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A CARBOXYLATE ION EXCHANGER BASED ON POLYACRYLONITRILE FIBER AS A POTENTIAL COMPONENT OF NUTRIENT SUBSTRATES FOR PLANTS

Abstract

The acidity parameters and type of functional groups of the aminocarboxylate polyampholyte with prevailing carboxylate groups prepared from an industrial polyacrylonitrile fiber (Panion-110), have been determined. An algorithm for determining the type of functional groups based on the potentiometric titration data at different concentrations of the background electrolyte, has been proposed. Titration curves were calculated for the background electrolyte concentrations corresponding to soil and nutrient solutions for plants. It has been concluded that the ion exchanger is suitable as a component of the ion exchanging fibrous substrate for plants, carrying potassium ions.

About the Authors

D. V. Shakhno
Institute of Physical Organic Chemistry of the National Academy of Sciences of Belarus
Belarus
Junior Researcher


V. S. Soldatov
Institute of Physical Organic Chemistry of the National Academy of Sciences of Belarus
Belarus

Academician, D. Sc. (Chemistry), Professor, Head of the Laboratory

 

 



References

1. Soldatov V. S., Kosandrovich E. G., “Ion exchangers for air purification”, Ion exchange and solvent extraction, 2011, vol. 20, pp. 45–117.

2. Kosandrovich E. G., Soldatov V. S., “Fibrous Ion Exchangers”, Ion exchange technology I: theory and materials, Springer, Amsterdam, NL, 2012, pp. 299–371.

3. Zverev M. P., Khemosorbtsionnye volokna [Chemosorption fibers], Khimiia, Moscow, RU, 1981.

4. Vol’f L. A., Volokna s osobymi svoistvami [Fibers with special properties], Khimiia, Moscow, RU, 1980.

5. Soldatov V. S., Shunkevich A. A., Sergeev G. I., “Synthesis, structure and properties of new fibrous ion exchangers”, Reactive Polymers, 1988, vol. 7, no. 2–3, pp. 159–172.

6. Arnon D. I., Grossenbacher K. A., “Nutrient. Ion-exchange Materials”, Soil Science, 1947, vol. 63, no. 3, pp. 159–182.

7. Chmoczynska M., Pristavko S., Soldatov V. S., Wasag H., “The influence of ion-exchange substrates on grass growth in sandy soils”, Journal of Plant Nutrition and Soil Science, 2014, vol. 117, no. 3, pp. 438–442.

8. Soldatov V. S., Peryshkina N. G., Kharoshka R. P., Ionitnye pochvy [Ion-exchanging soils], Nauka i tekhnika, Minsk, BY, 1978.

9. Matraszek R., Szymańska M., Chomczyńska M., Soldatov V. S., “Productivity and chemical composition of tomato and cucumber plants growing in nickel polluted soils fertilized with Biona-312”, Communications in Soil Science and Plant Analysis, 2010, vol. 41, no. 2, pp. 155–172.

10. Soldatov V. S., Peryshkina N. G., Lukashevich L. I., Khoroshko R. P., “Artificial substrates for plants based on fibrous ion exchanging materials”, Vestsі Natsyyanal’nai akademіі navuk Belarusі. Seryia khіmіchnykh navuk [Proceedings of the National Academy of Sciences of Belarus. Chemistry Series], 1985, no. 6, pp. 85– 90.

11. Fediun’kin D. V., Intensivnaia kul’tura rastenii v iskusstvennykh usloviiakh [Intensive plant cultivation under artificial conditions], Nauka i tekhnika, Minsk, BY, 1988.

12. Soldatov V. S., “Potentiometric titration of ion exchangers”, Reactive and Functional Polymers, 1998, vol. 38, no. 2–3, pp. 73–112.

13. Nesterenok P. V., Soldatov V. S., “A method for determination of polyampholytes’ acidity parameters”, Vestsі Natsyyanal’nai akademіі navuk Belarusі. Seryia khіmіchnykh navuk [Proceedings of the National Academy of Sciences of Belarus. Chemistry Series], 2013, no. 2, pp. 31–36.

14. Mironova T.V., Soldatov V.S., “Potentiometric titration of ion exchangers at various concentrations of background electrolyte”, Vestsі Natsyyanal’nai akademіі navuk Belarusі. Seryia khіmіchnykh navuk [Proceedings of the National Academy of Sciences of Belarus. Chemistry Series], 2003, no. 4, pp. 95–100.

15. Nesterenok P. V., Soldatov V. S., “Protolytic properties of aminocarboxylic polyampholytes based on modacryl polymeric matrix”, Vestsі Natsyyanal’nai akademіі navuk Belarusі. Seryia khіmіchnykh navuk [Proceedings of the National Academy of Sciences of Belarus. Chemistry Series], 2014, no. 4, pp. 72–79.


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ISSN 1561-8331 (Print)
ISSN 2524-2342 (Online)