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Исследование кинетических закономерностей окислительного превращения пропилена в акролеин на модифицированном клиноптилолите

https://doi.org/10.29235/1561-8331-2025-61-1-24-29

Анатацыя

Изучены кинетические закономерности реакции окислительного превращения пропилена в акролеин на катализаторе 1 % Ni2+-клиноптилолит, при различных температурах (320–380 °С), объемных скоростях |700–1 400 ч–1 и парциальных давлениях реагентов ( PC H3 6 = 0,36–0,46 атм., PO2 = 0,55–0,64 атм.). На основе экспериментальных данных предложена стадийная схема протекания реакции.

Аб аўтарах

Т. Гусейнова
Институт катализа и неорганической химии имени академика М. Нагиева Министерства науки и образования Республики Азербайджан
Азербайджан


Г. Али-заде
Academician M. Nagiyev Institute of Catalysis and Inorganic Chemistry, Ministry of Science and Education of the Republic of Azerbaijan
Азербайджан


М. Алиева
Academician M. Nagiyev Institute of Catalysis and Inorganic Chemistry, Ministry of Science and Education of the Republic of Azerbaijan
Азербайджан


В. Ярыев
Academician M. Nagiyev Institute of Catalysis and Inorganic Chemistry, Ministry of Science and Education of the Republic of Azerbaijan
Азербайджан


Спіс літаратуры

1. Gallagher Milton, Hasche Rudolph Leonard. Process for the manufacture of unsaturated aldehydes. Patent US 2245582. Publ. date 17 Juny 1941. Available at: https://patents.google.com/patent/US2245582A/en (accessed 25.05.2023).

2. Alkhazov T. G., Adjamov K. Yu., Khanmamedova A. K. Catalytic oxidation of propylene. Russian Chemical Reviews, 1982, vol. 51, no. 6, pp. 950–967. https://doi.org/10.1070/RC1982v051n06ABEH002858

3. Keiko N. A., Voronkov M. G. Methods for the synthesis of acrolein and its α-substituted. Russian Chemical Reviews, 1993, vol. 62, no. 8, pp. 796–812. https://doi.org/10.1070/RC1993v062n08ABEH000045

4. Hearne G. W., Adams M. L. Catalytic oxidation of hydrocarbons. Patent US 2486842. Publ. Date 01 November 1949. Available at: https://patents.google.com/patent/US2486842A/en?oq=Catalytic+oxidation+of+hydrocarbons:+pat.+2486842+US.+%E2%84%96+677530 (accessed 25.05.2023).

5. Yukelson I. I. Technology of basic organic synthesis. Moscow, Khimiya Publ., 1968. 507 p. (in Russian).

6. Lebedev N. N. Chemistry and technology of basic organic and petrochemical synthesis. Moscow, Khimiya Publ., 1998. 592 p. (in Russian).

7. Boreskov G. K. Heterogeneous catalysis. Moscow, Nauka Publ., 1989. 197 p. (in Russian).

8. Volta J.-C., Bertrand O., Floquet N. On the reaction specificity of MoO3 faces: the role of Mo18O52 as a precursor for MoO3 propylene oxidation catalysts. Journal of the Chemical Society, Chemical Communications, 1985, no. 19, pp. 1283–1285. https://doi.org/10.1039/c39850001283

9. Hayakawa T., Tsunoda T., Orita H., Kameyama T., Ueda M., Fukuda K., Takehira K. A solid electrolyte-aided study of alkene oxidation on a molybdate catalyst having the scheelite structure. Journal of the Chemical Society, Chemical Communications, 1988, no. 24, pp. 1593–1594. https://doi.org/10.1039/C39880001593

10. Aliev A. M., Najaf-Kuliev U. M., Huseynova T. I., Saryjanov A. A., Safarov A. R., Bakhmanov M. F., Agaeva R. Y., Yaryev V. M. Selection of an active modified zeolite catalyst and studying the kinetics and mechanism of the oxidative conversion of propylene in acrol. Oil Refining and Petrochemistry, 2019, no. 5, pp. 25–30.

11. Aliyev A. M., Najaf-Guliyev U. M., Huseynova T. I., Yariyev V. M., Kazimova E. M. Oxidative conversion of propylene to acroleın on metal zeolite catalysts. Azerbayjan chemical journal, 2019, no. 1, pp. 28–31. https://doi.org/10.32737/0005-2531-2019-1-28-31


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ISSN 1561-8331 (Print)
ISSN 2524-2342 (Online)