Preview

Proceedings of the National Academy of Sciences of Belarus, Chemical Series

Advanced search

Spatiotemporal variability of formaldehyde content in atmospheric air according to satellite measurements

https://doi.org/10.29235/1561-8331-2022-58-3-334-344

Abstract

Formaldehyde (HCHO) is a key ingredient in atmospheric chemistry, a precursor to ozone (O3) and an important indicator of atmospheric photochemical activity. It is also known to be a human and animal carcinogen. To assess the spatial and temporal variability of the formaldehyde content, the article analyzes long-term data (2003–2016) of measurements of the OMI spectrometer located on the Aura satellite. The results of the analysis showed that the tropospheric content of formaldehyde over most of the territory of Belarus for 2003–2016 had an uneven spatial distribution: there is a decrease in concentrations in the direction from the southwest to the northeast. Large cities and industrial centers form zones of increased troposphere pollution. The content of formaldehyde in the cells over the territory of Belarus during the study period was in the range of up to 30.8×1015 mol/cm2 and averaged 6.5×1015 molec./cm2. In most of the obtained values (84.1 %), the formaldehyde concentrations were fixed within the range of 2.0–10.0×1015 molec./cm2, and only 0.6 % exceeded 15.0×1015 molec./cm2. The obtained data are compared with the data of the ground-based atmospheric air monitoring system. The content of formaldehyde in the troposphere over the territory of Belarus, as well as in the surface layer of the atmosphere, has a pronounced seasonal dynamics with a maximum in the warm season with the highest concentrations in July and August. An analysis of the intra-annual dynamics of formaldehyde content in the surface layer and in the troposphere column indicates the presence of general trends, both for Belarus as a whole and for individual cities.1

About the Authors

Yu. G. Kokosh
Institute for Nature Management, National Academy of Sciences of Belarus
Belarus

Kokosh Yuliya G. – Ph. D. (Geography), Senior Researcher.

10, Skoriny str., 220076, Minsk



S. V. Kakareka
Institute for Nature Management, National Academy of Sciences of Belarus
Belarus

Kakareka Sergey V. – D. Sc. (Engineering), Professor, Head of the Laboratory.

10, Skoriny str., 220076, Minsk



References

1. National Environmental Monitoring System of the Republic of Belarus. Monitoring of atmospheric air. Archive of observation results for 2005–2015. Available at: https://www.nsmos.by/content/173.html (accessed 24 April 2021) (in Russian).

2. Norms of maximum permissible concentrations of pollutants in the atmospheric air and approximately safe levels of exposure to pollutants in the atmospheric air of settlements and places of mass recreation of the population: Decree of the Ministry of Health of the Republic of Belarus, 08.11.2016, No. 113. Base of regulatory legal acts of the Ministry of Health of the Republic of Belarus. Available at: http://www.svetlcge.by/wp-content/uploads/2016/02/Postanovleniye-MZ-RB-ot-08.11.2016-№-113.pdf/ (accessed 10 October 2021 (in Russian).

3. Assessment report on formaldehyde for developing ambient air quality objectives. Edmonton: Alberta Environment, 2004. 112 p. https://doi.org/10.5962/bhl.title.102043

4. Kakareka S. V. Formaldehyde in urban air. Izvestiya Rossiiskoi Akademii Nauk. Seriya Geograficheskaya, 2012, no. 5, pp. 82–89 (in Russian).

5. Bezuglaya E. Y, Smirnova N. V. Air of cities and its changes. St. Petersburg, Asterion Publ., 2008. 254 p. (in Russian).

6. Kokosh Y. G., Kakareka S. V. Seasonal dynamics of formaldehyde concentrations in atmospheric air of Belarusian cities. Prirodopol’zovaniye = Nature management, 2019, no. 1, pp. 28–36 (in Russian).

7. Kakareka S. V., Kokosh Yu. G. The long-term dynamics of formaldehyde content in the atmospheric air of the cities of Belarus. Prirodopol’zovaniye: sb. nauch. tr. [Nature management: a collection of articles]. Minsk, 2013, vol. 23, pp. 31–39 (in Russian).

