vestichИзвестия Национальной академии наук Беларуси. Серия химических наукProceedings of the National Academy of Sciences of Belarus, Chemical Series1561-83312524-2342The Republican Unitary Enterprise Publishing House "Belaruskaya Navuka"10.29235/1561-8331-2023-59-2-105-114vestich-809Research ArticleФИЗИЧЕСКАЯ ХИМИЯPHYSICAL CHEMISTRYКаталитическая активность Co, Cu, Mn оксидных катализаторов, полученных золь-гель методом с горением, в реакции низкотемпературного окисления оксида углеродаCatalytic activity of Co, Cu and Mn oxide catalysts synthesized by the sol-gel combustion method in the low-temperature oxidation of carbon oxideЗульфугароваС. М.ZulfugarovaS. M.

Зульфугарова Сима Мамед гызы – канд. хим. наук,зав. лаб.

пр. Г. Джавида, 113, AZ1143, Баку

Zulfugarova Sima Mamed – Ph. D. (Chemistry), Headof the Laboratory

113, H. Javid Ave., AZ1143, Baku

zsm07@mail.ruАзимоваГ. Р.AzimovaG. R.

Азимова Гюнель Рамиз гызы – науч. сотрудник

пр. Г. Джавида, 113, AZ1143, Баку

Azimova Gunel Ramiz – Researcher

113, H. Javid Ave., AZ1143, Baku

АлескероваЗ. Ф.AleskeroivaZ. F.

Алескерова Зулейха Фикрет гызы – науч. сотрудникпр. Г. Джавида, 113, AZ1143, Баку

 

Aleskeroiva Zuleyxa Fikret – Researcher

113, H. Javid Ave., AZ1143, Baku

ГусейнлиГ. М.GuseinliG. M.

Гусейнли Горхмаз Мансур оглы – канд. хим. наук,зав. лаб.

пр. Г. Алиева, 35, AZ7000, Нахчыван

Guseinli Gorkhmaz Mansur – Ph. D. (Chemistry), Headof the Laboratory

35, G. Aliyev Ave., AZ7000, Naxchivan

ТагиевД. Б.TagiyevD. B.

Тагиев Дилгам Бабир оглы – академик НАН Азербайджана, д-р хим. наук, профессор, директор

пр. Г. Джавида, 113, AZ1143, Баку

Tagiyev Dilgam Babir – Academician, D. Sc. (Chemistry), Professor. Director

113, H. Javid Ave., AZ1143, Baku

Институт катализа и неорганической химии Национальной академии наук АзербайджанаInstitute of Catalysis and Inorganic ChemistryИнститут природных ресурсов Национальной академии наук АзербайджанаInstitute of Natural Resources202303062023592105114Copyright © Зульфугарова С.М., Азимова Г.Р., Алескерова З.Ф., Гусейнли Г.М., Тагиев Д.Б., 20232023Зульфугарова С.М., Азимова Г.Р., Алескерова З.Ф., Гусейнли Г.М., Тагиев Д.Б.Zulfugarova S.M., Azimova G.R., Aleskeroiva Z.F., Guseinli G.M., Tagiyev D.B.Данная работа распространяется под лицензией Creative Commons Attribution 4.0.This work is licensed under a Creative Commons Attribution 4.0 License.https://vestichem.belnauka.by/jour/article/view/809

Осуществлен синтез катализаторов на основе оксидов кобальта, меди и марганца золь-гель методом с горением и изучена их каталитическая активность в реакции низкотемпературного окисления монооксида углерода в диоксид. Синтезированы оксиды кобальта, меди и марганца, а также их двойные оксиды Co–Mn, Cu–Mn и Co–Cu. Рентгенофазовым анализом показано образование в системах Co–Mn и Cu–Mn манганитов и оксидов соответствующих металлов. В системе Co–Cu выявлено образование только оксидов этих металлов. Установлено, что кобальти медь-марганцевые оксидные системы, синтезированные золь-гель методом с горением, проявляют высокую каталитическую активность в низкотемпературном (110–140 °С) превращении монооксида углерода в диоксид. Осуществлен одностадийный синтез каталитической системы Cu–Mn/Al2O3 золь-гель методом со сжиганием прекурсоров с гидрогелем связующего (Al2O3) и установлена ее высокая активность в низкотемпературной конверсии монооксида углерода. Каталитические системы исследовали РФ-, ИК-спектральными методами, БЭТ, СЭМ. Полученные результаты показывают возможность получения активных в низкотемпературном окислении монооксида углерода многокомпонентных оксидных катализаторов технологически простым золь-гель методом с горением. 

