vestichИзвестия Национальной академии наук Беларуси. Серия химических наукProceedings of the National Academy of Sciences of Belarus, Chemical Series1561-83312524-2342The Republican Unitary Enterprise Publishing House "Belaruskaya Navuka"10.29235/1561-8331-2025-61-1-24-29vestich-934Research ArticleФИЗИЧЕСКАЯ ХИМИЯPHYSICAL CHEMISTRYИсследование кинетических закономерностей окислительного превращения пропилена в акролеин на модифицированном клиноптилолитеStudy of kinetic regularities of the oxidative conversion of propylene to acrolein on a modified clinoptilolitehttps://orcid.org/0009-0001-4980-6537ГусейноваТ. И.HuseynovaT. I.

Гусейнова Тарана Ибад – научный сотрудник

пр-т Г. Джавида, 113, AZ-1143, Баку

Huseynova Tarana I. – Researcher

113, H. Javid Ave., AZ-1143, Baku

 

tarana1969@mail.ruhttps://orcid.org/0009-0007-9331-3303Али-задеГ. А.Ali-zadehG. A.

Али-заде Гюльмира Ахмед – доктор философии по химии, доцент, ведущий научный сотрудник

пр-т Г. Джавида, 113, AZ-1143, Баку

Ali-zadeh Gulmira A. – Ph. D. (Chemistry), Associate Professor, Leading Researcher

113, H. Javid Ave., AZ-1143, Baku

aylinka25@mail.ruhttps://orcid.org/0009-0002-7870-0667АлиеваМ. Г.AliyevaM. G.

Алиева Махизар Гафар – доктор философии по хи- мии, старший научный сотрудник

пр-т Г. Джавида, 113, AZ-1143, Баку

Aliyeva Makhizar G. – Ph. D. (Сhemistry), Senior Researcher

113, H. Javid Ave., AZ-1143, Baku

alieva.makhizer@mail.ruЯрыевВ. М.YariyevV. M.

Ярыев Вагиф Маммадага – научный сотрудник

пр-т Г. Джавида, 113, AZ-1143, Баку

Yariyev Vagif M. – Researcher

113, H. Javid Ave., AZ-1143, Baku

Институт катализа и неорганической химии имени академика М. Нагиева Министерства науки и образования Республики АзербайджанAcademician M. Nagiyev Institute of Catalysis and Inorganic Chemistry, Ministry of Science and Education of the Republic of AzerbaijanAcademician M. Nagiyev Institute of Catalysis and Inorganic Chemistry, Ministry of Science and Education of the Republic of AzerbaijanAzerbaijan2025270220256112429Copyright © Гусейнова Т.И., Али-заде Г.А., Алиева М.Г., Ярыев В.М., 20252025Гусейнова Т.И., Али-заде Г.А., Алиева М.Г., Ярыев В.М.Huseynova T.I., Ali-zadeh G.A., Aliyeva M.G., Yariyev V.M.Данная работа распространяется под лицензией Creative Commons Attribution 4.0.This work is licensed under a Creative Commons Attribution 4.0 License.https://vestichem.belnauka.by/jour/article/view/934

Изучены кинетические закономерности реакции окислительного превращения пропилена в акролеин на катализаторе 1 % Ni2+-клиноптилолит, при различных температурах (320–380 °С), объемных скоростях |700–1 400 ч–1 и парциальных давлениях реагентов ( PC H3 6 = 0,36–0,46 атм., PO2 = 0,55–0,64 атм.). На основе экспериментальных данных предложена стадийная схема протекания реакции.

The kinetic regularities of oxidative conversion of propylene to acrolein with 1 % Ni2+-clinoptilolite catalyst at different temperatures (320–380 °C), volume rates of 700–1 400 h–1 and partial pressures (PC H3 6 = 0.36–0.46 atm., PO2 = 0.55–0.64 atm.), have been studied. On the basis of the experimental data, a stepwise scheme of the reaction course was proposed.

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The authors declare that there are no conflicts of interest present.