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<article article-type="research-article" dtd-version="1.3" xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xml:lang="ru"><front><journal-meta><journal-id journal-id-type="publisher-id">vestich</journal-id><journal-title-group><journal-title xml:lang="ru">Известия Национальной академии наук Беларуси. Серия химических наук</journal-title><trans-title-group xml:lang="en"><trans-title>Proceedings of the National Academy of Sciences of Belarus, Chemical Series</trans-title></trans-title-group></journal-title-group><issn pub-type="ppub">1561-8331</issn><issn pub-type="epub">2524-2342</issn><publisher><publisher-name>The Republican Unitary Enterprise Publishing House "Belaruskaya Navuka"</publisher-name></publisher></journal-meta><article-meta><article-id pub-id-type="doi">10.29235/1561-8331-2024-60-2-115-120</article-id><article-id custom-type="elpub" pub-id-type="custom">vestich-877</article-id><article-categories><subj-group subj-group-type="heading"><subject>Research Article</subject></subj-group><subj-group subj-group-type="section-heading" xml:lang="ru"><subject>ФИЗИЧЕСКАЯ ХИМИЯ</subject></subj-group><subj-group subj-group-type="section-heading" xml:lang="en"><subject>PHYSICAL CHEMISTRY</subject></subj-group></article-categories><title-group><article-title>Цинкионный аккумулятор с неводным электролитом и положительным электродом на основе цинк-марганцевой шпинели</article-title><trans-title-group xml:lang="en"><trans-title>Zinc-ion battery with non-aqueous electrolyte and zinc-manganese spinel positive electrode</trans-title></trans-title-group></title-group><contrib-group><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Семёнов</surname><given-names>В. В.</given-names></name><name name-style="western" xml:lang="en"><surname>Siamionau</surname><given-names>U. V.</given-names></name></name-alternatives><bio xml:lang="ru"><p>Семёнов Владислав Вадимович – аспирант</p><p>ул. Ленинградская, 14, 220030, Минск</p></bio><bio xml:lang="en"><p>Siamionau Uladzislau V. – Postgraduate Student</p><p>14, Leningradskaya Str., 220030, Minsk</p></bio><email xlink:type="simple">u.v.siamionau@gmail.com</email><xref ref-type="aff" rid="aff-1"/></contrib><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Анискевич</surname><given-names>Е. Н.</given-names></name><name name-style="western" xml:lang="en"><surname>Aniskevich</surname><given-names>Y. M.</given-names></name></name-alternatives><bio xml:lang="ru"><p>Анискевич Евгений Николаевич – кандидат химических наук, научный сотрудник</p><p>Гунья-дон, Гванджин-гу, Сеул</p><p> </p></bio><bio xml:lang="en"><p>Aniskevich Yauhen M. – Ph. D. (Chemistry), Researcher</p><p>Gunja-Dong, Gwangjin-Gu, 05006, Seoul</p><p> </p></bio><email xlink:type="simple">aniskevich.y.m@gmail.com</email><xref ref-type="aff" rid="aff-2"/></contrib><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Иванченко</surname><given-names>А. Р.</given-names></name><name name-style="western" xml:lang="en"><surname>Ivanchanka</surname><given-names>A. R.</given-names></name></name-alternatives><bio xml:lang="ru"><p>Иванченко Алексей Романович – студент</p><p>Радвиленайское шоссе 19, 50299</p></bio><bio xml:lang="en"><p>Ivanchanka Aliaksei R. – Student</p><p>19, Radvilėnų pl., 50299, Kaunas</p></bio><xref ref-type="aff" rid="aff-3"/></contrib><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Рагойша</surname><given-names>Г. А.</given-names></name><name name-style="western" xml:lang="en"><surname>Ragoisha</surname><given-names>G. A.</given-names></name></name-alternatives><bio xml:lang="ru"><p>Рагойша Геннадий Антонович – кандидат химических наук, ведущий научный сотрудник</p><p>ул. Ленинградская, 14, 220006, Минск</p></bio><bio xml:lang="en"><p>Ragoisha Genady A. – Ph. D. (Chemistry), Leading Researcher</p><p>14, Leningradskaya Str., 220006, Minsk</p></bio><email xlink:type="simple">ragoishag@bsu.by</email><xref ref-type="aff" rid="aff-4"/></contrib><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Кулак</surname><given-names>А. И.