The synthesis of catalysts based on cobalt, copper and manganese oxides by sol-gel method with combustion was carried out, and their catalytic activity was studied in the reaction of low-temperature oxidation of carbon monoxide to dioxide. Oxides of cobalt, copper and manganese, as well as their double oxides (Co–Mn, Cu–Mn and Co–Cu) were synthesized. X-ray phase analysis showed the formation of manganites and oxides of corresponding metals in the Co–Mn and Cu–Mn systems. It was revealed that in the Co–Cu system only oxides of separate metals are formed. It was found that cobaltmanganese and copper-manganese oxide systems synthesized by sol-gel combustion method exhibit high catalytic activity in the low-temperature (110–140 0C) conversion of carbon monoxide into dioxide. One-step synthesis of Cu–Mn/Al2O3 catalytic system was also carried out by sol-gel method with burning precursors with binder hydrogel (Al2O3), and its high activity in low-temperature conversion of carbon monoxide was revealed. The catalytic systems were investigated by X-ray diffraction, IR spectral methods, BET, SEM. The results obtained show the possibility of obtaining active multicomponent oxide catalysts in low-temperature oxidation of carbon monoxide by technologically simple sol-gel combustion method. 

монооксид углероданизкотемпературное окислениезоль-гель метод с горениемоксидные катализаторыcarbon monoxidelow-temperature oxidationcombustion sol-gel methodoxide catalystsReferencesRoyer, S. Catalytic oxidation of carbon monoxide over transition metal oxides / S. Royer, D. Duprez // ChemCataChem. – 2011. – Vol. 3, N 1. – P. 24–65. https://doi.org/10.1002/cctc.201000378Royer S., Duprez D. Catalytic oxidation of carbon monoxide over transition metal oxides. ChemCatChem., 2011, vol. 3, pp. 24–65. https://doi.org/10.1002/cctc.201000378Nanocatalysts for Low-Temperature Oxidation of CO: Review / G. G. Xanthopouloua [et al.] // Eurasian Chem.-Technol. J. – 2015. – Vol. 17. – P.17–32.Xanthopouloua G. G., Novikova V. A., Knysha Yu. A., Amosova A. P. Nanocatalysts for Low-Temperature Oxidation of CO: Review. Eurasian Chemico-Technological Journal, 2015, vol. 17, pp. 17–32.Soliman, N. K. Factors affecting CO oxidation reaction over nanosized materials: A review / N. K. Soliman // J. Mat. Res. Technol. – 2019. – Vol. 8, N 2. – P. 2395–2407. https://doi.org/10.1016/j.jmrt.2018.12.012Soliman N. K. Factors affecting CO oxidation reaction over nanosized materials: A review. Journal of Materials Research and Technology, 2019, vol. 8, no. 2, pp. 2395–2407. https://doi.org/10.1016/j.jmrt.2018.12.012Dey, S. Selection of Manganese oxide catalysts for catalytic oxidation of Carbon monoxide at ambient conditions / S. Dey, N. S. Mehta // Res., Environ. Sustainability. – 2020. – Vol. 1. – P. 100003. https://doi.org/10.1016/j.resenv.2020.100003Dey S., Mehta N. S. Selection of Manganese oxide catalysts for catalytic oxidation of Carbon monoxide at ambient conditions. Resources, Environment and Sustainability, 2020, vol. 1, 100003. https://doi.org/10.1016/j.resenv.2020.100003Mahammadunnisa, S. NiO/Ce1−x NixO2−δ as an alternative to noble metal catalysts for CO oxidation / S. Mahammadunnisa, M. K. Reddy, N. Lingaiah // Catal. Sci. Technol. – 2013. – N 3. – P. 730–736. https://doi.org/10.1039/C2CY20641BMahammadunnisa