Protective Langmuir–Blodgett coatings based on long-chain fatty acids
https://doi.org/10.29235/1561-8331-2021-57-4-480-487
Abstract
The morphology and tribotechnical properties of Langmuir–Blodgett (LB) monolayers and multilayers of some fatty acids, such as nervonic (NA), cerotic (CA) and montanic acids (OCA), was investigated. It was established that the wear resistance of silicon surface coated by LB monolayer of OCA is greater by 11 and 1.3 times in comparison with the LB monomolecular films of NA and CA, respectively. The multilayer of OCA, formed by 140 layers, increases the stability of steel surface by 35 times.
About the Authors
V. M. Akulova
Institute of Chemistry of New Materials of the National Academy of Sciences of Belarus
Belarus
Belarus
Viktoryia M. Akulova – Ph. D. Student, Junior Researcher
36, F. Skorina str., 220141, Minsk, Republic of Belarus
A. E. Salamianski
Institute of Chemistry of New Materials of the National Academy of Sciences of Belarus
Belarus
Belarus
Aliaksandr E. Salamianski – Ph. D. (Chemistry), Leading Researcher
36, F. Skorina str., 220141, Minsk, Republic of Belarus
G. B. Melnikova
A.V. Luikov Heat and Mass Transfer Institute of the National Academy of Sciences of Belarus
Belarus
Belarus
Galina B. Melnikova – Ph. D. (Chemistry), Senior Researcher
15, P. Brovki str., 220072, Minsk, Belarus
D. A. Nekrashevich
Institute of Chemistry of New Materials of the National Academy of Sciences of Belarus
Belarus
Belarus
Darya A. Nekrashevich – Junior Researcher
36, F. Skorina str., 220141, Minsk, Republic of Belarus
Yu. V. Sinkevich
Belarusian National Technical University
Belarus
Belarus
Yurii V. Sinkevitch – D. Sc. (Engineering), Professor
9, B. Khmelnitsky str., 220013, Minsk, Belarus
I. G. Chishankov
Institute of Chemistry of New Materials of the National Academy of Sciences of Belarus
Belarus
Belarus
Ignat G. Chishankov – Junior Researcher
36, F. Skorina str., 220141, Minsk, Republic of Belarus
V. E. Agabekov
Institute of Chemistry of New Materials of the National Academy of Sciences of BelarusBelarus
Belarus
Belarus
Vladimir E. Agabekov – Academician, D. Sc. (Chemistry), Professor, Head of the Department
36, F. Skorina str., 220141, Minsk, Republic of Belarus
References
1. Reeves C. J., Menezes P. L., Jen T.-C., Lovell M. R. The influence of fatty acids on tribological and thermal properties of natural oils as sustainable biolubricants. Tribology International, 2015, vol. 90, pp. 123–134. https://doi.org/10.1016/j.triboint.2015.04.021
2. Anand A., Irfan U. H. M., Vohra K., Raina A., Wani M. F. Role of Green Tribology in Sustainability of Mechanical Systems: A State of the Art Survey. Materials Today: Proceedings, 2017, vol 4, no. 2, pp. 3659–3665. https://doi.org/10.1016/j.matpr.2017.02.259
3. Ku I. S. Y., Reddyhoff T., Holmes A. S., Spikes H. A. Wear of silicon surfaces in MEMS. Wear, 2011, vol. 271, no. 7–8, pp. 1050–1058. https://doi.org/10.1016/j.wear.2011.04.005
4. Cuong P. D., Quy T. D., Yoon E.-S. A study on surface modification for tribological application in MEMS. Proceedings of the International Conference on System Science and Engineering. Ho Chi Minh, 2017, pp. 408–411. https://doi.org/10.1109/ICSSE.2017.8030907
5. Li M., Su B., Zhou B., Wang H., Meng J. Preparation and tribological properties of self-assembled tetraethoxysilane/octadecyltrichlorosilane bilayer films. Surface Topography: Metrology and Properties, 2019, vol. 7, pp. 1–17. https://doi.org/10.1088/2051-672X/ab1564
6. Sahoo R. R., Biswas S. K. Frictional response of fatty acids on steel. Journal of Colloid and Interface Science, 2009, vol. 333, no. 2, pp. 707–718. https://doi.org/10.1016/j.jcis.2009.01.046
7. Kenar J. A., Moser B. R., List G. R. Naturally Occurring Fatty Acids: Source, Chemistry, and Uses. Fatty Acids: Chemistry, Synthesis, and Applications / U. A. Moghis (ed.). Academic Press and AOCS Press, 2017, pp. 23–82. https://doi.org/10.1016/B978-0-12-809521-8.00002-7
8. Krist S. (ed.). Vegetable Fats and Oils. Wien, Springer Internat. Publ., 2020, 832 p. https://doi.org/10.1007/978-3-030-30314-3
9. Grossman R. F. (ed.). Handbook of Vinyl Formulating. Hoboken, New Jersey, John Wiley & Sons, Inc., 2008. 2nd ed. 531 p. https://doi.org/10.1002/9780470253595
10. Liu F., Wang P., Xiong X., Zeng X., Zhang X., Wu G. A Review of Nervonic Acid Production in Plants: Prospects for the Genetic Engineering of High Nervonic Acid Cultivars Plants. Front Plant Sci., 2021. Available at: https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7973461 (Accessed 15 August 2021). https://doi.org/10.3389/fpls.2021.626625
11. Salamianski A. E., Zhavnerko G. K., Agabekov V. E. Tribological behavior of composite Langmuir–Blodgett films of triacontanoic acid. Surface and Coating Technology, 2013, vol. 227, pp. 62–64. http://dx.doi.org/10.1016/j.surfcoat.2013.02.024
12. Kim D. I., Zhavnerko G. K., Ahn H.–S., Choi D.–H. Tribological properties of Langmuir–Blodgett films on silicon surface in microscale sliding contact. Tribology Letters, 2004, vol. 17, no. 2, pp. 169–177. https://doi.org/10.1023/B:TRIL.0000032442.03009.21
13. Patent BY 15411 Zhavnerko G. K., Agabekov V. E., Salamianski А. E., Chizhik S. А., Suslov А. А., Chikunov V. V. Device for forming mono- or multilayers of amphiphilic compounds on a solid surface. Publ. date 28.02.2012.
