vestichИзвестия Национальной академии наук Беларуси. Серия химических наукProceedings of the National Academy of Sciences of Belarus, Chemical Series1561-83312524-2342The Republican Unitary Enterprise Publishing House "Belaruskaya Navuka"10.29235/1561-8331-2023-59-4-271-284vestich-845Research ArticleФИЗИЧЕСКАЯ ХИМИЯPHYSICAL CHEMISTRYСинтез наностержней золота с применение смешанного восстановителя гидрохинон– аскорбиновая кислотаSynthesis of gold nanorods using a mixed reducing agent hydroquinone–ascorbic acidhttps://orcid.org/0000-0001-8618-6771КулаковичО. С.KulakovichO. S.

Кулакович Ольга Сергеевна – кандидат химических наук, ведущий научный сотрудник

пр-т Независимости, 68, 220072, Минск

Kulakovich Olga S. – Ph. D. (Chemistry), Leading Reseacher

68, Nezalezhnasti Ave., 220072, Minsk

o.kulakovich@ifanbel.basnet.byРаецкийП. Д.RaetskyP. D.

Раецкий Павел Дмитриевич – младший научный сотрудник

пр-т Независимости, 68, 220072, Минск

Raetsky Pavel D. – Junior Researcher

68, Nezalezhnasti Ave., 220072, Minsk

raetskypavel@gmail.comВершининаО. В.VershininaO. V.

Вершинина Олеся Валерьевна – инженер

Институтский пер., 9, 141701, Долгопрудный

Vershinina Olesya V. – Engineer. Center for Testing Functional Materials 

9, Institutskiy per., 141701, Dolgoprudny

seraia.ov@phystech.eduhttps://orcid.org/0000-0003-2072-3970ТроцюкЛ. Л.TrotsyukL. L.

Троцюк Людмила Леонидовна – кандидат химических наук, старший научный сотрудник

пр-т Независимости, 68, 220072, Минск

Trotsiuk Lyudmila L. – Ph. D. (Chemistry), Senior Researcher

68, Nezalezhnasti Ave., 220072, Minsk

mila_tro@yahoo.comИнститут физики имени Б. И. Степанова НАН БеларусиB. I. Stepanov Institute of Physics of the National Academy of Sciences of BelarusМосковский физико-технический институтMoscow Institute of Physics and Technology202302122023594271284Copyright © Кулакович О.С., Раецкий П.Д., Вершинина О.В., Троцюк Л.Л., 20232023Кулакович О.С., Раецкий П.Д., Вершинина О.В., Троцюк Л.Л.Kulakovich O.S., Raetsky P.D., Vershinina O.V., Trotsyuk L.L.Данная работа распространяется под лицензией Creative Commons Attribution 4.0.This work is licensed under a Creative Commons Attribution 4.0 License.https://vestichem.belnauka.by/jour/article/view/845

Предложена новая смешанная восстановительная система для синтеза наностержней золота (НСЗ), включающая аскорбиновую кислоту (АК) и гидрохинон (ГХ). Выявлены зависимости, связывающие положение полосы продольного плазмонного резонанса НСЗ с концентрациями используемых при их синтезе ионов серебра, аскорбиновой кислоты, гидрохинона, позволяющие получать НСЗ с заданными оптическими свойствами. Обнаружено, что при использовании смешанного восстановителя могут быть достигнуты бо́льшие показатели монодисперсности и морфологического выхода по сравнению с индивидуальными восстановителями, что особенно актуально для получения коротких НСЗ с максимумом продольного плазмонного резонанса в области 600–700 нм.

A new mixed reduction system for the synthesis of gold nanorods (NRs), including ascorbic acid and hydro- quinone, has been proposed. Dependence of NRs longitudinal plasmon resonance band position on the concentration of silver ions, ascorbic acid and hydroquinone during synthesis were found, which makes it possible to obtain NRs with required op- tical properties. It was found that when using a mixed reducing agent, higher monodispersity and morphological yield can be achieved as compared to individual reducing agents, which is especially important for obtaining short NRs with a maximum of longitudinal plasmon resonance in the region of 600–700 nm.

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The authors declare that there are no conflicts of interest present.