S., Reddy M. K., Lingaiah N. NiO/Ce 1−xNixO2−δ as an alternative to noble metal catalysts for CO oxidation. Catalysis Science & Technology, 2013, no. 3, pp. 730–736. https://doi.org/10.1039/C2CY20641BPrasad, R. A Review on CO Oxidation Over Copper Chromite Catalyst / R. Prasad, P. Singh // Catal. Rewiews: Science and Engineering. – 2012. – Vol. 54, iss. 2. – P. 224–279. https://doi.org/10.1080/01614940.2012.648494Prasad R., Singh P. A Review on CO Oxidation Over Copper Chromite Catalyst . Catalysis Rewiews: Science and Engineering, 2012, vol. 54, iss. 2, pp. 224–279. https://doi.org/10.1080/01614940.2012.648494Aniz, C. U. A study on catalysis by ferrospinels for preventing atmospheric pollution from carbon monoxide / C. U. Aniz, T. D. R. Nair // Open J. Phys. Chem. – 2011. – Vol. 1, N 3. – P. 124–130. https://doi.org/10.4236/ojpc.2011.13017Aniz C. U., Nair T. D. R. A study on catalysis by ferrospinels for preventing atmospheric pollution from carbon monoxide. Open Journal of Physical Chemistry, 2011, vol. 1, no. 3, pp. 124–130. https://doi.org/10.4236/ojpc.2011.13017Молчанов, В. В. Влияние механохимической активации на каталитические свойства ферритов со структурой шпинели / В. В. Молчанов, Р. А. Буянов, Ю. Т. Павлюхин // Кинетика и катализ. – 2003. – Т. 44, N 6. – С. 860–864. https://doi.org/10.1023/B:KICA.0000009055.02997.9cMolchanov V. V., Buyanov R. A., Pavlyukhin Yu. T. Effect of Mechanochemical Activation on the Catalytic Properties of Ferrites with the Spinel Structure. Kinetics and Catalysis, 2003, vol. 44, no. 6, pp. 788–792. https://doi.org/10.1023/B:KICA.0000009055.02997.9cNanosized copper ferrite materials: mechanochemical synthesis and characterization / E. Manova [et al.] // J. Solid State Chem. – 2011. – Vol. 184, iss. 5. – P. 1153–1158. https://doi.org/10.1016/j.jssc.2011.03.035Manova E., Tsoncheva T., Paneva D., Popova M., Velinov N., Kunev B., Tenchev K., Mitov I. Nanosized copper ferrite materials: mechanochemical synthesis and characterization. Journal of Solid State Chemistry, 2011, vol. 184, iss. 5, pp. 1153–1158. https://doi.org/10.1016/j.jssc.2011.03.035Томина, Е. В. Микроволновый синтез ортоферрита иттрия и допирование его никелем / Е. В. Томина, Н. А. Куркин, С. А. Мальцев // Конденсированные среды и межфазные границы. –2019. – Т. 21, N. 2. – С. 306–312. https://doi.org/10.17308/kcmf.2019.21/768Tomina E. V., Kurkin N. A., Mal`tsev S. A. Microwave synthesis of yttrium orthoferrite doped with nickel. Kondensirovannye sredy i mezhfaznye graniczy = Condensed Matter and Interphases, 2019, vol. 21, no. 2, pp. 306–312 (in Russian). https://doi.org/10.17308/kcmf.2019.21/768Микроволновый синтез ферритов (Co, Ni, Cu, Zn) / Ю. Н. Литвишков [и др.] // Журн. прикл. химии. – 2018. – T. 91, N. 5. – C. 679–687.Litvishkov Yu. N., Zul’fugarova S. M., Aleskerova Z. F., Gasangulieva N. M., Shakunova N. V., Aleskerov A. G. Microwave synthesis of Co, Ni, Cu, Zn ferrites. Russian Journal of Applied Chemistry, 2018, vol. 91, no. 5, pp. 793–801. https://doi.org/10.1134/S1070427218050105Рахманкулов, Д. Л. Микроволновое излучение и интенсификация химических процессов / Д. Л. Рахманкулов, И. Х. Бикбулатов. – М.: Химия, 2003. – 220 c.Rakhmankulov D. L., Bikbulatov I. Kh. Microwave radiation and intensification of chemical processes. Мoscow, Khimiya Publ., 2003. 