3D computer model of the Ag-Cu-Ni T-x-y diagram: verification of sections in the atlas of phase diagrams for lead-free soldering
https://doi.org/10.29235/1561-8331-2021-57-1-15-24
Abstract
Spatial (three-dimensional - 3D) computer model of the T-x-y diagram of the Ag - Cu - Ni system, which is promising for the development of environmentally friendly solders, is presented. The model is constructed on the basis of published data on the binary systems forming this ternary system, the concentration projection of the liquidus surfaces, and four isothermal sections. It is shown that the phase diagram (PD) consists of 14 surfaces and 9 phase regions. The adequacy of the model is confirmed by comparing the isothermal sections and the liquidus projection.
Supporting agencies: This work was been performed undeI the pIogIam of Institute of Physical MateIials Science of the Siberian Branch of the Russian Academy of Sciences (project 0336-2019-0008).
About the Authors
M. D. Parfenova
Institute of Physical Materials Science of the Siberian Branch of the Russian Academy of Sciences
Russian Federation
Russian Federation
Maria D. Parfenova - Ph. D. student. Institute of Physical Materials Science of the Siberian Branch of the Russian Academy of Sciences.
6, Sakhyanova Str., Ulan-Ude, Republic of Buryatia.
V. P. Vorob'eva
Institute of Physical Materials Science of the Siberian Branch of the Russian Academy of Sciences
Russian Federation
Russian Federation
Vera P. Vorob'eva - D. Sc. (Physics-Mathematics), Associate Professor, Leading Researcher. Institute of Physical Materials Science, Siberian Branch of the Russian Academy of Sciences.
6, Sakhyanova Str., Ulan-Ude, Republic of Buryatia.
V. I. Lutsyk
Institute of Physical Materials Science of the Siberian Branch of the Russian Academy of Sciences
Russian Federation
Russian Federation
Vasily I. Lutsyk - D. Sc. (Chemistry), Professor, Head of the Computer-aided Materials Design Sector. Institute of Physical Materials Science, Siberian Branch of the Russian Academy of Sciences.
6, Sakhyanova Str., Ulan-Ude, Republic of Buryatia.
References
1. Dinsdale A., Watson A., Kroupa A., Vrest’al J., Zemanova A., Vi'zdal J. Atlas of Phase Diagrams for Lead-Free Soldering. COST 531. Vol. 1. Brno, Czech Republic: Vydavatelstvi KNIHAR, 2008. 289 p.
2. Dinsdale A., Kroupa A., Watson A., Vrest’al J., Zemanova A., Broz P. Handbook of High-Temperature Lead-Free Solders: Atlas of Phase Diagrams. COSTMP0602. Vol. 1. Brno, Ceska republika: COST office, Brussels, Belgium, 2012. 218 pp.
3. Watson A. (ed.) Handbook of High-Temperature Lead-Free Solders: Materials Properties. COST Action MP0602. Vol. 2. Brno, Ceska republika: COST office, Brussels, Belgium, 2012. 145 pp.
4. Lutsyk V. I., Vorob'eva V. P. Three-Dimensional Model of Phase Diagram of Au-Bi-Sb System for Clarification of Thermodynamic Calculations. Russian Journal of Physical Chemistry, 2015, vol. 89, no. 10, pp. 1715-1722. https://doi.org/10.1134/S0036024415100192
5. Lutsyk V. I., Vorob'eva V. P., Shodorova S. Ya. Determining the Conditions for Changes of the Three-Phase Reaction Type in a V-Zr-Cr System. Russian Journal of Physical Chemistry, 2015, vol. 89, no. 13, pp. 2331-2338. https://doi.org/10.1134/S0036024415130245
6. Lutsyk V. I., Vorob'eva V. P. 3D Model of the T-x-y Diagram of the Bi-In-Sn System for Designing Microstructure of Alloys. Russian Journal ofInorganic Chemistry, 2016, vol. 61, no. 2, pp. 188-207. https://doi.org/10.1134/S0036023616020121
7. Lutsyk V. I., Vorob'eva V. P. 3D Verification of the T-x-y Diagram of the Ag-Au-Bi System Using a 3D Computer Model. Russian Journal ofInorganic Chemistry, 2016, vol. 61, no. 7, pp. 858-866. https://doi.org/10.1134/S0036023616070123
8. Lutsyk V. I., Vorob'eva V. P. 3D Computer Models of the T-x-y Diagrams, Forming the Fe-Ni-Co-FeS-NiS-CoS Subsystem. Russian Journal of Physical Chemistry A, 2017, vol. 91, no. 13, pp. 2593-2599. https://doi.org/10.1134/S0036024417130131
9. Lutsyk V., Zelenaya A. Concentration Fields of the Ternary Systems and Trajectory of Phases in T-x-y Diagrams. Journal of Physics: Conference Series, 2017, vol. 790, is. 1, pp. 012020. https://doi.org/10.1088/1742-6596/790/1/012020
10. Lutsyk V. I., Vorob'eva V. P. Verification of Phase Diagrams by Three-Dimension Computer Models. Modern Chemistry & Applications, 2017, vol. 5, no. 2, pp. 215. https://doi.org/10.4172/2329-6798.1000215
