Influence of the chemical structure of cation surfactants on the wetting process of rock-forming minerals
https://doi.org/10.29235/1561-8331-2019-55-2-142-148
Abstract
Interfacial interactions of cationic surfactants of various chemical structures at the solution / finely dispersed mineral material (quartz and dolomite) interface were studied. It is established that the modification of the surfaces of quartz and dolomite with cationic surfactants leads to a change in the structure and radius of the capillaries due to the formation of adsorption-solvate shells. The hydrophobic ability of cationic surfactants is determined by the structure of the hydrophilic part of their molecules – the balance of amino groups in the alkyl chains and the absence of steric hindrances during adsorption interaction with the surface of mineral materials. The mixture of surfactants containing six amino groups and a polyhydric alcohol glycerin has an effective hydrophobic ability from both aqueous and highly mineralized solutions.
About the Authors
O. N. Opanasenko
Institute of General and Inorganic Chemistry of the National Academy of Sciences of Belarus
Belarus
Belarus
Olga N. Opanasenko – D. Sc. (Chemistry), Associate Professor, Head of the Laboratory
9/1, Surganov Str., 220072, Minsk
N. P. Krutko
Institute of General and Inorganic Chemistry of the National Academy of Sciences of Belarus
Belarus
Belarus
Nikolay P. Krutko – Academian, D. Sc. (Chemistry), Professor, Head of the Department
9/1, Surganov Str., 220072, Minsk
O. L. Zhigalova
Institute of General and Inorganic Chemistry of the National Academy of Sciences of Belarus
Belarus
Belarus
Oksana L. Zhigalova – Ph. D. (Chemistry), Senior Researcher
9/1, Surganov Str., 220072, Minsk
O. V. Luksha
Institute of General and Inorganic Chemistry of the National Academy of Sciences of Belarus
Belarus
Belarus
Olga V. Luksha – Ph. D. (Chemistry), Senior Researcher
9/1, Surganov Str., 220072, Minsk
References
1. Palii А. О., Gorbunov А. T. The use of waterproofng agents for processing of wellbottom bands. Neftyanoe hozyajstvo = Oil industry, 1993, no. 10, pp. 64–65 (in Russian).
2. Gorbunov A. T., Shirokov V. A., Kryanov D. Yu. The use of cationic surfactants for increase of borehole productivity. Neftyanoe hozyajstvo = Oil industry, 1992, no. 9, pp. 20–22 (in Russian).
3. Washburn E. W. The dynamics of capillary flow. Physical review, 1921, vol. 17, no. 3, pp. 273–282. https://doi.org/10.1103/physrev.17.273
4. Theory. KRÜSS GmbH. 2008. Available at: http://www.kruss.info. (accessed 14 November 2008).
5. Owens D. K., Wendt R. C. Estimation of the surface free energy of polymers. Journal of Applied Polymer Science, 1969, vol. 13, no 8, pp. 1741–1747. https://doi.org/10.1002/app.1969.070130815
6. Siebold A., Walliser A., Nardin M., Oppliger M., Schultz J. Capillary rise for thermodynamic characterization of solid particle surface. Journal of Colloid and Interface Science, 1997, vol. 186, no 1, pp. 60–70. https://doi.org/10.1006/jcis.1996.4640
7. Opanasenko O. N., Zhigalova O. L., Luksha O. V. The regulation of colloidal chemical properties of cationic surfactants solutions with low molecular weight alcohols. Sviridovskie chteniya: sb. st. [Sviridov readings. Digest of articles]. Minsk, Belarusian State University, 2011, pp. 147–156 (in Russian).
8. Korolev M. I., Rogachev M. K. The selection of chemical composition for oil displacement from the water-flooded borehole. Inzhener-neftyanik = Oil-engineer, 2017, no 2. pp. 48–53 (in Russian).
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