Preview

Proceedings of the National Academy of Sciences of Belarus, Chemical Series

Advanced search

Catalytic method for synthesis of polyampholytes from (poly)acrylonitrile fiber

Abstract

Fibrous amino carboxylic ion exchangers with different anionic and cationic exchange capacity have been prepared by a new method of the high-temperature catalytic amination of the PAN fiber nitrile groups. Chelating ion exchangers with aminodiacetic functional groups has been obtained from these ion exchangers by alkylation reaction. Mechanical properties of monofilaments of obtained materials have been studied. Acid-base properties for each functional group type of the synthesized ion exchangers have been determined by the earlier proposed method.

About the Authors

P. V. Nesteronok
Институт физико-органической химии НАН Беларуси
Belarus


E. G. Kosandrovich
Институт физико-органической химии НАН Беларуси
Belarus


L. N. Shachenkova
Институт физико-органической химии НАН Беларуси
Belarus


T. A. Korshunova
Институт физико-органической химии НАН Беларуси
Belarus


References

1. Druzhinina T. V., Nazar’ina L. A. // Fibre Chemistry. 1999. Vol. 31, N 4. P. 252-262.

2. Kotze M. H. // J. of the minerals, metals and materials society. 1992. May. P. 46-50.

3. Zverev M. P. // Fibre Chemistry. 1993. Vol. 25, N 6. P. 498-504.

4. Zverev M. P. // Fibre Chemistry. 2002. Vol. 34, N 6. P. 456-465.

5. Soldatov V. S. // Solvent extraction and ion exchange. Vol. 26. P. 457-513.

6. Kosandrovich E. G., Soldatov V. S. Fibrous ion exchangers / Chapter 9 of the book «Ion exchange technology I: theoryand materials», Inamuddin and Mohammad Luqman Eds. Springer: United Kingdom, 2012. Р. 299-371.

7. Патент РБ 15904.

8. Soldatov V. S. // React. and Funct. Polym. 1998. N38. P. 73-112.

9. Нестеронок П. В., Солдатов В. С. // Весцi НАН Беларусi. Cер. хiм. навук. 2013. № 2. С. 31-36.

10. Лысенко А. А., Асташкина В. О., Емец Л. В., Вольф А. Л. // ЖПХ. 1989. Т. 62, № 10. С. 2287-2293.

11. Szabadka O. // Talanta. 1982. Vol. 29. P. 177-181.


Review

Views: 436


Creative Commons License
This work is licensed under a Creative Commons Attribution 4.0 License.


ISSN 1561-8331 (Print)
ISSN 2524-2342 (Online)