FORMATION AND PROPERTIES OF LANGMUIR–BLODGETT FILMS OF 2,4-HENEICOSANEDIONE WITH BORON NITRIDE PARTICLES
Abstract
It was found that incorporation of α-BN (the average particles size ~ 600 nm) into the structure of the HD Langmuir layer resulted in an increase of minimal area per molecule from 0.27 to 0.34 nm2 and wear stability of HD monolayer. Composite LB films of HD with α-BN particles can be used as protective coatings in precision friction units.
About the Authors
A. E. SalamianskiBelarus
Ph. D. (Chemistry), Senior Researcher.
K. I. Dubatouka
Belarus
Junior Researcher.
V. E. Agabekov
Belarus
Academician, D. Sc. (Chemistry)
References
1. Bhushan B., Principles and Applications of Tribology, John Wiley and Sons Ltd, Chichester, GB, 2013.
2. Solomyanskii A.E., Zhavnerko G.K. and Agabekov V.E., ″Tribological behavior of composite Langmuir–Blodgett films of triacontanoic acid″, Surface and Coatings Technology, 2013, vol. 227, pp. 62–64.
3. Solomyanskii A.E., Zhavnerko G.K. and Agabekov V.E., ″Tribological properties of Langmuir-Blodgett of diketones and fatty acids″, Zhurnal prikladnoi khimii [Journal of Applied Chemistry], 2012, vol. 85, no. 9, pp. 1539–1544.
4. Zhavnerko G.K., Agabekov V.E., Solomyanskii A.E., Chizhik S.A., Suslov A.A. and Chikunov V.V., GNU ″Institut khimii novykh materialov NAN Belarusi″, Ustroistvo dlya polucheniya na tverdoi poverkhnosti mono- ili mul’tisloinykh plenok amfifil’nykh soedinenii [A device for preparation of mono- or multilayer films of amphiphilic compounds on a solid surface], Baza patentov Belarusi, BY, Pat. 15411.
5. Chaney A. and Astle M.J., ″The reaction of certain unsymmetrical β-diketones with ethylmagnesium bromide″, Journal of Organic Chemistry, 1951, vol. 16, pp. 57–63.
6. Komkov O.Yu., ″Reciprocating microtribometer operating under small loads: design features and the procedure for specimen testing″, Trenie i iznos [Friction and wear], 2003, vol. 24, no. 6, pp. 642–648.
7. Song L., Ci L., Lu H., Sorokin P. B., Jin C., Ni J., Kvashnin A.G., Kvashnin D.G., Lou J., Yakobson B.I. and Ajayan P.M., ″Characterization of Atomic Hexagonal Boron Nitride″, Nano Letters, 2010, vol. 10, pp. 3209–3215.
8. Pasyuta V.M. and Goloudina S.I., ″A device for preparation of mono- and multilayer organic nanocomposites by Langmuir – Blodgett method″, Peterburgskii zhurnal elektroniki [St. Petersburg Electronics Journal], 2001, vol. 4, pp. 71–78.