vestichИзвестия Национальной академии наук Беларуси. Серия химических наукProceedings of the National Academy of Sciences of Belarus, Chemical Series1561-83312524-2342The Republican Unitary Enterprise Publishing House "Belaruskaya Navuka"10.29235/1561-8331-2023-59-3-242-256vestich-830Research ArticleХИМИЯ ВЫСОКОМОЛЕКУЛЯРНЫХ СОЕДИНЕНИЙPOLYMER CHEMISTRYПолучение гибридных абсорбентов посредством прививки акриламида к цепям хитозана под воздействием гамма-излученияObtaining hybrid absorbents by grafting acrylamide onto chitosan chains under gamma irradiationФоминаЕ. К.FominaE. K.

Фомина Елена Константиновна – канд. хим. наук, вед. науч. сотрудник

ул. Ленинградская, 14, 220006, Минск

Fomina Elena K. – Ph. D. (Chemistry), Leading Researcher

14, Leningradskaya Str., 220006, Minsk

famina@bsu.byГринюкЕ. В.GrinyukE. V.

Гринюк Евгений Валерьевич – канд. хим. наук, доцент, директор

ул. Ленинградская, 14, 220006, Минск

 

Grinyuk Evgeni V. – Ph. D. (Chemistry), Associate Professor, Director

14, Leningradskaya Str., 220006, Minsk

grinyuk@tut.byКлимовцоваИ. А.KlimovtsovaI. A.

Климовцова Ираида Аркадьевна – ст. науч. сотрудник

ул. Ленинградская, 14, 220006, Минск

Klimovtsova Iraida A. – Senior Researcher

14, Leningradskaya Str., 220006, Minsk

Klimovtsova@bsu.byКудрявскийД. Л.KudryavskyD. L.

Кудрявский Дмитрий Леонович – аспирант, мл. науч. сотрудник

ул. Ленинградская, 14, 220006, Минск

Kudryavsky Dmitry L. – Postgraduate Student, Junior Researcher

14, Leningradskaya Str., 220006, Minsk

Kudryavsky@bsu.byФедоренкоА. А.FedorenkoA. A.

Федоренко Александра Андреевна – аспирант, мл. науч. сотрудник

ул. Ленинградская, 14, 220006, Минск

Fedorenko Alexandra A. – Graduate Student, Junior Researcher

14, Leningradskaya Str., 220006, Minsk

sashfedorenko@gmail.comИванчиковЯ. Д.IvanchikovY. D.

Иванчиков Ян Дмитриевич – химик

ул. Московская, 13, 220007, Минск

Ivanchikov Yan D. – Chemist

13, Moskovskaya Str., 220007, Minsk

yanmozel@gmail.comШиманД. И.ShimanD. I.

Шиман Дмитрий Иванович – канд. хим. наук, доцент, вед. науч. сотрудник

ул. Ленинградская, 14, 220006, Минск

Shiman Dmitri I. – Ph. D. (Chemistry), Аssociate Professor, Leading Researcher

14, Leningradskaya Str., 220006, Minsk

shimand@bsu.byСальниковаИ. А.SalnikovaI. A.

Сальникова Ирина Аркадьевна – зав. сектором

220109, а/я 119, Минск

Salnikova Irina A. – Head of the Research Section

220109, lockbox 119, Minsk

salirina@mail.ruЯкименкоО. В.YakimenkoO. V.

