Determination of the quantitative content of volatile components in ethanol-containing products
S. V. Charapitsa,
S. N. Sytova,
L. N. Sabalenka,
A. N. Kavalenka,
D. V. Yushkevitc,
M. F. Zayats,
V. V. Egorov,
S. M. Leschev https://doi.org/10.29235/1561-8331-2024-60-4-340-346
Abstract
A method is proposed for correctly determining the quantitative content of volatile components, including ethyl alcohol, in alcohol-containing products. The method is based on the use of sample density measurement data and chromatographic data for determining the quantitative content of volatile compounds. It is shown that in a number of cases the difference between the values of the volumetric content of ethyl alcohol in alcoholic products, calculated according to the interstate standard GOST 3639 and according to the proposed method, exceeds by several times the declared measurement error limit of 0.1 % by volume. The results obtained can be used to update state, interstate and international standards for quality control and safety of alcoholic and alcohol-containing products.
About the Authors
S. V. Charapitsa
Institute for Nuclear Problems of Belarusian State University
Belarus
Belarus
Charapitsa Siarhei V. – Ph. D. (Physics and Mathe matics), Associate Professor. Leading Researcher
11, Babruiskaya Str., 220006, Minsk
S. N. Sytova
Institute for Nuclear Problems of Belarusian State University
Belarus
Belarus
Sytova Svetlana N. – Ph. D. (Physics and Mathematics), Associate Professor. Head of the Laboratory
11, Babruiskaya Str., 220006, Minsk
L. N. Sabalenka
Belarusian State University
Belarus
Belarus
Sabalenka Lidziya N. – Postgraduate Student
14, Leningradskaya Str., 220030, Minsk
A. N. Kavalenka
Institute for Nuclear Problems of Belarusian State University
Belarus
Belarus
Kavalenka Anton N. – Senior Researcher
11, Babruiskaya Str., 220006, Minsk
D. V. Yushkevitc
Belarusian State University; Institute for Nuclear Problems of Belarusian State University
Belarus
Belarus
Yushkevitch Daniil V. – 5th year Student
14, Leningradskaya Str., 220030, Minsk
M. F. Zayats
Belarusian State University
Belarus
Belarus
Zayats Mikhail F. – D. Sc. (Chemistry), Head of the Department
14, Leningradskaya Str., 220030, Minsk
V. V. Egorov
Belarusian State University
Belarus
Belarus
Egorov Vladimir V. – D. Sc. (Chemistry), Professor
14, Leningradskaya Str., 220030, Minsk
S. M. Leschev
Belarusian State University
Belarus
Belarus
Leschev Sergey M. – D. Sc. (Chemistry), Professor
14, Leningradskaya Str., 220030, Minsk
References
1. Commission Regulation (EC) № 2870/2000 laying down Community reference methods for the analysis of spirits drinks. Official Journal, 2000, L 333. Available at: http://data.europa.eu/eli/reg/2000/2870/oj (accessed 1 February 2023).
2. State Standard 3639-79. Water-alcohol solutions. Methods for determining the concentration of ethyl alcohol. Moscow, IPK Standards Publishing House, 2004. 12 p. (in Russian).
3. Maksimova M. I. Tables for determining the volume and content of ethyl alcohol in water-alcohol solutions. Moscow, IPC Standards Publishing House, 1999. 144 p. (in Russian).
4. International alcoholometric tables. Available at: https://www.oiml.org/en/files/pdf_r/r022-e75.pdf (accessed 1 February 2023).
5. STB 2368-2014. Fruit brandy. General technical conditions. Minsk, Gosstandart, Belarusian State Institute of Standardization and Certification, 2014. 12 p. (in Russian).
6. STB 1952-2009. Raw ethyl alcohol from food raw materials. Technical specifications. Minsk, Gosstandart, Belarusian State Institute of Standardization and Certification, 2009. 12 p. (in Russian).
7. STB 2369-2014. Fruit vodkas. General technical conditions. Minsk, Gosstandart, Belarusian State Institute of Standardization and Certification. 16 p. (in Russian).
8. STB 1386-2013. Cognacs. General technical conditions. Minsk, Gosstandart, Belarusian State Institute of Standardization and Certification, 2013. 16 p. (in Russian).
9. STB 2138-2011. Belarusian Calvados. General technical conditions. Minsk, Gosstandart, Belarusian State Institute of Standardization and Certification, 2011. 16 p. (in Russian).
10. State Standard 31493-2012. Wine distillate. Technical specifications. Moscow, Standartinform Publ., 2013. 12 p. (in Russian).
11. Regulation (EC) No 110/2008 of the European Parliament and of the Council of 15 January 2008 on the Definition, Description, Presentation, Labelling and the Protection of Geographical Indications of Spirit Drinks and Repealing Council Regulation (EEC) No 1576/89. Official Journal of the European Union, 2008, L 39/16. Available at: http://data.europa.eu/eli/reg/2008/110(1)/oj (accessed 1 February 2023) (in Russian).
12. Charapitsa S. V., Sytova S. N., Korban A. L., Sobolenko L. N., Egorov V. V., Leschev S. M., Cabala R., Yilmaztekin M., Cabaroglu T. Interlaboratory Study of the method for dIrect determInatIon of VolatIle compoundS In alcoholIc productS uSIng ethanol aS Internal Standard Zhurnal Belorusskogo gosudarstvennogo universiteta. Himiya = Journal of the Belarusian State University. Chemistry, 2020, vol. 1, pp. 74–87 (in Russian). https://doi.org/10.33581/2520-257X-2020-1-74-87
13. Charapitsa S. V., Sytova S. N., Sobolenko L. N., Kolesnov A. Y., Tsimbalaev S. R. Improving quality and safety control of alcoholic and alcohol-containing products. Kontrol’ kachestva produkcii = Production Quality Control, 2021, № 11, pp. 41–46 (in Russian).
14. Sabalenka L. N., Charapitsa S. V., Sytova S. N., Kavalenka A. N., Zayats M. F., Egorov V. V., Leschev S. M., Melsitava I. V. Innovative method for determining the quantitative content of volatile compounds in alcohol products. Pishhevaya promyshlennost’: nauka i tehnologii = Food industry: science and technology, 2022, vol. 15, no. 4, pp. 88–99 (in Russian). https://doi.org/10.47612/2073-4794-2022-15-4(58)-88-99
15. STB 1929-2009 (State Standard Р 51653-2000). Wine products and wine raw materials. Method for determining the volume fraction of ethyl alcohol. Minsk: Gosstandart: Belarusian state Institute of Standardization and Certification, 2009. 14 p. (in Russian).
16. Correct determination of the volumetric content of ethyl alcohol. Available at: https://elab.bsu.by/article/747 (accessed 2 January 2023) (in Russian).
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