Obtaining hybrid absorbents by grafting acrylamide onto chitosan chains under gamma irradiation
https://doi.org/10.29235/1561-8331-2023-59-3-242-256
Abstract
Hybrid hydrogels have been synthesized by radiation grafting of acrylamide to chitosan chains. The structure of the acrylamide-grafted chitosan was examined using FTIR spectroscopy, X-ray diffraction and simultaneous thermal analysis. It has been determined that both hydroxyl and amino groups of the polysaccharide are the grafting centers of growing polyacrylamide chains on the chitosan macromolecules. The effect of the reagents ratio on the sorption and rheological properties of the obtained hydrogels has been studied. Hydrogels based on acrylamide-grafted chitosan were modified chemically by alkaline hydrolysis, and the effect of hydrolysis on the sorption capacity of hydrogels with respect to water and Cu(II) ions was examined.
Keywords
chitosan,
acrylamide,
gamma irradiation,
radiation initiation,
radical grafting copolymerization,
hydrogel,
sorption capacity,
Cu(II) ions
Supporting agencies: The research was supported financially by the BRFFR (grant no. X22УЗБ-025) «New methods for the preparation of hybrid polymer superabsorbents based on polysaccharides and polyacrylates».
About the Authors
E. K. Fomina
Research Institute for Physical Chemical Problems of the Belarusian State University
Belarus
Belarus
Fomina Elena K. – Ph. D. (Chemistry), Leading Researcher
14, Leningradskaya Str., 220006, Minsk
E. V. Grinyuk
Research Institute for Physical Chemical Problems of the Belarusian State University; Belarusian State University
Belarus
Belarus
Grinyuk Evgeni V. – Ph. D. (Chemistry), Associate Professor, Director
14, Leningradskaya Str., 220006, Minsk
I. A. Klimovtsova
Research Institute for Physical Chemical Problems of the Belarusian State University
Belarus
Belarus
Klimovtsova Iraida A. – Senior Researcher
14, Leningradskaya Str., 220006, Minsk
D. L. Kudryavsky
Research Institute for Physical Chemical Problems of the Belarusian State University; Belarusian State University
Belarus
Belarus
Kudryavsky Dmitry L. – Postgraduate Student, Junior Researcher
14, Leningradskaya Str., 220006, Minsk
A. A. Fedorenko
Research Institute for Physical Chemical Problems of the Belarusian State University; Belarusian State University
Belarus
Belarus
Fedorenko Alexandra A. – Graduate Student, Junior Researcher
14, Leningradskaya Str., 220006, Minsk
Y. D. Ivanchikov
Limited Liability Company «Adukar»
Belarus
Belarus
Ivanchikov Yan D. – Chemist
13, Moskovskaya Str., 220007, Minsk
D. I. Shiman
Research Institute for Physical Chemical Problems of the Belarusian State University; Belarusian State University
Belarus
Belarus
Shiman Dmitri I. – Ph. D. (Chemistry), Аssociate Professor, Leading Researcher
14, Leningradskaya Str., 220006, Minsk
I. A. Salnikova
The Joint Institute for Power and Nuclear Research – Sosny of the National Academy of Sciences of Belarus
Belarus
Belarus
Salnikova Irina A. – Head of the Research Section
220109, lockbox 119, Minsk
O. V. Yakimenko
Belarusian State University
Belarus
Belarus
Yakimenko Oleg V. – Senior Lecturer, Chemistry Department
14, Leningradskaya Str., 220006, Minsk
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