Preview

Proceedings of the National Academy of Sciences of Belarus, Chemical Series

Advanced search

Gas-sensitive composition of tungsten oxide with multiwall carbon nanotubes

Abstract

Multiwall carbon nanotubes (MWCNTs), exhibiting high gas adsorption activity, have been prepared in the high voltage discharge plasma under atmospheric pressure from a mixture of hydrocarbons (methane, propane) and air. The structural characteristics of nanotubes have been studied by TEM. Composition WO3 - MWNTs, prepared by sol-gel method, is of interest to create selective sensitive detectors of combustible gases. The greatest sensitivity to propane (≤ 500 %) has been observed at the substrate temperature below 200 °C, whereas high sensitivity to NO2 (≤300 %) has been observed at higher temperatures (T - 240 °C and more).

About the Authors

Y. S. Haiduk
Belarusian State University
Belarus


A. A. Savitsky
Belarusian State University
Belarus


D. A. Strizhakov
Institute of Chemistry of New Materials of National Academy of Sciences of Belarus
Belarus


O. G. Reutskaya
Research Institute of radiomaterials
Belarus


I. A. Taratyn
Research Institute of radiomaterials
Belarus


References

1. Wetchakun, K. Semiconducting metal oxides as sensors for environmentally hazardous gases / K. Wetchakun al.] // Sens. Actuators B. - 2011. - Vol. 160. - P. 580-591.

2. Wu, R. J. Promotive effect of CNT on Co<sub>3</sub>O<sub>4</sub>-SnO<sub>2</sub> in a semiconductor-type CO sensor working at room temperature / R. J. Wu al.] // Sens. Actuators B. - 2008. - Vol. 131. - P. 306-312.

3. Wongchoosuk, Ch. Portable electronic nose based on carbon nanotube-SnO<sub>2</sub> gas sensors and its application for detection of methanol contamination in whiskeys / Ch. Wongchoosuk al.] // Sens. Actuators B. - 2010. - Vol. 147. - P. 392-399.

4. Wei, B. Y. A novel SnO<sub>2</sub> gas sensor doped with carbon nanotubes operating at room temperature / B. Y. Wei al.] // Sens. Actuators B. - 2004. - Vol. 101. - P. 81-89.

5. Ding, X. C-doped WO<sub>3</sub> microtubes assembled by nanoparticles with ultrahigh sensitivity to toluene at low operating temperature / Ding Xiaohu [е! al.] // Sensors. Actuators B. - 2011. - Vol. 155. - P. 86-92.

6. Wu, R. J. The Novel CO sensing material CoOOH-WO<sub>3</sub> with Au and SWCNT performance enhancement / R. J. Wu fct al.] // Sens. Actuators B. - 2009. - Vol. 138. - P. 35-41.

7. Balazsi, C. Novel hexagonal WO<sub>3</sub> nanopowder with metal decorated carbon nanotubes as NO2 gas sensor / C. Balazsi fct al.] // Sens. Actuators B: Chem. - 2008. - Vol. 133. - P. 151-155.

8. Гайдук, Ю. С. Физико-химические свойства оксидной композиции WO<sub>3</sub>-Co<sub>3</sub>O<sub>4</sub>, полученной золь-гель методом / Ю. С. Гайдук, В. А. Ломоносов, А. А. Савицкий // Весці Нац. акад. навук Беларусі. Сер. хім. навук. - 2015. - № 2. -С. 9-13.

9. Гайдук, Ю. С. Влияние добавок благородных металлов на газочувствительные свойства оксида вольфрама, полученного золь-гель методом / Ю. С. Гайдук, А. А. Савицкий / Весці Нац. акад. навук Беларусі. Сер. хім. навук. -2015. - № 4. - С. 11-16.

10. Щур, Д. В. Углеродные наноматериалы и фазовые превращения в них / Д. В. Щур, З. А. Матысина, С. Ю. Загинайченко. - Днепропетровск: Наука и образование, 2007. - С. 615-616.

11. Chen, Y. K. Synthesis of carbon nanotubes containing metal oxides and metals of the d-block and f-block transition metals and related studies / Y. K. Chen al.] // J. Mater. Chem. - 1997. - Vol. 7, N 3. - P. 545-549.

12. Monthioux, M. Filling single-wall carbon nanotubes / M. Monthioux // Carbon. - 2002. Vol. 40. - P. 1809-1823.

13. Liu, J. A novel antimony-carbon nanotube-tin oxide thin film: carbon nanotubes as growth guider and energy buffer. Application for indoor air pollutants gas sensor / J. Liu al.] // J. Phys. Chem. 2008. - Vol. 112. - P. 6119-6125.

14. Wisitsoraat, A. Electron beam evaporated carbon nanotube dispersed SnO2 thin film gas sensor / A. Wisitsoraat fct al.] // J. Electroceram. - 2006. - Vol. 17. - P. 45-49.


Review

Views: 441


Creative Commons License
This work is licensed under a Creative Commons Attribution 4.0 License.


ISSN 1561-8331 (Print)
ISSN 2524-2342 (Online)