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Proceedings of the National Academy of Sciences of Belarus, Chemical Series

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Adsorption capacity of binary surfactants mixtures at solution/air and solution/mineral material interfaces

https://doi.org/10.29235/1561-8331-2018-54-4-399-405

Abstract

The adsorption capacity on the interphase surfaces of solution / air and solution / mineral material of binary mixtures of anionic (alkylbenzenesulfonic acid and its sodium salt (ABSCNa)) and nonionic surfactants (Tween-80) was studied. It has been established that the adsorption interaction of binary mixtures of surfactants with the surface of quartz and dolomite is affected by the presence of potential-determining ions that activate the surface of mineral materials, the charge and hydration of the anionic antagonists, the nature of the intermolecular interactions between the surfactant-components of the mixture. It was shown that the ABSCNa / Tween-80 mixture, characterized by low adsorption capacity to the mineral materials under study and absence of interaction between the surfactant components of the mixture, has a maximum oil displacement capacity from the surface of dolomite and quartz.

About the Authors

O. N. Opanasenko
Institute of General and Inorganic Chemistry of the National Academy of Sciences of Belarus, Minsk
Belarus
Ph. D. (Chemistry), Head of the Laboratory


N. P. Krutko
Institute of General and Inorganic Chemistry of the National Academy of Sciences of Belarus, Minsk
Belarus
D. Sc. (Chemistry), Professor, Head of the Department


O. L. Zhigalova
Institute of General and Inorganic Chemistry of the National Academy of Sciences of Belarus, Minsk
Belarus
Ph. D. (Chemistry), Senior Researcher


O. V. Luksha
Institute of General and Inorganic Chemistry of the National Academy of Sciences of Belarus, Minsk
Belarus
Ph. D. (Chemistry), Senior Researcher


T. A. Kozinets
Institute of General and Inorganic Chemistry of the National Academy of Sciences of Belarus, Minsk
Belarus
Researcher


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ISSN 1561-8331 (Print)
ISSN 2524-2342 (Online)