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SYNTHESIS AND PROPERTIES OF THE NEW FIBROUS ANION EXCHANGER WITH AMINOETHYLPIPERAZINE FUNCTIONAL GROUPS

Abstract

A new anion exchanger with aminoethylpiperazine functional groups has been synthesized from polyacrylonitrile fiber. The subsequent alkylation with epichlorohydrin afforded another anion exchanger with strong base functional groups. The optimal conditions for synthesis of these ion exchangers have been found, their physical chemical and sorption properties have been investigated. Experimental data of sulfur dioxide sorption on the ion exchanger with aminoethylpiperazine functional groups show its practical applicability for air purification from acidic pollutants.

About the Authors

E. G. Kosandrovich
Institute of Physical Organic Chemistry of the National Academy of Sciences of Belarus
Belarus
Ph. D. (Chemistry), Professor, Leading Researcher


L. N. Shachenkova
Institute of Physical Organic Chemistry of the National Academy of Sciences of Belarus
Belarus
Ph. D. (Chemistry), Senior Researcher


P. V. Nesteronok
Institute of Physical Organic Chemistry of the National Academy of Sciences of Belarus
Belarus
Scientific Researcher.


V. N. Yakubel
Institute of Physical Organic Chemistry of the National Academy of Sciences of Belarus
Belarus
J. Researcher.


V. S. Soldatov
Institute of Physical Organic Chemistry of the National Academy of Sciences of Belarus
Belarus
Academician, D. Sc. (Chemistry), Professor, Head of the Laboratory.


References

1. Kotze, M. H. (1992) «The status of ion exchange fibers for metallurgical application», Journal of the minerals, metalsand materials society, vol. 44, no. 5, pp. 46–50.

2. Zverev, M. P. (1993) «Technical and economical justification of the use of VION chemisorptive fibres», Fibre Chemistry,vol. 25, no. 6, pp. 498–504.

3. Druzhinina, T. V. and Nazar’ina, L. A. (1999) «Chemisorption fibres based on graft copolymers: fabrication

4. and properties», Fibre Chemistry, vol. 31, no. 4, pp. 252–262.

5. Zverev, M. P. (2002) «Fibre chemisorbents - material for environmental protection», Fibre Chemistry, vol. 34, no. 6, pp. 456–465.

6. Soldatov, V. S. (2008) «Syntheses and the main properties of FIBAN fibrous ion exchangers», Solvent extraction andion exchange, vol. 26, no. 5, pp. 457–513.

7. Kosandrovich, E. G. and Soldatov, V. S. (2012) «Fibrous ion exchangers», Chapter 9 of the book “Ion exchangetechnology I: theory and materials”, in Inamuddin and Mohammad Luqman (ed.), Springer, United Kingdom, pp. 299–371.

8. «Dimethylaminopropylamine (DMAPA)», NEO Chemical company group, Available at: http://neochemical.ru/File/Dimetilaminopropilamin_.pdf, (Accessed 21.06.2016)

9. «Aminoethylpiperazine (AEP)», Product information from Dow Chemical, Available at: http://neochemical.ru/File/AEP.pdf, (Accessed 21.06.2016)

10. Soldatov, V. S., Kosandrovich, E. G., Mitskevich, D. E., Zhilinskaya, A. V. and Polkhovskii, E. M. (2012) Sposobpolucheniya voloknistogo poliamfolita [Method for preparation of fibrous polyampholite], BY, Pat. 15904

11. Babko, A. K. and Pyatnitskii, I. V. (1956) Kolichestvennyi analiz [Qualitative analysis], GNTI Khimicheskoiliteratury, Moscow, RU

12. Soldatov, V. S. (1998) «Potentiometric titration of ion exchangers», Reactive and Functional Polymers, no. 38, pp. 73–112.

13. Nesteronok, P. V. and Soldatov, V. S. (2013) «A method for determination of polyampholytes' acidity parameters»,Vestsi NAN Belarusi. Seryya khimіchnykh navuk [Proceedings of the National Academy of Sciences of Belarus. Chemistry Series], no. 2, pp. 3–36.

14. Kosandrovich, E. G. and Soldatov, V. S. (2004) «Ammonia sorption from air by fibrous sulfo cation exchangerFIBAN K-1», Vestsi NAN Belarusi. Seryya khimіchnykh navuk [Proceedings of the National Academy of Sciences of Belarus. Chemistry Series], no. 3, pp. 95–98.


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ISSN 1561-8331 (Print)
ISSN 2524-2342 (Online)