Preview

Proceedings of the National Academy of Sciences of Belarus, Chemical Series

Advanced search

Modification of powder epoxy compositions with highly dispersed magnesium oxide

https://doi.org/10.29235/1561-8331-2020-56-2-220-228

Abstract

The process of forming epoxy powder compositions with the participation of highly dispersed magnesium oxide in the preparation of compositions by extrusion mixing of components in the melt is investigated. It is established that highly dispersed MgO particles participate in the polymerization process and act as additional crosslinking units of defective regions of the polymer network, which improves the functional properties of epoxy powder compositions. Coatings based on modified compositions are characterized by high physicomechanical properties at low temperature curing (130 °С) and can be used to form protective coatings on heat-sensitive products.

About the Authors

V. V. Komar
Institute of General and Inorganic Chemistry of the National Academy of Sciences of Belarus
Belarus

Valentina V. Komar – Ph. D. (Chemisry), Senior Researcher

9/1, Surganov Str., 220072, Minsk



T. A. Pochodina
Institute of General and Inorganic Chemistry of the National Academy of Sciences of Belarus
Belarus

Tatsiana A. Pochodina – Researcher

9/1, Surganov Str., 220072, Minsk



N. V. Kulinich
Institute of General and Inorganic Chemistry of the National Academy of Sciences of Belarus
Belarus

Natallia V. Kulinich – Researcher

9/1, Surganov Str., 220072, Minsk



N. P. Krut’k
Institute of General and Inorganic Chemistry of the National Academy of Sciences of Belarus
Belarus

Nikolai P. Krut’ko – Academician, D. Sc. ( Chemistry), Head of the Department

9/1, Surganov Str., 220072, Minsk



L. V. Ovseenko
Institute of General and Inorganic Chemistry of the National Academy of Sciences of Belarus
Belarus

Ludmila V. Ovseenko – Ph. D. (Chemisry), Deputy Director

9/1, Surganov Str., 220072, Minsk



References

1. Chen C., Knobaib M., Curliss D. Epoxy layered-silicate nanocomposites.Progress in Organic Coatings, 2003, vol. 47, no. 3–4, pp. 376–383. https://doi.org/10.1016/S0300-9440(03)00130-9

2. Bagherzadeh M. R., Mahdavi F. Preparation of epoxy-clay nanocomposite and investigation on its anti-corrosive behavior in epoxy coating. Progress in Organic Coatings, 2007, vol. 60, no. 2, pp. 117–120. https://doi.org/10.1016/j.porgcoat.2007.07.011

3. Zheng Y., Ning R. Effects of nanoparticles on the anticorrosion and mechanical properties of epoxy coating”. Materials Letters, 2003, vol. 57, no. 19, pp. 2940–2944. https://doi.org/10.1016/S0167-577X(02)01401-5

4. Verkholantsev V. V. Nanomaterials in paint coating technology. Lakokrasochnie materialy i ikh primenenie = Russian Coatings Journal, 2004, no. 10, pp. 20–23 (in Russian).

5. Vaganov G.V., Evtyukov N.Z., Mashlyakovskii L.N., Yudin V.E., Elokhovskii V.Yu., Ivan′kova E.M., Volkov A.Y., Sukhanova T.E. Effect of montmorillonite on the structure and properties of powder epoxy compounds for polymeric coatings. Russian journal of applied chemistry, 2011, vol. 84, no. 8, pp. 1408–1413. https://doi.org/10.1134/s1070427211080192

6. Vaganov G. V., Yudin V. E., Mashlyakovskii L. N., Evtukov N. Z., Elokhovskii V. Yu.Epoxy powder coatings with silicate nanoparticles of different morphology. Lakokrasochnye materialy i ih primenenie = Russian Coatings Journal, 2011, no. 11, pp. 37–41 (in Russian).

7. Sychev M. M., Minakova T. S., Slizhov Yu. G., Shilova O. A. Acid-base characteristics of solids and controlof the properties of materials and composites. St. Petersburg, Himizdat Publ., 2016. 276 p. (in Russian).

8. Sitnikov P. A., Ryabkov Yu. I., Belykh A. G., Vaseneva I. N., Kuchin A. V. Physical and chemical regularities of creating new hybrid epoxypolymer nanocomposites with increased strength characteristics. Izvestiya Komi nauchnogo tsentra URO RАN [News of the Komi Scientific Center of the Ural Branch of the Russian Academy of Sciences ], 2016, no. 1(25), pp. 18–22 (in Russian).

9. Ekimova I. A., Minakova T. S. Acid-base, adsorption and photosorption properties of magnesia samples. Protection of Metals, 2008, vol. 44, no. 3, pp. 310–313. https://doi.org/10.1134/s0033173208030156

10. Ekimova I. A., Minakova T. S. Acid-base and adsorption properties of the surface of oxides and fluorides of alkaline earth metals and magnesium. Polzunovskii vestnik = Polzunovsky vestnik, 2013, no. 1, pp. 67–71 (in Russian).

11. Ivanov M. G. Corrosion inhibitor of ferrous metals.Patent no. 2197563 RU.Publ. date. 27.01.2003 (in Russian).

12. Fedoseev A. V., Sorokov A. V., Stepin S. N. Obtaining an anticorrosive pigment by mechanical and chemical treatment of magnesium oxide.Vestnik tekhnologicheskogo universiteta = Herald of Kazan Technological University, 2012, vol. 15, pp. 69–70 (in Russian).

13. Matsukevich I. V., Krutko N. P., Ovseenko L. V., Polkhovskaya O. V., Hubitski D. V., Vashuk V. V. Effect of preparation method on physicochemical properties of nanostructured MgO powder.Vesti Natsyianal’noi akademii navuk Belarusi. Seryia khimicheskikh navuk= Proceeding of the National Academy of Sciences of Belarus. Chemical Series, 2018, vol. 54, no. 3, pp. 281–288 (in Russian). https://doi.org/10.29235/1561-8331-2018-54-3-281-288

14. Meyers R. A. Encyclopedia of Analytical Chemistry: Applications, Theory and Instrumentation. New York, Wiley, 2006. 14344 p. https://doi.org/10.1002/9780470027318

15. Kondrashov S. V., Shashkeev K. A., Popkov O. V., Solovianchik L. V. Mechanical properties of CNT nanocomposites (review). Proceedings of VIAM, 2016, no. 5, pp. 61–83 (in Russian). https://doi.org/10.18577/2307-6046-2016-0-5-8-8

16. Polukeeva L. G., Ananyeva E. S., Khvostov A. S., Larionova I. S., Shatskaya T. E., Ishkov A. V. Micromodification of a mixture of epoxydian binder and polymethylene-n-triphenylborate by detonation nanocarbons and nanodiamonds. Polzunovskii vestnik = Polzunovsky vestnik, 2008, no. 3, pp. 228–232 (in Russian).


Review

Views: 554


Creative Commons License
This work is licensed under a Creative Commons Attribution 4.0 License.


ISSN 1561-8331 (Print)
ISSN 2524-2342 (Online)