New methods of acid hydrolysis of cellulose and plant raw materials
https://doi.org/10.29235/1561-8331-2021-57-1-119-128
Abstract
Prospects for the development of hydrolysis production are determined by the relevance of industrial use of plant biomass to replace the declining reserves of fossil organic raw materials and increasing demand for ethanol, especially for its use as automobile fuel, protein-containing feed additives that compensate for protein deficiency in feed production, and other products. Based on the review of the research results presented in the scientific literature, the analysis of modern methods of liquid-phase acid hydrolysis of cellulose and various types of plant raw materials, including those that differ from traditional ones, is performed. The main directions of increasing its efficiency through the use of new catalytic systems and process conditions are identified. It is shown that the most promising methods for obtaining monosaccharides in hydrolytic processing of cellulose and microcrystalline cellulose, pentosan-containing agricultural waste and wood, are methods for carrying out the process at elevated and supercritical temperatures (high-temperature hydrolysis), the use of new types of solid-acid catalysts and ionic liquids.
Keywords
About the Author
V. S. BoltovskyBelarus
Valeriy S. Boltovskiy - D. Sc. (Engineering), Associate Professor, Professor, Belarusian State Technological University.
13a, Sverdlova Str., 220006, Minsk.
References
1. Sharkov V. I., Sapotnitskiy S. A., Tumanov I. F. Hydrolysis Production Technology] . Moscow, Lesnaya promyshlennost' Publ., 1973. 408 p. (in Russian).
2. Korol'kov I. I. Percolation hydrolysis of plant materials. Moscow, Lesnaya promyshlennost' Publ., 1978. 263 p. (in Russian).
3. Khol'kin Yu. I. Hydrolysis Production Technology. Moscow, Lesnaya promyshlennost' Publ., 1989. 496 p. (in Russian).
4. Boltovsky V. S. Hydrolytic processing of polysaccharide components of plant biomass: challenges and prospects. Vestsi Natsiyanal'nay akademii navuk Belarusi, seriya khimicheskikh nauk = Proceedings of the National Academy of Sciences of Belarus. Chemical series, 2014, no. 1, pp. 118-123 (in Russian).
5. Bolotnikova O. I., Mikhailova N. P., Ginak A. I. Acid and enzymatic hydrolysis of non- food-based biomass sources: prospects for industrial implementation. Izvestiya SPbGTI(TU): seriya 1. Khimiya i khimicheskaya tekhnologiya. Organicheskiy sintez i biotekhnologiya = Bulletin of the Saint Petersburg State Institute of Technology (Technical University): series 1. Chemistry and chemical technology. Organic synthesis and biotechnology, 2017, no. 39, pp. 89-95 (in Russian). https://doi.org/10.15217/issn1998984-9.2017.39.89
6. Grigoryevа O. N., Kharina M. V. Acid hydrolysis of lignocellulosic raw materials in bioethanol production technology. Vestnik tekhnologicheskogo universiteta = Bulletin of the Technological University, 2016, vol. 19, no. 10, pp. 128-132 (in Russian).
7. Kupiainen, L., Ahola J., Tanskanen J. Distinct effect of formic and sulfuric acids on cellulose hydrolysis at high temperature. Industrial & Engineering Chemistry Research , 2012, vol. 51, no. 8, pp. 3295-3300. https://doi.org/10.1021/ie202323u
8. Chu Chen-Yeon, Wu Shu-Yii, Tsai Chun-Yu, Lin Chiu-Yue. Kinetics of cotton cellulose hydrolysis using concentrated acid and fermentative hydrogen production from hydrolysate. International Journal of Hydrogen Energy, 2011, vol. 36, no. 14, pp. 8743-8750. https://doi.org/10.1016/j.ijhydene.2010.07.072
9. Zhao Yan, Lu Wen-Jing, Wang-Hong-Tao. Supercritical hydrolisis of cellulose for oligosaccharide production in cjmbinet technolodgy. International Journal of Hydrogen Energy, 2009, vol. 150, no. 2-3, pp. 411-417. https://doi.org/10.1016/j.ijhydene.2010.07.072
10. Cantero Danilo A., Sanchez Tapia Angel, Dolores Bermejo M., Jose Cocero M. Pressure and temperature effecton cellulose hydrolysis in pressurized water. Chemical Engineering Journal, 2015, no. 276, pp. 145-154. https://doi.org/10.1016/j.cej.2015.04.076