8. Kapsargin F. P., Kashkin V. B., Simonov K. V., Zuev D. V. Assessment of ecosystem based on remote sensing of the atmosphere. Sibirskii aerokosmicheskii zhurnal = Siberian Aerospace Journal, 2012, no. 6 (46), pp. 73–77 (in Russian).

9. Duncan B. N., Prados A. I., Lamsal L. N., Liu Y., Streets D. G., Gupta P., Hilsenrath E., Kahn R. A., Nielsen J. E., Beyersdorf A. J. , Burton S. P., Fiore A. M., Fishman J., Henze D. K., Hostetler C. A., Krotkov N. A., Lee P., Lin M., Pawson S., Pfister G., Pickering K. E., Pierce R. B., Yoshida Y., Ziemba L. D. Satellite data of atmospheric pollution for U.S. air quality applications: Examples of applications, summary of data end-user resources, answers to FAQs, and common mistakes to avoid. Atmospheric Environment, 2014, vol. 94, pp. 647–662. https://doi.org/10.1016/j.atmosenv.2014.05.061

10. De Smedt I., Müller J.-F., Stavrakou T., van der A R., Eskes H., Van Roozendael M. Twelve years of global observations of formaldehyde in the troposphere using GOME and SCIAMACHY sensors. Atmospheric Chemistry and Physics, 2008, vol. 8, pp. 4947–4963. https://doi.org/10.5194/acp-8-4947-2008

11. Levelt, P., Oord, G. H. J., Dobber M., Mälkki Anssi, Visser, Harm, Vries, Johan, Stammes, Piet, Lundell, Jens, Saari, Heikki. The Ozone Monitoring Instrument. IEEE Transactions on Geoscience and Remote Sensing, 2006, vol. 44, no. 5, pp. 1093–1101. https://doi.org/10.1109/TGRS.2006.872333

12. Chance K. (ed.). OMI Algorithm Theoretical – Basis Document. Vol. IV: OMI Trace Gas Algorithms. OMI, 2002. 78 с.

13. TEMIS – Tropospheric Emission Monitoring Internet Service. Available at: http://www.temis.nl/index.php (accessed 20 April 2018).

14. Fu T.-M., Jacob D. J., Palmer P. I., Chance K., Wang Y. X., Barletta B., Blake D. R., Stanton J. C., Pilling M. J. Spacebased formaldehyde measurements as constraints on volatile organic compound emissions in East and South Asia. Journal of Geophysical Research, 2007, vol. 112, no. D6. https://doi.org/10.1029/2006JD007853

15. DeSmedt I., Stavrakou T., Hendrick F., Danckaert T., Vlemmix T., Pinardi G., Theys N., Lerot C., Gielen C., Vigouroux C., Hermans C., Fayt C., Veefkind P., Müller J. F., Van Roozendael M. Diurnal, seasonal and long-term variations of global formaldehyde columns inferred from combined OMI and GOME-2 observations. Atmospheric Chemistry and Physics, 2015, vol. 15, no. 21, pp. 12519–12545. https://doi.org/10.5194/acp-15-12519-2015

16. Sitnov S. A., Mokhov I. I. Formaldehyde and nitrogen dioxide in the atmosphere during summer weather extremes and wild-fires in European Russia in 2010 and Western Siberia in 2012. International Journal of Remote Sensing, 2017, vol. 38, no. 14, pp. 4086–4106. https://doi.org/10.1080/01431161.2017.1312618

17. Sitnov S. A., Mokhov I. I. Weekly cyclicity of CH2O and NO2 content in the atmosphere of Russian regions (according to satellite data). 2017. Available at: https://www.researchgate.net/publication/322420770_Nedelnaa_ciklicnost_soderzania_CH2O_i_NO2_v_atmosfere_rossijskih_regionov_po_sputnikovym_dannym (accessed 6 December 2018). (in Russian).


Review

Views: 264


Creative Commons License
This work is licensed under a Creative Commons Attribution 4.0 License.


ISSN 1561-8331 (Print)
ISSN 2524-2342 (Online)