Прямая трансформация i-стероидных метиловых эфиров в 6-кетоны: использование в синтезе брассиностероидов
https://doi.org/10.29235/1561-8331-2019-55-2-175-181
Анатацыя
Разработан одностадийный метод трансформации 3α,5-цикло-6β-метиловых эфиров стероидов в соответствующие 3α,5-цикло-6-кетоны – ключевые интермедиаты в синтезе брассиностероидов под действием метил(трифторметил)диоксирана. Возможности метода продемонстрированы на примере получения биосинтетического предшественника брассинолида – 3-дегидротеастерона.
Аб аўтарах
А. Гурский
Институт биоорганической химии Национальной академии наук Беларуси
Беларусь
Беларусь
В. Жабинский
Институт биоорганической химии Национальной академии наук Беларуси
Беларусь
Беларусь
В. Хрипач
Институт биоорганической химии Национальной академии наук Беларуси
Беларусь
Беларусь
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