11. Lutsyk V. I., Vorob'eva V. P., Zelenaya A. E. 3D Computer Models of the Ag-Sb-Sn and MgO-Al2O3-SiO2 T-x-y DiagIams. Acta Physica Polonica A, 2018, vol. 133, no. 4, pp. 763-766. https://doi.org/10.12693/APhysPolA.133.763
12. Lutsyk V. I., Vorob'eva V. P., Zelenaya A. E. 3D Computer Model of the Ni-Cu-NiS-Cu2S Subsystem T-x-y Diagram above 575 oC. Russian Journal of Physical Chemistry, 2019, vol. 93, no. 13, pp. 2593-2599. https://doi.org/10.1134/S0036024419130156
13. Lutsyk V. I., Vorob'eva V. P. Computer Models of Eutectic Type T-x-y Diagrams with Allotropy. Two Inner Liquidus Fields of Two Low-Temperature Modifications of the Same Component. Journal of Thermal Analysis & Calorimetry, 2010, vol. 101, no. 1, pp. 25-31. https://doi.org/10.1007/s10973-010-0855-0
14. Shepelevich V. G., Gusakova O. V., Gusakova S. V., Metto E. S. Structure and Properties of Rapidly Solidifying Foils Sn - 14 at.% In - 6.5 at.% Zn. Vestsi Natsyyanal'nai akademii navuk Belarusi. Seryya fizika-technichnych navuk = Proceedings of the National Academy of Sciences of Belarus. Physical-technical series, 2020, vol. 65, no. 3, pp. 292-298 (in Russian). https://doi.org/10.29235/1561-8358-2020-65-3-292-298
15. Vorob'eva V. P., Lutsyk V. I., Shodorova S. Ya., Nasrulin E. R. 3D Model of the In-Sn-Zn T-x-y Diagram for Alloys MicIostIuctuIe Design. Vestnik NovGU [Bulletin of Novgorod State University], 2015, no. 6(89), pp. 67-74 (in Russian).
16. de Cesaris P. Sui sali di Roussin. Gazzetta chimica Italiana, 1908, vol. 38, pp. 285-299 (quoted [1]).
17. Guertler W., Bergmann A. Z. Metallkde, 1933, vol. 25, pp. 53-57 (quoted [1]).
18. Siewert T. A., Heinen R. W. Recent Look at Ag-Cu-Ni System. Metallurgical Transactions A, 1977, vol. 8A, no. 3, pp. 515-518. https://doi.org/10.1007/bf02661766
19. Luo H.-T., Chen S.-W. Phase equilibria of the ternary Ag-Cu-Ni system and the interfacial reactions in the Ag-Cu/Ni couples. Journal of Materials Science, 1996, vol. 31, p. 5059-5067. https://doi.org/10.1007/bf00355906
20. Liu X.J., Gao F., Wang C.P., Ishida K. Thermodynamic Assessment of the Ag-Ni Binary and Ag-Cu-Ni Ternary Systems. Journal of Electronic Materials, 2008, vol. 37, no. 2, pp. 210-217. https://doi.org/10.1007/s11664-007-0315-1
21. Raghavan V. On Nanomaterials and Phase Diagrams. Journal of Phase Equilibria and Diffusion, 2015, vol. 36, pp. 89-91. https://doi.org/10.1007/s11669-015-0361-y
22. Kroupa A., Vykoukal V., Kanaa T., Zemanova A., Pinkas J., Sob M. The Theoretical and Experimental Study of the Sb-Sn Nano-Alloys. Calphad, 2019, vol. 64, pp. 90-96. . https://doi.org/10.1016/j.calphad.2018.11.004
23. Hajra J. P., Acharya S. Thermodynamics and Phase Equilibria Involving Nano Phases in the Cu-Ag System. Journal of Nanoscience and Nanotechnology, 2004, vol. 4, no. 7, pp. 899-906. https://doi.org/10.1166/jnn.2004.088
24. Garzel G., Janczak-Rusch J., Zabdyr L. Reassessment of the Ag-Cu Phase Diagram for Nanosystems Including Particle Size and Shape Effect. Calphad, 2012, vol. 36, pp. 52-56. https://doi.org/10.1016/j.calphad.2011.11.005
25. Jabbareh M. A., Monji F. Thermodynamic Modeling of Ag-Cu Nanoalloy Phase Diagram. Calphad,2018, vol. 60, pp. 208-213. https://doi.org/10.1016/j.calphad.2018.01.004
26. Sopousek J., Vrestal J., Pinkas J., Broz P., Bursik J., Styskalik A., Skoda D., Zobac O., Lee J. Cu-Ni Nanoalloy Phase Diagram - Prediction and Experiment. Calphad, 2014, vol. 45, pp. 33-39. https://doi.org/10.1016/j.calphad.2013.11.004
27. Gaudry M., Cottancin E., Pellarin M., Lerme J., Arnaud L., Huntzinger J. R., Vialle J. L., Broyer M., Rousset J. L., Treilleux M., Melinon P. Size and Composition Dependence in the Optical Properties of Mixed (Transition Metal/Noble Metal) Embedded Clusters. Physical Review B, 2003, vol. 67, iss. 15, 155409. https://doi.org/10.1103/PhysRevB.67.155409
28. Mundotiya B. M., Srivastava C. Ag-Ni Nanoparticles: Synthesis and Phase Stability. Electrochemical and Solid-State Letters, 2012, vol. 15, no. 5, pp. K41-K44. https://doi.org/10.1149/2.esl120008
29. Srivastava C., Mundotiya B. M. Size and Solid Solubility in Electrodeposited Ag-Ni Nanoparticles. Materials Science Forum, 2012, vol. 736. https://doi.org/10.4028/www.scientific.net/MSF.736.21
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