Formation of octacalcium phosphate in the interaction of calcium carbonate and monocalcium phosphate monohydrate under galvanostatic conditions
https://doi.org/10.29235/1561-8331-2022-58-3-263-272
Abstract
The calcium phosphate composite octacalcium phosphate / calcite was obtained at pH 5–7 from the CaCO3/Ca(H2PO4)2 aqueous suspension in a galvanostatic mode at a current density of 20 mA/cm2 for 20 min. Drying at 80 °C without the precipitate maturation stage led to a powder formation consisting of brushite, calcite and a small amount of octacalcium phosphate. Prolonged maturation in air for 2 months led to the hydrolytic transformation of brushite into octacalcium phosphate stabilized by calcite. The use of electric current made it possible to increase the amount of octacalcium phosphate in the composite powder with the morphology of lamellar rosettes. Calcination at 800 °C of the composite powders led to the formation of α/β-tricalcium phosphate, β-calcium pyrophosphate, hydroxyapatite, and calcium oxide.
Keywords
octacalciumphosphate,
calcite,
dicalcium phosphate dehydrate,
galvanostatic mode,
tricalcium phosphate,
hydroxyapatite
Supporting agencies: The work was financially supported by the SPSR “Chemical processes, reagents and technologies, bioregulators and bioorganic chemistry” under assignment 2.1.04.7 for 2021–2025
About the Authors
V. K. Krut’ko
Institute of General and Inorganic Chemistry, National Academy of Sciences of Belarus
Belarus
Belarus
Krut’ko Valentina K. – Ph. D. (Chemistry), Associate professor, Head of the Laboratory.
9/1, Surganov str., 220072, Minsk
A. E. Doroshenko
Institute of General and Inorganic Chemistry, National Academy of Sciences of Belarus
Belarus
Belarus
Doroshenko Anna E. – Ph. D. student, Junior researcher.
9/1, Surganov str., 220072, Minsk
O. N. Musskaya
Institute of General and Inorganic Chemistry, National Academy of Sciences of Belarus
Belarus
Belarus
Musskaya Olga N. – Ph. D. (Chemistry), Associate professor, Leading researcher.
9/1, Surganov str., 220072, Minsk
S. M. Rabchynski
Belarusian State University
Belarus
Belarus
Rabchinsky Sergey M. – Ph. D. (Chemistry), Associate 0professor.
4, Nezavisimosti ave., 220030, Minsk
A. I. Kulak
Institute of General and Inorganic Chemistry, National Academy of Sciences of Belarus
Belarus
Belarus
Kulak Anatoly I. – Academician of the National Academy of Sciences of Belarus, D. Sc. (Chemistry), Professor, Director.
9/1, Surganov str., 220072, Minsk
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