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SYNTHESIS AND INVESTIGATION OF NEW FIBROUS CHELATE ION EXCHANGERS FIBAN ХС-1

Abstract

A method for chloromethylation of polypropylene fibers with a graft copolymer of styrene and divinylbenzene was developed and chloromethylated grafted fiber (CGF) with a high content of chloromethyl groups was obtained. CGF was used as intermediate for the preparation of the FIBAN XC-1 fibrous chelate sorbent with iminodiacetate groups, which is obtained by reaction CGF with dimethyl ester of iminodiacetic acid dimethyl ester and subsequent hydrolysis of the ester groups by sodium hydroxide. The method of FTIR spectroscopy was used to study the structure of the fibrous chelate ion exchanger. 

About the Authors

V. I. Grachek
Institute of Physical Organic Chemistry of the National Academy of Sciences of Belarus, Minsk
Belarus

Ph. D. (Chemistry), Leading Researcher

13, Surganov Str., 220072



G. N. Lysenko
Institute of Physical Organic Chemistry of the National Academy of Sciences of Belarus, Minsk
Belarus

Ph. D. (Chemistry), Senior Researcher

13, Surganov Str., 220072



A. A. Shunkevich
Institute of Physical Organic Chemistry of the National Academy of Sciences of Belarus, Minsk
Belarus

Ph. D. (Chemistry), Leading Researcher

13, Surganov Str., 220072



R. V. Martsynkevich
Institute of Physical Organic Chemistry of the National Academy of Sciences of Belarus, Minsk
Belarus

Ph. D. (Chemistry), Researcher

13, Surganov Str., 220072



O. I. Isakovich
Institute of Physical Organic Chemistry of the National Academy of Sciences of Belarus, Minsk
Belarus

Researcher

13, Surganov Str., 220072



A. P. Polikarpov
Institute of Physical Organic Chemistry of the National Academy of Sciences of Belarus, Minsk
Belarus

Ph. D. (Chemistry), Head of the Laboratory

13, Surganov Str., 220072



References

1. Grachek V. I., Shunkevich A. A., Martsynkevich R. V., Soldatov V. S., “Chelate sorbents for water purification”, Ekologiia i promyshlennost’ Rossii [Ecology and Industry of Russia], 2005, no. 1, pp. 25–27.

2. Shunkevich A. A., Grachek V. I., Ugolev I. I., Matveichuk S. V., “Application of FIBAN fibrous sorbents for concentration of 90Sr from wastewater”, Radiokhimiia [Radiochemistry], 2007, vol. 49, no. 6, pp. 554–556.

3. Soldatov V. S., Shunkevich A. A., Elinson I. S., “Chemically active textile materials as efficient means for water purification”, Desalination, 1999, vol. 124, pp. 181–192.

4. Shunkevich A. A., Mediak G. V., Martsinkevich R. V., Grachek V. I., Soldatov V. S., “Fibrous aminocarboxylic ion exchangers”, Corbtsionnye i khromatograficheskie protsessy [Sorption and chromatographic processes], 2001, vol. 1, no. 4, pp. 741–748.

5. Blokhin A. A., Abovskii N. D., Murashkin Iu. V., “Ion exchange extraction of palladium (II) from chloride solutions of complex composition”, Zhurnal prikladnoi khimii [Journal of Applied Chemistry], 2007, no. 7, pp. 1089–1093.

6. Miasoedova G. V., Savin S. B., Khelatoobrazuiushchie sorbenty [Chelating sorbents], Chemistry, Moscow, RU, 1980.

7. Shimamura M., Teramoto K., Yoshioka T., “Polystyrene based functional fibers”, in: Handbook of fiber Science and Technology, Vol. III, High Technology Fiber, part. B, in Zerw M. and Preston J. (ed.), Marcel Dekker Inc., New York, Basel, US, CH, 1989, pp. 209–252.

8. Soldatov V., Pawlowski L., Shunkevich A., Wasag H., New materials and technologies for environmental engineering. Part. I: Synthesis and structure of ion exchange fibers, Monographies of Polish Acad. Sci., Lublin, PL, no. 21, 2004.

9. Shimizu H., “Development of ion exchange technology in Japan. Part. III”, Journal of Ion Exchange, 1993, no. 4, pp. 2–19.

10. Soldatov V. S., Pokrovskaia A. I., Martsinkevich R. V., “Fibrous anion exchangers based on polypropylene”, Zhurnal prikladnoi khimii [Journal of Applied Chemistry], 1984, no. 6, pp. 1410–1413.

11. Eiffler J., Joeken G., Schneider H.-P., The Dow Chemical Company, Process for preparing an aminomethylphosphonic chelating resin, US, Pat. № 5109074 A.

12. Hering R., Khelatoobrazuiushchie ionoobmenniki [Chelatbildende lonenaustauscher], Translated by Barabanov V. A., Mir, Moscow, RU, 1971.

13. Polianskii N. G., Gorbunov G. V., Polianskaia N. P., Metody issledovaniia ionitov [Research methods of ion exchangers], Chemistry, Moscow, RU, 1976.

14. Nikonenko N. A., “Spectral characteristic of carbohydrates on the basis of mathematical treatment of IR spectra”, Abstract of Ph. D. dissertation, optics, The National Academy of Sciences of Belarus, the B. I. Stepanov Institute of Physics, Minsk, BY, 2000.

15. Kuptsov A. Kh., Zhizhin G. N., Fur’e-KR i Fur’e-IK spektry polimerov [Fourier-Raman and Furier – IR spectra of polymers], Fizmatlit, Moscow, RU, 2001.


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ISSN 1561-8331 (Print)
ISSN 2524-2342 (Online)