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Proceedings of the National Academy of Sciences of Belarus, Chemical Series

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Role of nanostructured modifiers in composite corundum ceramics preparation

https://doi.org/10.29235/1561-8331-2019-55-4-400-414

Abstract

Influence of highly disperse nanostructured modifiers of alumina – magnesia, partially stabilized zirconia – on the consolidation processes of composite ceramics of industrial corundum powders annealed at 1600–1700 °C, changes of its microstructure and physico-mechanical properties is investigated. It is established, that due to processes of self-diffusion of active modifiers there is a distribution of their nanograins on the borders of miсroparticles of corundum powder. In addition, nanostructured modifiers fill a pore space that causes sliding of particles under mechanical and thermal loads of material and transfers the mechanism of fragile destruction to pseudo-plastic. The entered nanostructured modifiers promote the process of lamellar zones formation throughout the material that also strengthens its mechanical properties. The correlation of composite ceramics structure and their physico-mechanical characteristics are developed.

About the Authors

T. M. Ulyanova
Institute of General and Inorganic Chemistry of the National Academy of Sciences of Belarus
Belarus

Tatyana M. Ulyanova – Ph. D. (Chemistry), Leading Researcher

9/1, Surganov Str., 220072



N. P. Кrutko
Institute of General and Inorganic Chemistry of the National Academy of Sciences of Belarus
Belarus

Nikolay P. Krutko – Academician, D. Sc. (Chemistry), Professor, Director General of the State Research and Production Association “Chemical Products and Technologies»

9/1, Surganov Str., 220072



P. A. Vityaz
Presidium of the National Academy of Sciences of Belarus
Belarus

Petr A. Vityaz – Academician, D. Sc. (Engineering), Head of Establishment of the National Academy of Sciences of Belarus

99, Nezavisimosti Ave., 220023, Minsk



A. A. Shevchenok
Belarusian State Agrarian Technical University
Belarus

Aleksandr A. Shevchenok – Ph. D. (Engineering), Assistant Professor

Aleksandr A. Shevchenok – Ph. D. (Engineering), Assistant Professor



L. V. Оvseenko
Institute of General and Inorganic Chemistry of the National Academy of Sciences of Belarus
Belarus

Ludmila V. Ovseenko – Ph. D. (Chemistry), Deputy Director for Science and Innovation

9/1, Surganov Str., 220072



L. V. Тitova
Institute of General and Inorganic Chemistry of the National Academy of Sciences of Belarus
Belarus

Ludmila V. Titova – Researcher

9/1, Surganov Str., 220072



E. A. Кashaed
State Research and Production Powder Metallurgy Association
Belarus

Evgenij A. Kashaed – Researcher. Powder Metallurgy Institute

41, Platonov Str., 220071, Minsk



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ISSN 1561-8331 (Print)
ISSN 2524-2342 (Online)