Effecting heterogeneous catalysts on aluminum and silicon axides
Abstract
Convenient and technologically suitable methods for immobilization of palladium and 1,2-azole ligands on mesoporous aluminum and silicon oxides have been developed. The obtained palladium composites: Pd /Al2O3(60), Pd / Al2O3(90), Pd-L1/ Al2O3(60), Pd-L2 /SiO2(60) and L1PdCl2@SiO2 demonstrate high catalytic activity and recovery in the Suzuki reaction in aqueous media.
Keywords
мезопористые оксиды алюминия и кремния,
гетерогенные Pd-катализаторы,
изоксазольные,
изотиазольные лиганды,
нековалентная модификация поверхности оксидного носителя,
реакция Сузуки,
mesoporous alumina and silica,
heterogeneous Pd-catalysts,
isoxazol and isothiazol ligands,
noncovalent modification of the surface of the oxide supports,
Suzuki reaction
About the Authors
N. A. Bumagin
M. V. Lomonosov Moscow State University, Department of Chemistry
Russian Federation
Russian Federation
E. A. Dikusar
Institute of Physical Organic Chemistry of the National Academy of Sciences of Belarus
Belarus
Belarus
A. V. Kletskov
Institute of Physical Organic Chemistry of the National Academy of Sciences of Belarus
Belarus
Belarus
S. K. Petkevich
Institute of Physical Organic Chemistry of the National Academy of Sciences of Belarus
Belarus
Belarus
V. I. Potkin
Institute of Physical Organic Chemistry of the National Academy of Sciences of Belarus
Belarus
Belarus
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