</given-names></name><name name-style="western" xml:lang="en"><surname>Kulak</surname><given-names>A. I.</given-names></name></name-alternatives><bio xml:lang="ru"><p>Кулак Анатолий Иосифович – академик</p><p>ул. Сурганова, 9/1, 220072, Минск</p></bio><bio xml:lang="en"><p>Kulak Anatoly I. – Academician of the National Academy of Sciences of Belarus, D. Sc. (Chemistry), Professor, Director</p><p>9/1, Surganov Str., 220072, Minsk</p></bio><email xlink:type="simple">kulak@igic.bas-net.by</email><xref ref-type="aff" rid="aff-5"/></contrib><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Стрельцов</surname><given-names>Е. А.</given-names></name><name name-style="western" xml:lang="en"><surname>Streltsov</surname><given-names>E. A.</given-names></name></name-alternatives><bio xml:lang="ru"><p>Стрельцов Евгений Анатольевич – доктор химических наук, профессор, заведующий кафедрой</p><p>ул. Ленинградская, 14, 220006, Минск</p></bio><bio xml:lang="en"><p>Streltsov Eugene A. – D. Sc. (Chemistry), Head of the Department</p><p>14, Leningradskaya Str., 220006, Minsk</p></bio><xref ref-type="aff" rid="aff-1"/></contrib></contrib-group><aff-alternatives id="aff-1"><aff xml:lang="ru"><institution>Белорусский государственный университет</institution></aff><aff xml:lang="en"><institution>Belarusian State</institution></aff></aff-alternatives><aff-alternatives id="aff-2"><aff xml:lang="ru"><institution>Университет Седжон</institution></aff><aff xml:lang="en"><institution>Sejong University</institution></aff></aff-alternatives><aff-alternatives id="aff-3"><aff xml:lang="ru"><institution>Каунасский технологический университет</institution></aff><aff xml:lang="en"><institution>Kaunas University of Technology</institution></aff></aff-alternatives><aff-alternatives id="aff-4"><aff xml:lang="ru"><institution>Научно-исследовательский институт физико-химических проблем Белорусского государственного университета</institution></aff><aff xml:lang="en"><institution>Research Institute for Physical Chemical Problems of the Belarusian State University</institution></aff></aff-alternatives><aff-alternatives id="aff-5"><aff xml:lang="ru"><institution>Инстиут общей и неорганической химии Национальной академии наук Беларуси</institution></aff><aff xml:lang="en"><institution>Institute of General and Inorganic Chemistry of the National Academy of Sciences of Belarus</institution></aff></aff-alternatives><pub-date pub-type="collection"><year>2024</year></pub-date><pub-date pub-type="epub"><day>24</day><month>05</month><year>2024</year></pub-date><volume>60</volume><issue>2</issue><fpage>115</fpage><lpage>120</lpage><permissions><copyright-statement>Copyright &amp;#x00A9; Семёнов В.В., Анискевич Е.Н., Иванченко А.Р., Рагойша Г.А., Кулак А.И., Стрельцов Е.А., 2024</copyright-statement><copyright-year>2024</copyright-year><copyright-holder xml:lang="ru">Семёнов В.В., Анискевич Е.Н., Иванченко А.Р., Рагойша Г.А., Кулак А.И., Стрельцов Е.А.</copyright-holder><copyright-holder xml:lang="en">Siamionau U.V., Aniskevich Y.M., Ivanchanka A.R., Ragoisha G.A., Kulak A.I., Streltsov E.A.</copyright-holder><license xml:lang="ru" license-type="creative-commons-attribution" xlink:href="https://creativecommons.org/licenses/by/4.0/" xlink:type="simple"><license-p>Данная работа распространяется под лицензией Creative Commons Attribution 4.0.</license-p></license><license xml:lang="en" license-type="creative-commons-attribution" xlink:href="https://creativecommons.org/licenses/by/4.0/" xlink:type="simple"><license-p>This work is licensed under a Creative Commons Attribution 4.0 License.