14. Eftaiha A. F., Qaroush A. K., Kayed G. G., Abdalrahman K. A., Assaf K. I., Paige M. F. Morphological and interaction characteristics of surface active ionic liquids and palmitic acid in mixed monolayers. Chem. Phys. Chem, 2020. Available at: https://chemistry-europe.onlinelibrary.wiley.com/doi/full/10.1002/cphc.202000359 (Accessed 02 August 2021).
15. Li S., Du L., Wei Z., Wang W. Aqueous-phase aerosols on the air-water interface: Response of fatty acid Langmuir monolayers to atmospheric inorganic ions. Science of the Total Environment, 2017, vol. 580, pp. 1155–1161. https://doi.org/10.1016/j.scitotenv.2016.12.072
16. Capistran B. A., Blanchard G. J. Effects of Cu (II) on the Formation and Orientation of an Arachidic Acid Langmuir– Blodgett Film. Langmuir, 2019, vol. 35, no. 9, pp. 3346−3353. https://doi.org/10.1021/acs.langmuir.9b00022
17. Koshima H., Iyotani Y., Peng Q., Ye S. Study of Friction-Reduction Properties of Fatty Acids and Adsorption Structures of their Langmuir–Blodgett Monolayers using Sum-Frequency Generation Spectroscopy and Atomic Force Microscopy. Tribology Letters, 2016, vol. 64, pp. 1–8. https://doi.org/10.1007/s11249-016-0771-y
18. Iimura K., Yamauchi Y., Tsuchiya Y., Kato T., Suzuki M. Two-Dimensional Dendritic Growth of Condensed Phase Domains in Spread Monolayers of cis-Unsaturated Fatty Acids. Langmuir, 2001, vol. 17, no. 15, pp. 4602–4609. https://doi.org/10.1021/la010236w
19. Schaper A., Wolthaus L., Moebius D., Jovin, T. M. Surface morphology and stability of Langmuir-Blodgett monoand multilayers of saturated fatty acids by scanning force microscopy. Langmuir, 1993, vol. 9, no. 8, pp. 2178–2184. https://doi.org/10.1021/la00032a046
20. Zhang P., Xue Q., Du Z., Zhang Z. The tribological behavior of LB films of fatty acids and nanoparticles. Wear, 2000, vol. 242, no. 1–2, pp. 147–151. https://doi.org/10.1016/S0043-1648(00)00405-1
21. Lundgren S. M., Ruths M., Danerlöv K., Persson K. Effects of unsaturation on film structure and friction of fatty acids in a model base oil. Journal of Colloid and Interface Science, 2008, vol. 326, no. 2, pp. 530–536. https://doi.org/10.1016/j.jcis.2008.05.068
22. Zachariah Z., Nalam P. C., Ravindra A., Raju A., Mohanlal A., Wang K., Castillo R. V., Espinosa–Marzal R. M. Correlation Between the Adsorption and the Nanotribological Performance of Fatty Acid-Based Organic Friction Modifiers on Stainless Steel. Tribology Letters, 2020, vol. 68, no. 11, pp. 1–16. https://doi.org/10.1007/s11249-019-1250-z
23. Hasegawa T., Nishijo J., Watanabe M., Umemura J., Ma Y., Sui G., Huo Q., Leblanc R. M. Characteristics of Long-Chain Fatty Acid Monolayers Studied by Infrared External-Reflection Spectroscopy. Langmuir, 2002, vol. 18, no. 12, pp. 4758–4764. https://doi.org/10.1021/la011756u
24. Jiang X., Zhang X., Dai S., Wang D., Li Y., Du Z. Reorganization of behenic acid monolayer on mica. Surface Review and Letters, 2005, vol. 12, no. 1, pp. 59–66. https://doi.org/10.1142/S0218625X05006792
25. Gretić Z. H., Mioč E. K., Čadež V., Šegota S., Otmačić Ćurković H., Hosseinpour S. The Influence of Thickness of Stearic Acid Self-Assembled Film on Its Protective Properties. Journal of The Electrochemical Society, 2016, vol. 163, no. 14, pp. 937–944. https://doi.org/10.1149/2.1461614jes
26. Yiannos P. N. Molecular reorientation of some fatty acids when in contact with water. Journal of Colloid Science, 1962, vol. 17, no. 4, pp. 334–347. https://doi.org/10.1016/0095-8522(62)90013-2
27. Dominguez D. D., Mowery R. L., Turner N. H. Friction and Durabilities of Well-Ordered, Close-Packed Carboxylic Acid Monolayers Deposited on Glass and Steel Surfaces by the Langmuir-Blodgett Technique. Tribology Transactions, 1994, vol. 37, no. 1, pp. 59–66. https://doi.org/10.1080/10402009408983266
Review
Views: 557
Email this article 