11. Zhang M., Gong G., Hui K. S., Hui K. N., Liu L. Hydrolysis of microcrystalline cellulose for fermentable ehexosein supercritical water. Journal of Energy Engineering, 2015, vol. 141, no 4, pp. 401-403. https://doi.org/10.1061/(ASCE)EY.1943-7897.0000218
12. Sasaki Chizuru, Sumimoto Keisuke, Asada Chikako, Nakamura Yoshitoshi Direct hydrolysis of cellulose to glucose using ultra-high temperature and pressures team explosion. Carbohydr. Polym.: Scientific and Technological Aspects of Industrially Important Polysaccharides, 2012, vol. 89, no 1, pp. 298-301. https://doi.org/10.1016/j.carbpol.2012.02.040
13. Morales-delaRosa Silvia, Campos-Martin Jose M., FierroJose L. G. High glucose yields from the hydrolysis of cellulose dissolved in ionic liquids. Chemical Engineering Journal, 2012, no. 181-182, pp. 538-541. https://doi.org/10.1016/j.carbpol.2012.02.040
14. Zhuo Kelei, Du Quanzhou, Bai Guangyue, Wang Congyue, Chen Yujuan, Wang Jianji. Hydrolysis of cellulose catalyzed by novel acidic ionic liquids. Carbohydr. Polym. Scientific and Technological Aspects of Industrially Important Polysaccharides, 2015, vol. 115. pp. 49-53. https://doi.org/10.1016/j.carbpol.2014.08.078
15. Guo Haixin, Lian Youfen, Yan Lulu, Qi Xinhua, Smith Richard Lee (Jr). Cellulose-derived superparamagnetic carbonaceous solid acid catalyst for cellulose hydrolysis in anionic liquid or aqueous reaction system. Green Chem.: An International Journaland Green Chemistry Resource, 2013, vol. 15, pp. 2167-2174. https://doi.org/10.1039/C3GC40433A
16. Onda A. Selective hydrolysis of cellulose and polysaccharides into sugars by catalytic hydrothermal method using sulfonated activated-carbon. Journal of the Japan Petroleum Institute, 2012, vol. 55, no. 2, pp. 73-86. https://doi.org/10.1627/jpi.55.73
17. Tian J., Fang C., Cheng M., Wang X. Hydrolysis of cellulose ove CsxH3-xP12O40 (x = 1-3) heteropolyacid catalysts. Chemical Engineering & Technology , 2011, vol. 34, pp. 482-486. https://doi.org/10.1002/ceat.201000409
18. Liu Min, Jia Songyan, Gong Yanyan, Song Chunshan, Guo Xinwen. Effective hydrolysis of cellulose in to glucose over sulfonated sugar-derived carbon in an ionic luquid. Industrial & Engineering Chemistry Research, 2013, vol. 52, no. 24, pp. 8167-8173. https://doi.org/10.1021/ie400571e
19. Bai Yuan-Yuan, Xiao Ling-Ping, Sun Run-Cang. Efficient hydrolyzeation of cellulose in ionic liquid by novel sulfonated biomass-based catalysts. Cellulose, 2014, vol. 21, no. 4, pp. 2327-2336. https://doi.org/10.1021/ie102487w
20. Gurgel L. V. A., Marabezi K., Zanbom M. D., Da Silva A. A. Dilute acid hydrolysis of sugar cane bagasse at high temperature:A kinetic study of cellulose saccharification and glucose decomposition. Pt. I. Sulfuric acid as the catalyst. Industrial & Engineering Chemistry Research, 2012, vol. 51, no. 3, pp. 1173-1185. https://doi.org/10.1021/ie2025739
21. Um Byung-Hwan, Bae Sung-Ho. Statistical methodology for optimizing the dilute acid hydrolysis of sugarcane bagasse. Korean Journal of Chemical Engineering, 2011, vol. 28, no. 5, pp. 1172-1176. https://doi.org/10.1007/s11814-011-0058-9
22. Lopez Y., Gullon D., Puls J., Parajo J., martin C. Dilute acid pretreatment of starch-containing rice hulls for ethanol production. Holzforschung, 2011, vol. 65, no. 4, pp. 467-473. https://doi.org/10.1515/hf.2011.082
23. Zhu Tao, Li Pingli, Wang Xiaowei, Yang Wandian, Chang Heying, Ma Sai Optimization of formic acid hydrolysis of corn cob in xylose production. Korean Journal of Chemical Engineering, 2014, vol. 31, no. 9, pp. 1624-1631. https://doi.org/10.1007/s11814-014-0073-8
24. Kim Tae Hyun. Sequential hydrolysis of hemicellulose and lignin in lignocellulosic biomass by two-stage percolation process using dilute sulfuric acid and ammonium hydroxide. Korean Journal of Chemical Engineering, 2011, vol. 28, no. 11, pp. 2156-2162. https://doi.org/10.1007/s11814-011-0093-6
25. Kleshchevnikov L. I., Loginova I. V., Kharina M. V., Emel'yanov V. M. High-temperature hydrolysis of fruit shells of oats with sulfurous acid. Vestnik Kazanskogo tekhnologicheskogo universiteta = Bulletin of Kazan Technological University, 2015, vol. 18, no. 19, pp. 254-256 (in Russian).