</license-p></license></permissions><self-uri xlink:href="https://vestichem.belnauka.by/jour/article/view/877">https://vestichem.belnauka.by/jour/article/view/877</self-uri><abstract><p>Установлен значительный рост (на порядок) удельной поверхности порошков цинк-марганцевой шпинели ZnMn2O4 путем ее частичного растворения в водном растворе H2SO4. Удельная поверхность определялась методом адсорбции молекулярного азота. Обнаружена корреляция величин удельной поверхности и удельной емкости положительных ZnMn2O4 электродов, используемых в неводных цинк-ионных аккумуляторах.</p></abstract><trans-abstract xml:lang="en"><p>Zinc manganite spinel powder specific surface area was found to increase by an order of magnitude via a treatment with sulfuric acid. The specific surface area, determined by nitrogen adsorption, correlates with the specific capacity of zinc manganite spinel positive electrodes. Zinc manganite spinel subjected to a controllable acidic treatment is a promising material for the non-aqueous zinc-ion batteries.</p></trans-abstract><kwd-group xml:lang="ru"><kwd>цинк-ионные аккумуляторы</kwd><kwd>манганит цинка</kwd><kwd>шпинель</kwd><kwd>удельная емкость</kwd></kwd-group><kwd-group xml:lang="en"><kwd>zinc-ion batteries</kwd><kwd>zinc manganite</kwd><kwd>spinel</kwd><kwd>specific capacity</kwd></kwd-group><funding-group><funding-statement xml:lang="ru">Работа выполнена при финансовой поддержке государственной программы научных исследований «Химические процессы, реагенты и технологии, биорегуляторы и биооргхимия» на 2021–2025 гг. (научно-исследовательские работы 20210562 и 20211465).</funding-statement><funding-statement xml:lang="en">The work was carried out with the financial support from the State scientific research program “Chemical processes, reagents and technologies, bioregulators and bioorgchemistry” for 2021–2025. (research papers 20210562 and 20211465).</funding-statement></funding-group></article-meta></front><back><ref-list><title>References</title><ref id="cit1"><label>1</label><citation-alternatives><mixed-citation xml:lang="ru">30 years of lithium-ion batteries / M. Li [et al.] // Adv. Mater. – 2018. – Vol. 30, № 33. – P. 1800561.</mixed-citation><mixed-citation xml:lang="en">Li M., Lu J., Chen Z., Amine K. 30 years of lithium-ion batteries. Advanced Materials., 2018, vol. 30, no. 33, pp. 1800561.</mixed-citation></citation-alternatives></ref><ref id="cit2"><label>2</label><citation-alternatives><mixed-citation xml:lang="ru">Lithium Metal: The Key to Green Transportation / P. Lindagato [et al.] // Appl. Sci. – 2023. – Vol. 13, № 1. – P. 405.</mixed-citation><mixed-citation xml:lang="en">Lindagato P., Yang G., Macháček J., Irénée M., Anastase N., Kanimba Ntwali H. P. Lithium Metal: The Key to Green Transportation. Applied Sciences, 2023, vol. 13, no. 1, pp. 405.</mixed-citation></citation-alternatives></ref><ref id="cit3"><label>3</label><citation-alternatives><mixed-citation xml:lang="ru">Muldoon, J. Quest for nonaqueous multivalent secondary batteries: magnesium and beyond / J. Muldoon, C. B. Bucur, T. Gregory // Chem. Rev.– 2014. – Vol. 114, № 23. – P. 11683–11720.</mixed-citation><mixed-citation xml:lang="en">Muldoon J., Bucur C. B., Gregory T. Quest for nonaqueous multivalent secondary batteries: magnesium and beyond. Chemical reviews, 2014, vol. 114, no. 23, pp.11683–11720.</mixed-citation></citation-alternatives></ref><ref id="cit4"><label>4</label><citation-alternatives><mixed-citation xml:lang="ru">Emerging non-lithium ion batteries / Y. Wang [et al.] // Energy Storage Mater. – 2016. – Vol. 4. – P. 103–129.</mixed-citation><mixed-citation xml:lang="en">Wang Y., Chen R., Chen T., Lv H., Zhu G., Ma L., Wang C., Jin Z., Liu J. Emerging non-lithium ion batteries. Energy Storage Materials, 2016, vol. 4, pp. 103–129.</mixed-citation></citation-alternatives></ref><ref id="cit5"><label>5</label><citation-alternatives><mixed-citation xml:lang="ru">Electrochemically induced structural transformation in a γ-MnO2 cathode of a high capacity zinc-ion battery system / M. H. Alfaruqi [et al.] // Chem. Mater. – 2015. – Vol. 27, № 10. – P. 3609–3620.