert A. A., Valenzuela E. Higher heating value determination of wheat straw from Baja California, Mexico. Energy, 2016, vol. 109, pp. 612–619. https://doi.org/10.1016/j.energy.2016.05.011

Demirbaş A. Calculation of higher heating values of biomass fuels. Fuel, 1997, vol. 76, no. 5, pp. 431–434. https://doi.org/10.1016/S0016-2361(97)85520-2

Demirbaş A. Relationships between lignin contents and heating values of biomass. Energy Conversion Management, 2001, vol. 42, no. 2, pp. 183–188. https://doi.org/10.1016/S01968904(00)00050-9

Naik S., Goud V. V., Rout P. K., Jacobson K., Dalai A. K. Characterization of Canadian biomass for alternative renewable biofuel. Renewable Energy, 2010, vol. 35, no. 8, pp. 1624–1631. https://doi.org/10.1016/j.renene.2009.08.033

Gravalos I., Xyradakis P., Kateris D., Gialamas T., Bartzialis D., Giannoulis K. An experimental determination of gross calorific value of different agroforestry species and bio-based industry residues. Natural Resources, 2016, vol. 7, no. 1, pp. 57–68. https://doi.org/10.4236/nr.2016.71006

García R., Pizarro C., Lavín A.G., Bueno J. L. Characterization of Spanish biomass wastes for energy use. Bioresource Technology, 2012, vol. 103, no. 1, pp. 249–258. https://doi.org/10.1016/j.biortech.2011.10.004

Suárez J. A., Luengo C. A., Felfli F. F., Bezzon G., Beatón P. A. Thermochemical properties of Cuban biomass. Energy Sources, 2000, vol. 22, no. 10, pp. 851–857. https://doi.org/10.1080/00908310051128156

Enes T., Aranha J., Fonseca T., Lopes D., Alves A., Lousada J. Thermal properties of residual agroforestry biomass of Northern Portugal. Energies, 2019, vol. 12, no. 8, pp. 1418. https://doi:10.3390/en12081418

Wang X., Yang Z., Liu X., Huang G., Xiao W., Han L. The composition characteristics of different crop straw types and their multivariate analysis and comparison. Waste Management, 2020, vol. 110, pp. 87–97. https://doi.org/10.1016/j.wasman.2020.05.018

Singh H., Sapra P. K., Sidhu B. S. Evaluation and characterization of different biomass residues through proximate and ultimate analysis and heating value. Asian Journal Engineering and Applied Technology, 2013, vol. 2, no. 2, pp. 6–10.

Prem Ananth Surendran C., Shanmugam P. Correlation between empirical formulae based stoichiometric and experimental methane potential and calorific energy values for vegetable solid wastes. Energy Reports, 2021, vol. 7, pp. 19–31. https://doi.org/10.1016/j.egyr.2020.10.071

Adapa P., Tabil L., Schoenau G., Opoku A. Pelleting characteristics of selected biomass with and without steam explosion pretreatment. International Journal Agricultural and Biological Engineering, 2010, vol. 3, no. 3, pp. 62–79. https://doi.org/10.3965/j.issn.1934-6344.2010.03.062-079

Danish M., Naqvi M., Farooq U., Naqvi S. Characterization of South Asian agricultural residues for potential utilization in future ‘energy mix’. Energy Procedia, 2015, vol. 75, pp. 2974–2980. https://doi.org/10.1016/j.egypro.2015.07.604

Demirbas A., Gullu D., Çaglar A., Akdeniz F. Estimation of calorific values of fuels from lignocellulosics. Energy Sources, 1997, vol. 19, no. 8, pp. 765–770. https://doi.org/10.1080/00908319708908888

Parikh J., Channiwala S. A., Ghosal G. K. A correlation for calculating HHV from proximate analysis of solid fuels. Fuel, 2005, vol. 84, no. 5, pp. 487–494. https://doi.org/10.1016/j.fuel.2004.10.010

Channiwala S. A., Parikh P. P. A unified correlation for estimating HHV of solid, liquid and gaseous fuels. Fuel, 2002, vol. 81, no. 8, pp. 1051–1063. https://doi.org/10.1016/S00162361(01)00131-4

Ebeling J. M., Jenkins B. M. Physical and chemical properties of biomass fuels. Transaction of the American Society of Agricultural Engineers (ASAE), 1985, vol. 28, no. 3, pp. 898–902. https://doi.org/10.13031/2013.32359

Gaur S., Reed T. B. Thermal Data for Natural and Synthetic Fuels. New York: Marcel Dekker Inc., 1998.

