Novel derivatives of atophan (2-phenylquinoline-4-carboxic acid)
https://doi.org/10.29235/1561-8331-2024-60-1-27-35
Abstract
Acylation of substituted hydroxybenzaldehydes with hydrochloride of atophane acylchloride in dichloromethane in the presence of triethylamine gave esters, capable of forming (E)-azomethines when condensed with amines (4-aminoazobenzene, 4-aminoantipyrine) in methanol. In addition, an ester of atophane with a natural fragment of curcumin was obtained. Films based on (E)-azomethine with an azobenzene fragment were found to have a high polarizing ability.
Keywords
atophane,
4-aminoantipyrine,
4-aminoazobenzene,
curcumin,
hydroxybenzaldehydes,
acylation,
azomethines
Supporting agencies: This work has been performed with a partial financial support of Belarusian Republican Foundation for Fundamental Research (grant Х23-012).
About the Authors
E. A. Dikusar
Institute of Physical Organic Chemistry of the National Academy of Sciences of Belarus
Belarus
Belarus
Evgenij A. Dikusar – Ph. D. (Chemistry), Senior Researcher, Institute of Physical Organic Chemistry of the National Academy of Sciences of Belarus.
13, Surganov Str., 220072, Minsk
E. A. Akishina
Institute of Physical Organic Chemistry of the National Academy of Sciences of Belarus
Belarus
Belarus
Ekaterina A. Akishina – Researcher, Institute of Physical Organic Chemistry of the National Academy of Sciences of Belarus.
13, Surganov Str., 220072, Minsk
S. G. Stepin
Vitebsk State Order of Peoples’ Friendship Medical University
Belarus
Belarus
Svjatoslav G. Stepin – Ph. D. (Chemistry), Associate Professor, Head of the Department, Vitebsk State Order of Peoples’ Friendship Medical University.
17, Frunze Ave., 210023, Vitebsk
L. N. Filippovich
Institute of Physical Organic Chemistry of the National Academy of Sciences of Belarus; International Sakharov Environmental Institute of Belarusian State University
Belarus
Belarus
Liudmila N. Filippovich – Ph. D. (Chemistry), Associate Professor, Senior Researcher, Institute of Physical Organic Chemistry of the National Academy of Sciences of Belarus.
13, Surganov Str., 220072, Minsk
N. V. Bogdanova
International Sakharov Environmental Institute of Belarusian State University
Belarus
Belarus
Natalia V. Bogdanova – Senior Lecturer, International Sakharov Environmental Institute of Belarusian State University.
23A, Dolgbrodskaya Str., 220070, Minsk
S. N. Shahab
Institute of Physical Organic Chemistry of the National Academy of Sciences of Belarus; International Sakharov Environmental Institute of Belarusian State University
Belarus
Belarus
Siyamak Nasser Shahab – Ph. D. (Chemistry), Associate Professor, Leading Researcher, Institute of Physical Organic Chemistry of the National Academy of Sciences of Belarus.
13, Surganov Str., 220072, Minsk
V. I. Potkin
Institute of Physical Organic Chemistry of the National Academy of Sciences of Belarus
Belarus
Belarus
Vladimir I. Potkin – Dr. Sci. (Chemistry), Professor, Academician, Head of the Laboratory, Institute of Physical Organic Chemistry of the National Academy of Sciences of Belarus.
13, Surganov Str., 220072, Minsk
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