220 p. (in Russian).Ванецев, А. С. Микроволновой синтез индивидуальных и многокомпонентных оксидов / А. С. Ванецев, Ю. Д. Третьяков // Успехи химии. – 2007. – T. 76, N. 5. – C. 435–453.Vanetsev A. S., Tret`yakov Yu. D. Microwave-assisted synthesis of individual and multicomponent oxides. Russian Chemical Reviews, 2007, vol. 76, no. 5, pp. 397. https://doi.org/10.1070/RC2007v076n05ABEH003650Yen-Chun, Liu. Magnetic and catalytic properties of copper ferrite nanopowders prepared by a microwave-induced combustion process / Yen-Chun Liu, Yen-Pei Fu // Ceram. Int. – 2010. – Vol. 36, iss. 5. – P. 1597–1601. https://doi.org/10.1016/j.ceramint.2010.02.032Yen-Chun Liu, Yen-Pei Fu. Magnetic and catalytic properties of copper ferrite nanopowders prepared by a microwave-induced combustion process. Ceramics International, 2010, vol. 36, iss. 5, pp. 1597–1601. https://doi.org/10.1016/j.ceramint.2010.02.032Catalytic activity of copper ferrite synthesized with the using of microwave treatment in the oxidation reaction of carbon monoxide / G. R. Azimova [et al.] // Am. J. Clin. Nutr. – 2020. – Vol. 2. – P. 29–35.Azimova G. R., Zulfugarova S. M., Aleskerova Z. F., Ismailov E. H. Catalytic activity of copper ferrite synthesized with the using of microwave treatment in the oxidation reaction of carbon monoxide. American Journal of Clinical Nutrition, 2020, vol. 2, pp. 29–35.Bushkova, V. S. Synthesis and study of the properties of nanoferrites obtained by the sol-gel method with the participation of auto-combustion / V. S. Bushkova // Journal of Nano- and Electronic Physics. – 2015. – Vol. 7, N.1. – P. 01023–01029.Bushkova V. S. Synthesis and study of the properties of nanoferrites obtained by the sol-gel method with the participation of auto-combustion. Journal of Nano- and Electronic Physics, 2015, vol. 7, no.1, pp. 01023–01029.Structural parameters and magnetic properties of copper ferrite nanopowders obtained by the sol-gel combustion / V. A. Zhuravlev [et al.] // J. Alloys Compd. – 2016. – Vol. 692. – P. 705–712. https://doi.org/10.1016/j.jallcom.2016.09.069Zhuravlev V. A., Minin R. V., Itin V. I., Lilenko I. Yu. Structural parameters and magnetic properties of copper ferrite nanopowders obtained by the sol-gel combustion. Journal of Alloys and Compounds, 2016, vol. 692, pp. 705–712. https://doi.org/10.1016/j.jallcom.2016.09.069Sol-gel auto combustion synthesis and characterizations of cobalt ferritenanoparticles: Different fuels approach / V. R. Bhagwata [et al.] // Mater. Sci. Eng. – 2019. – Vol. 248. – P. 11438. https://doi.org/10.1016/j.mseb.2019.114388Bhagwata V. R., Ashok V. Humbeb, Morec S. D., Jadhavb K. M. Sol-gel auto combustion synthesis and characterizations of cobalt ferritenanoparticles: Different fuels approach. Materials Science & Engineering, 2019, vol. 248, p. 11438. https://doi.org/10.1016/j.mseb.2019.114388Synthesis of cobalt ferrite (CoFe2O4) by combustion with different concentrations of glycine / C. G. Kaufmann [et al.] // IOP Conf. Ser.: Mater. Sci. Eng. – 2019. – Vol. 659. – P. 012079. https://doi.org/10.1088/1757-899X/659/1/012079Kaufmann C. G., Zampiva R. Y. S., Alves A. K., Bergmann C. P., Giorgini L. Synthesis of cobalt ferrite (CoFe2O4) by combustion with different concentrations of glycine. IOP Conference Series: Materials Science and