Якименко Олег Владиславович – ст. преподаватель

ул. Ленинградская, 14, 220006, Минск

Yakimenko Oleg V. – Senior Lecturer, Chemistry Department

14, Leningradskaya Str., 220006, Minsk

yakimenkoo955@gmail.comНаучно-исследовательский институт физико-химических проблем Белорусского государственного университетаБеларусьResearch Institute for Physical Chemical Problems of the Belarusian State UniversityBelarusНаучно-исследовательский институт физико-химических проблем Белорусского государственного университета; Белорусский государственный университетБеларусьResearch Institute for Physical Chemical Problems of the Belarusian State University; Belarusian State UniversityBelarusООО «Адукар»БеларусьLimited Liability Company «Adukar»BelarusОбъединенный институт энергетических и ядерных исследований – Сосны Национальной академии наук БеларусиБеларусьThe Joint Institute for Power and Nuclear Research – Sosny of the National Academy of Sciences of BelarusBelarusБелорусский государственный университетБеларусьBelarusian State UniversityBelarus202304092023593242256Copyright © Фомина Е.К., Гринюк Е.В., Климовцова И.А., Кудрявский Д.Л., Федоренко А.А., Иванчиков Я.Д., Шиман Д.И., Сальникова И.А., Якименко О.В., 20232023Фомина Е.К., Гринюк Е.В., Климовцова И.А., Кудрявский Д.Л., Федоренко А.А., Иванчиков Я.Д., Шиман Д.И., Сальникова И.А., Якименко О.В.Fomina E.K., Grinyuk E.V., Klimovtsova I.A., Kudryavsky D.L., Fedorenko A.A., Ivanchikov Y.D., Shiman D.I., Salnikova I.A., Yakimenko O.V.Данная работа распространяется под лицензией Creative Commons Attribution 4.0.This work is licensed under a Creative Commons Attribution 4.0 License.https://vestichem.belnauka.by/jour/article/view/830

Синтезированы гибридные гидрогели посредством радиационной прививки акриламида к цепям хитозана в уксуснокислых водных растворах. Структура привитого сополимера хитозана с акриламидом изучена методами Фурье-ИК спектроскопии, рентгенофазового анализа и совмещенного термического анализа. Установлено, что центрами прививки растущих цепей полиакриламида на макромолекулах хитозана являются как гидроксильные, так и аминогруппы полисахарида. Изучено влияние мольных отношений реагентов на сорбционные и реологические свойства полученных гидрогелей. Проведено химическое модифицирование гидрогелей на основе привитых сополимеров хитозана с акриламидом посредством щелочного гидролиза и установлено его влияние на сорбционную способность гидрогелей по отношению к воде и ионам Cu(II).

Hybrid hydrogels have been synthesized by radiation grafting of acrylamide to chitosan chains. The structure of the acrylamide-grafted chitosan was examined using FTIR spectroscopy, X-ray diffraction and simultaneous thermal analysis. It has been determined that both hydroxyl and amino groups of the polysaccharide are the grafting centers of growing polyacrylamide chains on the chitosan macromolecules. The effect of the reagents ratio on the sorption and rheological properties of the obtained hydrogels has been studied. Hydrogels based on acrylamide-grafted chitosan were modified chemically by alkaline hydrolysis, and the effect of hydrolysis on the sorption capacity of hydrogels with respect to water and Cu(II) ions was examined.

хитозанакриламидгамма-облучениерадиационное инициированиерадикальная прививочная сополимеризациягидрогельсорбционная способностьионы Cu(II)chitosanacrylamidegamma irradiationradiation initiationradical grafting copolymerizationhydrogelsorption capacityCu(II) ionsРабота выполнена при финансовой поддержке Белорусского республиканского фонда фундаментальных исследований (грант № Х22УЗБ-025) «Новые методы получения гибридных полимерных суперабсорбентов на основе полисахаридов и полиакрилатов».The research was supported financially by the BRFFR (grant no. X22УЗБ-025) «New methods for the preparation of hybrid polymer superabsorbents based on polysaccharides and polyacrylates».ReferencesAhmed, E. M. Hydrogel: Preparation, characterization, and applications: A review / E. M. Ahmed // J. Adv. Res. – 2015. – Vol. 6, № 2. – P. 105–121. https://doi.org/10.1016/j.jare.2013.07.006Ahmed E. M. Hydrogel: Preparation, characterization, and applications: A review. 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The authors declare that there are no conflicts of interest present.