</mixed-citation><mixed-citation xml:lang="en">Alfaruqi M. H., Mathew V., Gim J., Kim S., Song J., Baboo J. P., Choi S. H., Kim J. Electrochemically induced structural transformation in a γ-MnO2 cathode of a high capacity zinc-ion battery system. Chemistry of Materials, 2015, vol. 27, no. 10, pp. 3609–3620.</mixed-citation></citation-alternatives></ref><ref id="cit6"><label>6</label><citation-alternatives><mixed-citation xml:lang="ru">Recent advances in Zn-ion batteries / M. Song [et al.] // Adv. Funct. Mater. – 2018. – Vol. 28, №. 41. – С. 1802564.</mixed-citation><mixed-citation xml:lang="en">Song, M., Tan H., Chao D., Jin H. FanRecent advances in Zn-ion batteries. Advanced Functional Materials, 2018, vol. 28, no. 41, pp. 1802564.</mixed-citation></citation-alternatives></ref><ref id="cit7"><label>7</label><citation-alternatives><mixed-citation xml:lang="ru">Blanc, L. E. Scientific challenges for the implementation of Zn-ion batteries / L. E. Blanc, D. Kundu, L. F. Nazar // Joule. – 2020. – Vol. 4, № 4. – P. 771–799.</mixed-citation><mixed-citation xml:lang="en">Blanc L. E., Kundu D., Nazar L. F. Scientific challenges for the implementation of Zn-ion batteries. Joule, 2020, vol. 4, no. 4, pp. 771–799.</mixed-citation></citation-alternatives></ref><ref id="cit8"><label>8</label><citation-alternatives><mixed-citation xml:lang="ru">Chang, K. In situ synthesis of MoS2/graphene nanosheet composites with extraordinarily high electrochemical performance for lithium ion batteries / K. Chang, W. Chen // Chem. Commun. – 2011. – Vol. 47, iss. 14. – P. 4252–4254.</mixed-citation><mixed-citation xml:lang="en">Chang K., Chen W. In situ synthesis of MoS2/graphene nanosheet composites with extraordinarily high electrochemical performance for lithium ion batteries. Chemical Communications. 2011, vol. 47, iss. 14, pp. 4252–4254.</mixed-citation></citation-alternatives></ref><ref id="cit9"><label>9</label><citation-alternatives><mixed-citation xml:lang="ru">Self-assembled MoS2–carbon nanostructures: influence of nanostructuring and carbon on lithium battery performance / S. K. Das [et al.] // J. Mater. Chem. – 2012. – Vol. 22, № 26. – P. 12988–12992.</mixed-citation><mixed-citation xml:lang="en">Das S. K., Mallavajula R., Jayaprakash N., Archer L. A. Self-assembled MoS2–carbon nanostructures: influence of nanostructuring and carbon on lithium battery performance. Journal of Materials Chemistry, 2012, vol. 22, no. 26, pp. 12988–12992.</mixed-citation></citation-alternatives></ref><ref id="cit10"><label>10</label><citation-alternatives><mixed-citation xml:lang="ru">Ultraporous, Ultrasmall MgMn2O4 Spinel Cathode for a Room-Temperature Magnesium Rechargeable Battery / H. Kobayashi [et al.] // ACS nano. – 2023. – Vol. 17, № 3. – P. 3135–3142.</mixed-citation><mixed-citation xml:lang="en">Kobayashi H., Fukumi Y., Watanabe H., Iimura R., Nishimura N., Mandai T., Tominaga Y., Nakayama M., Ichitsubo T., Imai H. Ultraporous, Ultrasmall MgMn2O4 Spinel Cathode for a Room-Temperature Magnesium Rechargeable Battery. ACS nano, 2023, vol. 17, no. 3, pp. 3135–3142.</mixed-citation></citation-alternatives></ref><ref id="cit11"><label>11</label><citation-alternatives><mixed-citation xml:lang="ru">Cation-deficient spinel ZnMn2O4 cathode in Zn(CF3SO3)2 electrolyte for rechargeable aqueous Zn-ion battery / N. Zhang [et al.] // J. Am. Chem. Soc. – 2016. – Vol. 138, №39. – P. 12894–12901.</mixed-citation><mixed-citation xml:lang="en">Zhang N., Cheng F., Liu Y., Zhao Q., Lei K., Chen C., Liu X., Chen J. Cation-deficient spinel ZnMn2O4 cathode in Zn(CF3SO3)2 electrolyte for rechargeable aqueous Zn-ion battery. Journal of the American Chemical Society, 2016, vol. 138, no. 39, pp. 12894–12901.