Engineering, 2019, vol. 659, p. 012079. https://doi.org/10.1088/1757-899X/659/1/012079Synthesis and characterization of nickel ferrite nanoparticles by sol - gel auto combustion method / R. Kesavamoorthi [et al.] // J. Chem. Pharm. Sci. – 2016. – Vol. 9, N. 1. – P. 160–162.Kesavamoorthi R., Vigneshwaran A. N., Vijayalakshmi Sanyal, C. Ramachandra Raja. Synthesis and characterization of nickel ferrite nanoparticles by sol-gel auto combustion method. Journal of Chemical and Pharmaceutical Sciences, 2016, vol. 9, no. 1, pp. 160–162.Dey, S. Catalytic conversion of carbon monoxide into carbon dioxide over spinel catalysts: An overview / S. Dey, G. Ch. Dhal // Mater. Sci. Energy Technol. – 2019. – Vol. 2, iss. 3. – P. 575–588. https://doi.org/10.1016/j.mset.2019.06.003Dey S., Dhal G. Ch. Catalytic conversion of carbon monoxide into carbon dioxide over spinel catalysts: An overview. Materials Science for Energy Technologies, 2019, vol. 2, iss. 3, pp. 575–588. https://doi.org/10.1016/j.mset.2019.06.003Copper based mixed oxide catalysts (CuMnCe, CuMnCo and CuCeZr) for the oxidation of CO at low temperature / S. Dey [et al.] // Mater. Discovery. – 2017. – Vol. 10. – P. 1–14. https://doi.org/10.1016/j.md.2018.02.001Dey S., Dhal G. C., Mohan D., Prasad R. Copper based mixed oxide catalysts (CuMnCe, CuMnCo and CuCeZr) for the oxidation of CO at low temperature. Materials Discovery. 2017, vol. 10, pp. 1–14. https://doi.org/10.1016/j.md.2018.02.001Effect of preparation conditions on the catalytic activity of CuMnOx catalysts for CO Oxidation / S. Dey [et al.] // Bull. Chem. Reaction Eng. Catal. – 2017. – Vol. 12, N. 3. – P. 1–15. https://doi.org/10.9767/bcrec.12.3.900.437-451Dey S., Dhal G. C., Mohan D., Prasad R. Effect of preparation conditions on the catalytic activity of CuMnOx catalysts for CO Oxidation. Bulletin of Chemical Reaction Engineering & Catalysis, 2017, vol. 12, no. 3, pp. 1–15. https://doi.org/10.9767/bcrec.12.3.900.437-451Kinetics of catalytic oxidation of CO over copper-manganese oxide catalyst / M. Li [et al.] // Separation and Purification Technology. – 2007. – Vol. 57, iss. 1. – P. 147–151. https://doi.org/10.1016/j.seppur.2007.03.016Li M., Wang D.-H., Shi X.-C., Zhang Z.-T., Dong T.-X. Kinetics of catalytic oxidation of CO over copper-manganese oxide catalyst. Separation and Purification Technology, 2007, vol. 57, iss. 1, pp. 147–151. https://doi.org/10.1016/j.seppur.2007.03.016Pillai, U. R. Room temperature oxidation of carbon monoxide over copper oxide catalyst /Pillai U. R., Deevi S. Room temperature oxidation of carbon monoxide over copper oxide catalyst. Applied Catalysis B: Environmental, 2006, vol. 64, no. 1-2, pp. 146–154. https://doi.org/10.1016/j.apcatb.2005.11.005U. R. Pillai, S. Deevi // Applied Catalysis B: Environmental. – 2006. – Vol. 64, N 1-2. – P. 146–154. https://doi.org/10.1016/j.apcatb.2005.11.005Brusentsov Yu. A., Minaev A. M. Fundamentals of physics and technology of oxide semiconductors. Tambov, 2002. 80 p. (in Russian).Брусенцов, Ю. А. Основы физики и технологии оксидных полупроводников / Ю. А. Брусенцов, А. М. Минаев. – Тамбов, 2002. – 80 c.Брусенцов, Ю. А. Основы физики и технологии оксидных полупроводников / Ю. А. Брусенцов, А. М. Минаев. – Тамбов, 2002. – 80 c.

The authors declare that there are no conflicts of interest present.