Ioelovich M. Y. Study of thermal energy of alternative solid fuels. Izvestiya Vuzov. Prikladnaya Khimiya i Biotekhnologiya = Proceedings of Universities. Applied Chemistry and Biotechnology, 2018, vol. 8, no. 4, pp. 117–124. http:// doi.org/10.21285/2227-2925-2018-8-4-117-124

Blunk S. L., Jenkins B. M. Combustion properties of lignin residue from lignocelluloses fermentation. CA, Davis: University of California., 2000, pp. 1385–1391.

Trinh T. N. Jensen P. A., Dam-Johansen K., Knudsen N. O., Sørensen H. R., Hvilsted S. Comparison of lignin, macroalgae, wood, and straw fast pyrolysis. Energy and Fuels, 2013, vol. 27, no. 3, pp. 1399–1409. https://doi.org/10.1021/ef301927y

Ryeztsov V. F., Matvejchyk A. C., Chernyavskij N. V., Rudavina E. V. Experimental research of mineral composition of straw and husks on their thermal performance. Alternativnaya Energetika i Ekologiya = Alternative Energy and Ecology, 2012, vol. 7, pp. 94–100 (in Russian).

Bychkov A. L., Denkin A. I., Tikhova V. D., Lomovsky O. I. Prediction of higher heating values of plant biomass from ultimate analysis data. J. Thermal Analysis and Calorimetry, 2017, vol. 130, no. 3, pp. 1399–1405. https://doi.org/10.1007/s10973-017-6350-0

Bychkov A. L., Denkin A. I., Tihova V. D., Lomovsky O. I. Prediction of higher heating values of lignocellulose from elemental analysis. Khimija Rastitel'nogo Syr'ja = Chemistry of Plant Raw Material, 2014, no. 3, pp. 99–104 (in Russian). https://doi.org/10.14258/jcprm.1403099

Phayom W., Umezaki C., Tanaka M. Relationships between major constituents, storage conditions, and higher heating values of rice straw. Engineering in Agriculture, Environment and Food, 2012, vol. 5, no. 2, pp. 76–82. https://doi.org/10.1016/S1881-8366(12)80018-8

Chaloupková V., Ivanova T., Hutla P., Špunarová M. Ash melting behavior of rice straw and calcium additives. Agriculture, 2021, vol. 11, no. 12, p. 1282. https://doi.org/10.3390/agriculture11121282

Tortosa Masiá A. A., Buhre B. J. P., Gupta R. P., Wall T. F. Characterising ash of biomass and waste. Fuel Processing Technology, 2007, vol. 88, no. 11–12, pp. 1071–1081. https://doi.org/10.1016/j.fuproc.2007.06.011

Bradna J., Malaťák J., Velebil J. Impact of differences in combustion conditions of rape straw on the amount of flue gases and fly ash properties. Agronomy Research, 2017, vol. 15, no. 3, pp. 649– 657.

Górnicki K., Kaleta A., Winiczenko R. Prediction of higher heating value of oat grain and straw biomass. ICoRES 2019 in E3S Web of Conferences, 2020, vol. 154, no. 01003, p. 1–7. https://doi.org/10.1051/e3sconf/202015401003

Virmond E., De Sena R. F., Albrecht W., Althoff C. A., Moreira R. F. P. M., José H. J. Characterisation of agroindustrial solid residues as biofuels and potential application in thermochemical processes. Waste Management, 2012, vol. 32, no. 10, pp. 1952–1961. https://doi.org/10.1016/j.wasman.2012.05.014

Mata-Sánchez J., Pérez-Jiménez J. A., Díaz-Villanueva M. J., Serrano A., Núñez-Sánchez N., López-Giménez F. J. Statistical evaluation of quality parameters of olive stone to predict its heating value. Fuel, 2013, vol. 113, pp. 750–756. https://doi.org/10.1016/j.fuel.2013.06.019