</mixed-citation></citation-alternatives></ref><ref id="cit12"><label>12</label><citation-alternatives><mixed-citation xml:lang="ru">Mechanism of Zn insertion into nanostructured δ-MnO2: a nonaqueous rechargeable Zn metal battery / S. D. Han [et al.] // Chem. Mater. – 2017. – Vol. 29, № 11. – P. 4874–4884.</mixed-citation><mixed-citation xml:lang="en">Han S. D., Kim S., Li D., Petkov V., Yoo H. D., Phillips P., Wang H., Kim J., More K., Key B., Klie R. F., Cabana J., Stamenkovic V. R., Fister T. T., Marković N. M., Burrell A. K., Tepavcevic S., Vaughey J. T. Mechanism of Zn insertion into nanostructured δ-MnO2: a nonaqueous rechargeable Zn metal battery. Chemistry of Materials, 2017, vol. 29, no. 11, pp. 4874–4884.</mixed-citation></citation-alternatives></ref><ref id="cit13"><label>13</label><citation-alternatives><mixed-citation xml:lang="ru">Formation of MnxZny(OH)z SO4·5H2O – not intercalation of Zn – is the basis of the neutral MnO2/Zn battery first discharge reaction / I. Stoševski [et al.] // Electrochim. Acta. – 2021. – Vol. 390. – P. 138852.</mixed-citation><mixed-citation xml:lang="en">Stoševski, I., Bonakdarpour A., Fang B., Lo P., Wilkinson D. P. Formation of MnxZny(OH)z SO4·5H2O – not intercalation of Zn – is the basis of the neutral MnO2/Zn battery first discharge reaction. Electrochimica, 2021, vol. 390, pp. 138852.</mixed-citation></citation-alternatives></ref><ref id="cit14"><label>14</label><citation-alternatives><mixed-citation xml:lang="ru">MnO2 electrodeposition at the positive electrode of zinc-ion aqueous battery containing Zn2+ and Mn2+ cations / U. V. Siamionau [et al.] // J. Solid State Electrochem. – 2023. – Vol. 27. – P. 1911–1918.</mixed-citation><mixed-citation xml:lang="en">Siamionau U. V., Aniskevich Y., Ragoisha G. A., Streltsov E. A. MnO2 electrodeposition at the positive electrode of zinc-ion aqueous battery containing Zn2+ and Mn2+ cations. Journal of Solid State Electrochemistry, 2023, vol. 27, pp. 1911–1918.</mixed-citation></citation-alternatives></ref><ref id="cit15"><label>15</label><citation-alternatives><mixed-citation xml:lang="ru">Rechargeable zinc-ion batteries with manganese dioxide cathode: How critical is choice of manganese dioxide polymorphs in aqueous solutions? / U. Siamionau [et al.] // J. Power Sources. – 2022. – Vol. 523. – P. 231023.</mixed-citation><mixed-citation xml:lang="en">Siamionau U., Aniskevich Y., Mazanik A., Kokits O., Ragoisha G., Jo J. H., Myung S.-T., Streltsov E. Rechargeable zinc-ion batteries with manganese dioxide cathode: How critical is choice of manganese dioxide polymorphs in aqueous solutions? Journal of Power Sources, 2022, vol. 523, pp. 231023.</mixed-citation></citation-alternatives></ref><ref id="cit16"><label>16</label><citation-alternatives><mixed-citation xml:lang="ru">Controllable synthesis of spinel nano-ZnMn2O4 via a single source precursor route and its high capacity retention as anode material for lithium ion batteries / Y. Deng [et al.] // J. Mater. Chem. – 2011. – Vol. 21, № 32. – P. 11987–11995.</mixed-citation><mixed-citation xml:lang="en">Deng Y., Tang S., Zhang Q., Shi Z., Zhang L., Zhan S.-Z., Chen G. Controllable synthesis of spinel nano-ZnMn2O4 via a single source precursor route and its high capacity retention as anode material for lithium ion batteries. Journal of Materials Chemistry, 2011, vol. 21, no. 32, pp. 11987–11995.</mixed-citation></citation-alternatives></ref><ref id="cit17"><label>17</label><citation-alternatives><mixed-citation xml:lang="ru">Gregg, S.J. Adsorption surface area and porosity / S. Gregg, K. Sing. – London: Academic Press, 1982. – 303 p.</mixed-citation><mixed-citation xml:lang="en">Gregg S. J., Sing K. Adsorption surface area and porosity. London: Academic Press, 1982. 303 p.</mixed-citation></citation-alternatives></ref></ref-list><fn-group><fn fn-type="conflict"><p>The authors declare that there are no conflicts of interest present.</p></fn></fn-group></back></article>
