Role of nanostructured modifiers in composite corundum ceramics preparation
https://doi.org/10.29235/1561-8331-2019-55-4-400-414
Abstract
Influence of highly disperse nanostructured modifiers of alumina – magnesia, partially stabilized zirconia – on the consolidation processes of composite ceramics of industrial corundum powders annealed at 1600–1700 °C, changes of its microstructure and physico-mechanical properties is investigated. It is established, that due to processes of self-diffusion of active modifiers there is a distribution of their nanograins on the borders of miсroparticles of corundum powder. In addition, nanostructured modifiers fill a pore space that causes sliding of particles under mechanical and thermal loads of material and transfers the mechanism of fragile destruction to pseudo-plastic. The entered nanostructured modifiers promote the process of lamellar zones formation throughout the material that also strengthens its mechanical properties. The correlation of composite ceramics structure and their physico-mechanical characteristics are developed.
About the Authors
T. M. UlyanovaBelarus
Tatyana M. Ulyanova – Ph. D. (Chemistry), Leading Researcher
9/1, Surganov Str., 220072
N. P. Кrutko
Belarus
Nikolay P. Krutko – Academician, D. Sc. (Chemistry), Professor, Director General of the State Research and Production Association “Chemical Products and Technologies»
9/1, Surganov Str., 220072
P. A. Vityaz
Belarus
Petr A. Vityaz – Academician, D. Sc. (Engineering), Head of Establishment of the National Academy of Sciences of Belarus
99, Nezavisimosti Ave., 220023, Minsk
A. A. Shevchenok
Belarus
Aleksandr A. Shevchenok – Ph. D. (Engineering), Assistant Professor
Aleksandr A. Shevchenok – Ph. D. (Engineering), Assistant Professor
L. V. Оvseenko
Belarus
Ludmila V. Ovseenko – Ph. D. (Chemistry), Deputy Director for Science and Innovation
9/1, Surganov Str., 220072
L. V. Тitova
Belarus
Ludmila V. Titova – Researcher
9/1, Surganov Str., 220072
E. A. Кashaed
Belarus
Evgenij A. Kashaed – Researcher. Powder Metallurgy Institute
41, Platonov Str., 220071, Minsk
References
1. Lukin E. S. Modern high density oxide ceramics with adjustable micro structure. Part 2. Justification of the principles of the choice of the modifying additives, influencing extent of agglomeration of oxide ceramics. Ogneupory i tekhnicheskaya keramika = Refractory materials and technical ceramics, 1996, no. 5, pp. 2–13 (in Russian).
2. Zakharov A. I., Surkov G. M. Fundamentals of ceramics technology. Microstructure, properties and principles of receiving pottery. Steklo i keramika = Glass and ceramics, 2000, no. 4, pp. 12–16 (in Russian).
3. Toyohiko Y., Pengyuan L., Masamitsu I. Room and High Temperatue Mechanical Properties of 2D-Alumina Fiber Reinforced Alumina Composite Fabricated By Hot-Pressing. Proc. of the 5 Int. Conf. HT CMC5, Publ. by Amer. Cer. Soc., Seattle, 2005. Seattle, USA, 2005, pp. 247–252.
4. Andrievsky R. A., Ragulya A. V. Nanostructural materials. Moscow, Akademiya Publ., 2005. 192 p. (in Russian).
5. Zholudev D. S., Grigoriev S. S., Panfilov P. E., Zaytsev D. V. Justification of use of ceramics on the basis of aluminum oxide by means of studying of its mechanical properties. Sovremennye problemy nauki i obrazovaniya = Modern problems of science and education, 2014, no. 3, pp. 520–526 (in Russian).
6. Tarasova S. V. Corundum ceramics for heads of endoprostheses of a coxofemoral joint. Moscow, 2003, 16 p. (in Russian).
7. Ulyanova T. M., Vityaz P. A., Krutko N. P., Titova L.V., Medichenko S. V. High-porous fibrous fillers and modifiers of composite materials. Porous permeable materials: technologies and products on their basis. Minsk, Diatekh Publ., 2011, pp. 384–393 (in Russian).
8. Amelina O. D. Development of unsintered technology of vacuum-dense corundum ceramics of VC100 group for needs of the electronic equipment. Moscow, 2016, 17 p. (in Russian).
9. Mashimo T., Tsumoto K., Nakamara K. High pressure phase transformation of corundum (α-Al2O3) observed under shock compression. Geophysical Research Letters, 2000, vol. 27, no. 14, pp. 2021–2024. https://doi.org/10.1029/2000gl008490
10. Gregg, S., Sing K. Adsorption, Surface Area and Porosity. London, Academic Press, 1982. 303 p.
11. Umanskii Ya. S. Rentgenografiya of metals and semiconductors. Moscow, Metallurgiya Publ., 1969. 265 p. (in Russian).
12. Ulyanova T. M., Krut’ko N. P., Vityaz P. A., Titova L. V. Investigation of Nanostructured Oxides: Synthesis, Structure and Properties. Journal of Nanoscience and Nanotechnology, 2010, vol. 10, pp. 2107–2112. https://doi.org/10.1166/jnn.2011.3138
13. Ilyushchenko A. Ph., Shevchenok A. A, Ulyanova T. M., Titova L. V., Kulbitskaya L. V., Stepkin M. O. Аlumina ceramics modified by nanostructured AL2O3–gO whiskers. Proceedings of the European Congress and Exibition on Advanced Materials and Processes «Euro PM–2013», Chalmers University of Technology, Gothenburg, Sweden, 2013, pp. 13106–13111.