Maksimuk Yu., Ponomarev D., Sushkova A., Krouk V., Vasarenko I., Antonava Z. Standard molar enthalpy of formation of vanillin. Journal of the Thermal Analysis and Calorimetry, 2018, vol. 131, no. 2, pp. 1721–1733. https://doi.org/10.1007/s10973-017-6651-3

Korchagina E. N. Metrological characteristics of K-1 and K-3 reference benzoic acids. Measerement Techniques, 2001, vol. 44, no. 11, pp. 1138–1142. https://doi.org/10.1023/A:1014021519763

Bogolitsyn K. G., Gusakova M. A., Krasikova A. A. Molecular self-organization of wood lignin–carbohydrate matrix. Planta, 2021, vol. 254, no. 30, pp. 1–21. https://doi.org/10.1007/s00425021-03675-4

Maksimuk Yu. V., Ponomarev D. A., Kursevich V. N., Fes’ko V. V. Calorific value of wood fuel. Lesnoy zhurnal = Forestry journal, 2017, vol. 4, pp. 116–129 (in Russian). https://doi.org/10.17238/issn0536-1036.2017.4.116

Peduzzi E., Boissonnet G., Maréchal F. Biomass modelling: Estimating thermodynamic properties from the elemental composition. Fuel, 2016, vol. 181, pp. 207–217. https://doi.org/10.1016/J.FUEL.2016.04.111

Galhano dos Santos R., Bordado J. C., Mateus M. M. Estimation of HHV of lignocellulosic biomass towards hierarchical cluster analysis by Euclidean’s distance method. Fuel, 2018, vol. 221, pp. 72–77. https://doi.org/10.1016/j.fuel.2018.02.092

Huang C., Han L., Liu X., Yang Z. Models predicting calorific value of straw from the ash content. International Journal Green Energy, 2008, vol. 5, no. 6, pp. 533–539. https://doi.org/10.1080/15435070802498507

Jain A. K. Correlation models for predicting heating value through biomass characteristics. Journal of Agricultural Engineering, 1997, vol. 34, no. 3, pp. 12–25.

Sheng C., Azevedo J. L. T. Estimating the higher heating value of biomass fuels from basic analysis data. Biomass and Bioenergy, 2005, vol. 28, no. 5, pp. 499–507. https://doi.org/10.1016/J.BIOMBIOE.2004.11.008

Callejón-Ferre A. J., Velázquez-Martí B., López-Martínez J. A., Manzano-Agugliaro F. Greenhouse crop residues: Energy potential and models for the prediction of their higher heating value. Renewable and Sustainable Energy Reviews, 2011, vol. 15, no. 2, pp. 948–955. https://doi.org/10.1016/J.RSER.2010.11.012

Maksimuk Yu., Antonava Z., Krouk V., Korsakova A., Kursevich V. Prediction of higher heating value (HHV) based on the structural composition for biomass. Fuel, 2021, vol. 299, no. 120860, pp. 1–7. https://doi.org/10.1016/j.fuel.2021.120860

Vassilev S. V., Baxter D., Andersen L. K., Vassileva C. G., Morgan T. J. An overview of the organic and inorganic phase composition of biomass. Fuel, 2012, vol. 94. pp. 1–33. https://doi.org/10.1016/j.fuel.2011.09.030

Maksimuk Yu. V., Antonova Z. A., Fes’ko V. V., Kursevich V. N. Diesel biofuel viscosity and heat of combustion. Chemistry and Technology of Fuels and Oils, 2009, vol. 45, no. 5, pp. 343–348. https://doi.org/10.1007/s10553-009-0147-1

Kienzle E., Schrag I., Butterwick R., Opitz B. Calculation of gross energy in pet foods: new data on heat combustion and fibre analysis in a selection of foods for dogs and cats. Journal Animal Physiology and Animal Nutrition, 2001, vol. 85, no. 5–6, pp. 148–157. https://doi.org/10.1046/j.14390396.2001.00311.x

The authors declare that there are no conflicts of interest present.