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Proceedings of the National Academy of Sciences of Belarus, Chemical Series

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Extraction of food synthetic dyes from aqueous solutions with liquid ion exchanger

https://doi.org/10.29235/1561-8331-2020-56-1-58-66

Abstract

Synthetic dyes (SD) are widely used in modern food industry. According to the requirements of the Customs Union Technical Regulation, the content of SD is standardized, therefore, universal and express methods of analysis are needed. The main difficulty in determining them in food products is the separation from the matrix components such as proteins, fats, carbohydrates, anthocyanins. For this purpose, the extraction of commonly used synthetic food dyes from aqueous solutions using a liquid ion exchanger trioctylamine (TOA), dissolved in chloroform and toluene, was studied. Distribution coefficients (D) and recovery rates (R, %) were calculated. It has been established that TOA quantitatively extracts SD from aqueous acidified solutions, while they can be completely reextracted at pH > 8–9.

About the Authors

E. M. Pliashak
Scientific Practical Center of Hygiene
Belarus

Yekatsiaryna M. Pliashak – doctoral student at the Department of analytical chemistry of Belarusian State University; Junior Researcher. Scientific Practical Center of Hygiene

Leningradskaya str., 14, 220030, Minsk;

Akademicheskaya Str., 8 , 220012, Minsk



S. M. Leschev
Belarusian State University
Russian Federation

Sergey M. Leschev – D. Sc. (Chemistry), Professor

14, Leningradskaya Str., 220030, Minsk



A. I. Palianskikh
Scientific Practical Center of Hygiene
Russian Federation

Alena I. Palianskikh – Ph. D. (Chemistry), Senior Researcher. Scientific Practical Center of Hygiene

8, Akademicheskaya Str., 220012, Minsk



L. L. Belusheva
Scientific Practical Center of Hygiene
Russian Federation

Liudmila L. Belusheva – Head of the Laboratory

8, Akademicheskay Str., 220012, Minsk



M. F. Zayats
Belarusian State University
Russian Federation

Mikhail F. Zayats – Ph. D. (Chemistry), Head of the Department

14, Leningradskaya Str., 220030, Minsk

 



References

1. Mursalova M.G., Saidalieva S. Z. Pishchevye krasiteli [Food dyes] Povyshenie kachestva i bezopasnosti pishchevykh produktov : materialy V Vseros. nauch. konf., Makhachkala, 27 okt. 2015-28 okt. 2016 g. [Improving food quality and safety. Materials of the V All-Russian Scientific Conference]. Makhachkala, 2016, p. 177 (in Russian).

2. Shaulina L. P., Korsun L. N. Quality control and food safety of food raw materials. Irkutsk, ISU Publ., 2011. 111 p. (in Russian).

3. TR TS 029/2012. Safety requirements of food additives, flavorings and processing aids. Minsk, Ekonomenergo Publ., 2012. 308 p. (in Russian).

4. State Standart 32050-2013. Food products. Methods of identification and determination of the mass fraction of synthetic dyes in caramel. Moscow, Standartinform, 2014. 24 p. (in Russian).

5. Li X. Q., Zhang Q. H., Ma K., Li H. M., Guo Z. Identification and determination of 34 water-soluble synthetic dyes in foodstuff by high performance liquid chromatography–diode array detection–ion trap time-of-flight tandem mass spectrometry. Food Chemistry, 2015, vol. 182, pp. 316–326. https://doi.org/10.1016/j.foodchem.2015.03.019.6

6. Chibisova M. V., Berezkin V. G. Definition of synthetic dyes in food by thin-layer chromatography, UVand IRspectrocsopy. Sorbtsionnye i khromatograficheskie processy = Sorption and Chromatographic Processes, 2011, vol. 11, no 2, pp. 219–228 (in Russian).

7. Shestopalova N. B., Chernova R. K., Zhukova D. V., Tokareva M. E. Determination of synthetic dyes in food. Ekologicheskie problemy promyshlennykh gorodov : sb. nauch. tr. po materialam 6-i Vseros. nauch.-prakt. konf. s mezhdunar. uchastiem. Ch. 1 [Environmental problems of industrial cities: 6th all-Russian scientific and practical conference with international participation. Part. 1]. Saratov, 2013, pр. 314–315 (in Russian).

8. Korenman Y. I., Sukhanov P. T., Sannikova N. Y. Extraction of monoazo dyes by hydrophilic extractants from aqueous solutions. Vestnik Voronezhskogo gosudarstvennogo universiteta inzhenernykh tekhnologiy = Proceedings of the Voronezh State University of Engineering Technologies, 2012, no. 3, pp. 115–117 (in Russian).

9. Bento W., Lima B. P., Paim A. P. S. Simultaneous determination of synthetic colorants in yogurt by HPLC. Food Chemistry, 2015, vol. 183, pp. 154–160. https://doi.org/10.1016/j.foodchem.2015.03.050

10. Palianskikh A. I., Belyshava L. L., Fiodarava T. A., Filatchankava E. V., Pliashak Y. M. Control procedure for synthetic dyes content in food products. Khimicheskaya bezopasnost’ = Chemical Safety Science, 2019, vol. 3, no 1 (5), pp. 166–181 (in Russian).

11. Lurie Yu.Yu. Handbook of analytical chemistry. Moscow, Khimiya Publ., 1971. 456 р. (in Russian).


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ISSN 1561-8331 (Print)
ISSN 2524-2342 (Online)