vestichИзвестия Национальной академии наук Беларуси. Серия химических наукProceedings of the National Academy of Sciences of Belarus, Chemical Series1561-83312524-2342The Republican Unitary Enterprise Publishing House "Belaruskaya Navuka"10.29235/1561-8331-2023-59-3-183-192vestich-824Research ArticleФИЗИЧЕСКАЯ ХИМИЯPHYSICAL CHEMISTRYКаталитические свойства и устойчивость порошковых сплавов никель–олово в процессе электрохимического выделения водорода из раствора щелочиCatalytic properties and stability of nickel–tin powder alloys in the process of electrochemical hydrogen evolution from alkali solutionhttps://orcid.org/0000-0002-4877-0974ВрублевскаяО. Н.VrublevskayaO. N.

Врублевская Ольга Николаевна – канд. хим. наук, доцент, зам. директора

ул. Ленинградская, 14, 220006, Минск

Vrublevskaya Olga N. – Ph. D. (Chemistry), Associate Professor, Vice Director for Scientific Work

14, Leningradskaya Str., 220006, Minsk

 

vrublevskaya.olga@gmail.comКареваН. Ю.KarevaN. Yu.

Карева Наталья Юрьевна – студент

ул. Ленинградская, 14, 220050, Минск

Kareva Natalia Yu. – Student

14, Leningradskaya Str., 220050, Minsk

natalja.kareva@gmail.comКалесникА. Д.KalesnikA. D.

Калесник Анастасия Дмитриевна – студент

ул. Ленинградская, 14, 220050, Минск

Kalesnik Anastasiya D. – Student

4, Leningradskaya Str., 220050, Minsk

nastyakalesnik@gmail.comhttps://orcid.org/0000-0001-8937-4161КудакоА. А.KudakaA. A.

Кудако Антон Александрович – науч. сотрудник

ул. Ленинградская, 14, 220006, Минск

Kudaka Anton A. – Researcher

14, Leningradskaya Str., 220006, Minsk

kudako.anton@gmail.comhttps://orcid.org/0000-0001-6104-3707БолормааБ.BolormaaB.

Бурэнтогтох Болормаа – науч. сотрудник

пр. Мира, 54Б, 13330, Улан-Батор

Burentogtokh Bolormaa – Researcher at the Materials Science Department

54B, Peace Ave., 13330, Ulaanbaatar

Bolormss_b@mas.ac.mnhttps://orcid.org/0000-0001-5369-7647СевжидсуренГ.SevjidsurenG.

Галсан Севжидсурен – канд. физ.-мат. наук, зав. отделением материаловедения

пр. Мира, 54Б, 13330, Улан-Батор

Galsan Sevjidsuren – Ph. D. (Physics). Chair of the Materials Science Department

54B, Peace Ave., 13330, Ulaanbaatar

sevjidsureng@mas.ac.mnНаучно-исследовательский институт физико-химических проблем Белорусского государственного университетаResearch Institute for Physical Chemical Problems of the Belarusian State UniversityБелорусский государственный университетBelarusian State UniversityИнститут физики и технологии Монгольской академии наукInstitute of Physics and Technology of the Mongolian Academy of Sciences202302092023593183192Copyright © Врублевская О.Н., Карева Н.Ю., Калесник А.Д., Кудако А.А., Болормаа Б., Севжидсурен Г., 20232023Врублевская О.Н., Карева Н.Ю., Калесник А.Д., Кудако А.А., Болормаа Б., Севжидсурен Г.Vrublevskaya O.N., Kareva N.Y., Kalesnik A.D., Kudaka A.A., Bolormaa B., Sevjidsuren G.Данная работа распространяется под лицензией Creative Commons Attribution 4.0.This work is licensed under a Creative Commons Attribution 4.0 License.https://vestichem.belnauka.by/jour/article/view/824

Химически и электрохимически синтезированы порошковые сплавы Ni–Sn с содержанием никеля соответственно от 24,4 до 78,5 ат.% и от 30,6 до 55,1 ат.% для применения в качестве катализаторов электрохимического восстановления водорода в растворе щелочи. Установлено, что каталитически активная площадь поверхности химически синтезированных порошков больше в сравнении с электрохимически полученными, максимальной площадью характеризуется сплав Ni24,4Sn75,6. Выявлено, что для химически синтезированных порошков каталитические свойства, оцененные по значению потенциала, при котором достигается плотность тока 10 мА/см2, возрастают в ряду Ni24,4Sn75,6 < Ni78,5Sn21,5 < Ni; электрохимически полученные сплавы являются неэффективными катализаторами. Установлено, что сплав Ni24,4Sn75,6 характеризуется большей сохранностью каталитически активной площади поверхности в процессе эксплуатации в сравнении с никелем и сплавом Ni78,5Sn21,5.

Ni–Sn powder alloys with a nickel content from 24.4 to 78.5 at.% and from 30.6 to 55.1 at.%, respectively, were synthesized chemically and electrochemically for the use as catalysts for the hydrogen electrochemical reduction (HER) in alkali solution. It was established that the catalytically active surface area of chemically synthesized powders was larger in comparison with electrochemically obtained ones. Ni24.4Sn75.6 powder alloy has the largest surface area. It was found that catalytic properties of chemically synthesized powders increased in the row Ni24.4Sn75.6 < Ni78.5Sn21.5 < Ni. Electrochem ically obtained alloys are inefficient as HER catalysts. It was found that Ni24.4Sn75.6 alloy is characterized by the greater re tention of catalytically active surface area during exploitation in alkali solution in comparison with Ni and Ni78.5Sn21.5 alloy. 

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The authors declare that there are no conflicts of interest present.