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Proceedings of the National Academy of Sciences of Belarus, Chemical Series

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Structure formation in gypsum-magnesia materials for laying in the developed spaces of salt deposits

https://doi.org/10.29235/1561-8331-2019-55-3-359-368

Abstract

The influence of the preparation method, gypsum content and liquid-solid ratio on the process of hardening and properties of mixed gypsum-magnesia binders intended for laying in the developed space of salt areas has been studied. With the introduction of fillers – waste from the development of salt deposits and plasticizers – in them, filling mixtures, which are non-linear viscoplastic thixotropic systems with a certain period of stress and strain relaxation, have been obtained. The phase composition of hardening products, electrokinetic, rheological and physico-mechanical properties of the obtained plasticized filling mixtures depending on the method of injection, the type and content of plasticizers have been investigated. At optimum liquid-solid ratio and the plasticizer content of the mixture with low static and dynamic yield stress and effective viscosity and extended setting time have been obtained.

About the Authors

N. Ch. Belous
Institute of General and Inorganic Chemistry of the National Academy of Sciences of Belarus
Belarus

Natalia Ch. Belous – Ph. D. (Chemistry), Senior Researcher

9/1, Surganov Str., 220072, Minsk



S. P. Rodtsevich
Institute of General and Inorganic Chemistry of the National Academy of Sciences of Belarus
Belarus

Sofia P. Rodtsevich – Researcher

9/1, Surganov Str., 220072, Minsk



O. N. Opanasenko
Institute of General and Inorganic Chemistry of the National Academy of Sciences of Belarus
Belarus

Olga N. Opanasenko – D. Sc. (Chemistry), Head of the Laboratory of Oil and Organic-Mineral Dispersions

9/1, Surganov Str., 220072, Minsk



N. P. Krutko
Institute of General and Inorganic Chemistry of the National Academy of Sciences of Belarus
Belarus

Nikolay P. Krutko – Academician, D. Sc. (Chemistry), Head of the Department of Composite Materials

9/1, Surganov Str., 220072, Minsk



V. V. Shevchuk
Institute of General and Inorganic Chemistry of the National Academy of Sciences of Belarus
Belarus

Viacheslav V. Shevchuk – Corresponding Member of the National Academy of Sciences of Belarus, D. Sc. (Chemistry), Head of the Department of Mineral Fertilizers

9/1, Surganov Str., 220072, Minsk



References

1. Pechkovskii V. V., Aleksandrovich H. M., Pinaev G. F. Potassium Fertilizer Technology. Minsk, Vysheishaya shkola Publ., 1968, 264 p. (in Russian).

2. Kirichenko L. N., Sabirov R. H., Skvirskii L. Ya., Teterina N. N. Potash ore concentration flotation technology. Perm, Solikamsk Print., 2002. 484 p. (in Russian).

3. Chumakov L. S. Nature Preservation. Minsk, Sovremennaya shkola Publ., 2003. 300 p. (in Russian).

4. Wei-ying L. Concerning methods of coagulation and flocculation in water-treatment. Ind. Water and Wastewater, 2001, vol. 32, no. 2. pp. 37–39.

5. Kurenkov V. F. Polyacrylamide flocculants. Sorosovskii obrazovatel’nyi zhurnal = Soros Educational Journal, 1997, no. 7. pp. 57−63 (in Russian).

6. Vorob’ev P. D., Krut’ko N. P., Vorob’eva E. V., Cherednichenko D. V., Basalyga I. I. Peculiarities of the formation of polyacrylamide compound-based polyelectrolyte complexes in the course of the flocculation of clay-salt dispersions. Colloid Journal, 2007, vol. 69, no 5, pp. 552–556. https://doi.org/10.1134/s1061933x07050031

7. Baran’ Sh., Mesarosh R., Kozakova I., Shkvarla I. Kinetics and mechanism of flocculation of suspensions of bentonite and kaolin by polyelectrolytes and the strength of the floccules formed. Colloid Journal, 2009, vol. 71, no. 3, pp. 285−292. https://doi.org/10.1134/s1061933x09030016

8. Kurenkov V. F., Snigirev S. V., Len’ko O. A., Churikov F. I. The influence of anionic and cationic Flocculants Praestols on the flocculation of kaolin suspensions. Russian Journal of Applied Chemistry, 1999, vol. 72, no. 11, pp. 1892–1896 (in Russian).

9. Baran A. A., Gregori D. Flocculation of kaolin suspensions with cationic polyelectrolytes. Colloid Journal, 1996, vol. 58, no. 1, pp. 13−18 (in Russian).

10. Davlyud D. N., Vorobieva E. V., Layeuskaya Е. V., Krutko N. P., Vorobiev P. D., Сherednichenko D. V. Rheological properties and concentration cross-overs of polyacrylamide and anionic (co)polymers of аcrilamide in aqueous-salt solutions. Doklady Natsional’noi akademii nauk Belarusi = Doklady of the National Academy of Sciences of Belarus, 2017, vol. 61, no. 4, pp. 69–76 (in Russian)

11. Manzhay V. N., Klimova N. L. New features of the turbo method for studying dilute polymer solutions. Izvestiya Tomskogo politekhnicheskogo universiteta = Bulletin of the Tomsk Polytechnic University, 2006, vol. 309, no. 6, pp. 85–87 (in Russian).

12. Tambo N., Watanabe Y. Physical Aspects of Flocculation Process II. Contact Flocculation. Water Research, 1979, vol. 13, no. 5, pp. 441−448. https://doi.org/10.1016/0043-1354(79)90036-8


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ISSN 1561-8331 (Print)
ISSN 2524-2342 (Online)