26. Vaneeva R. T., Anan'eva O. V., Bariev R. A., Mukhametdinova A. F. Kinetics study and optimization of the process of high-temperature hydrolysis of a mixture of wheat straw and bran with phosphoric acid. Vestnik tekhnologicheskogo universiteta = Bulletin of Technological University, 2020, vol. 23, no. 1, pp. 43-45 (in Russian).
27. Yin W.-P., LiX., Ren Y.-L., Zhao S., Wang J.-J. Selective hydrolysis of lignocelluloses from corn stalk in anionic liquid. Journal of Applied Polymer Science, 2013, vol. 129, no. 1, pp. 472-479. https://doi.org/10.1002/app.38759
28. Si Wenqing, Li Yichen, Zheng Jie, WeiShun‘an, Wang Dan. Enhanced hydrolysis of bamboo biomass by chitosan based solid acid catalyst with surfactant addition in ionic liquid. Carbohydr. Polym.: Scientific and Technological Aspects of Industrially Important Polysaccharides, 2017, vol. 174, pp. 154-159. https://doi.org/10.1016/j.carbpol.2017.05.082
29. Li Sen, Qian Elka W., Shibata Tomohiro, Hosomi Masaaki. Catalytic hydrothermal saccharification of rice straw using mesoporous silica-based solid acid catalysts. Journal of the Japan Petroleum Institute, 2012, vol. 55, no. 4, pp. 250-260. https://doi.org/10.1627/jpi.55.250
30. Hermiati Euis, Azuma Jun-ichi, Tsubaki Shuntaro, Mangunwidjaja Djumali, Sunarti Titi C., Suparno Ono, Prasetya Bambang. Improvement of microwave-assisted hydrolysis of cassava pulp and tapioca flour by addition of activeated carbon. Carbohydr. Polym.: Scientific and Technological Aspects of Industrially Important Polysaccharides, 2012, vol. 87, no. 1, pp. 939-942. https://doi.org/10.1016/j.carbpol.2011.08.033
31. Ablaev A. R., Kharina M. V., Khramova I. A., Emel'yanov V. M. Investigation of kinetics of hightemperature hydrolysis of birch sawdust with sulfurous acid. Bashkirskiy khimicheskiy zhurnal = Bashkir Chemical Journal, 2014, vol. 21, no. 3, pp. 86-89 (in Russian).
32. Mc. Donald Armando G., Clark Tomas A. Characterization of oligosaccharides releazed by steam explosion of sulphardioxide impregnated Pinus radiata. Journal of Wood Chemistry and Technology, 1992, vol. 12, no. 1, pp. 55-78. https://doi.org/10.1080/02773819208545050
33. Zhang Taiying, Kumar Rajeev, Wyman Charles E. Sugar yields from dilute oxalic acid pretreatment of maple wood compared to those with other dilute acids and hot water. Carbohydr. Polym.: Scientific and Technological Aspects of Industrially Important Polysaccharides, 2013, vol. 92, no. 1, pp. 334-344. https://doi.org/10.1016/j.carbpol.2012.09.070
34. Boltovskiy V. S., Gal'perin A. S. Hydrolytic destruction of wood polysaccharides in the microwave field. Gidroliznaya i lesokhimicheskaya promyshlennost' [Hydrolysis and wood chemical industry], 1993, no. 3, pp. 5-6 (in Russian).
35. Boltovskii V. S., Gal¢perin A. S. Hydrolytic destruction of wood polysaccaharides in a microwave field. Hydrolysis and wood chemistry, 1993, no. 5, pp. 14-18.
36. Kustov L. M., Vasina T. V., Ksenofontov V. A. Ionic liquids as catalytic media. Rossiyskiy khimicheskiy zhurnal (Zhurnal Rossiyskogo khimicheskogo obshchestva im. D. I. Mendeleeva) = Russian Journal of General Chemistry, 2004, vol. XLVIII, no. 6, pp. 13-35 (in Russian).