Hydrolysis of radicals and molecules of some ethers
https://doi.org/10.29235/1561-8331-2020-56-1-75-80
Abstract
The radiolysis of aqueous solutions of tributylphosphate, butylacetate and isobutylacetate under the γ-radiation in an argon atmosphere has been studied. The hydrolysis of ester radicals with the formation of butanol-1, butanol-2, isobutanol and acetic acid has been observed. The effect of pH on the yields of these radiolysis products has been studied. It has been shown that the rate constants of hydrolysis of radicals are ~ 108 times higher than the rate constants of hydrolysis of ester molecules.
About the Author
V. S. Kosobutskii
Belarusian State University
Belarus
Belarus
Viachaslau S. Kosobutskii – Ph. D. (Chemistry), Associate Professor
14, Leningradskaya Str., 220030, Minsk
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